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Emission spectrum of oxygen is shown as a band containing all colors with some distinct colors as discrete bold lines.
Emission spectrum of oxygen. When an electrical discharge is passed through a substance, its atoms and molecules absorb energy, which is reemitted as EM radiation. The discrete nature of these emissions implies that the energy states of the atoms and molecules are quantized. Such atomic spectra were used as analytical tools for many decades before it was understood why they are quantized. (credit: Teravolt, Wikimedia Commons)

It was a major puzzle that atomic spectra are quantized. Some of the best minds of 19th-century science failed to explain why this might be. Not until the second decade of the 20th century did an answer based on quantum mechanics begin to emerge. Again a macroscopic or classical body of gas was involved in the studies, but the effect, as we shall see, is due to individual atoms and molecules.

Phet explorations: models of the hydrogen atom

How did scientists figure out the structure of atoms without looking at them? Try out different models by shooting light at the atom. Check how the prediction of the model matches the experimental results.

Models of the Hydrogen Atom

Test prep for ap courses

The visible spectrum of sunlight shows a range of colors from red to violet. This spectrum has numerous dark lines spread throughout it. Noting that the surface of the Sun is much cooler than the interior, so that the surface is comparable to a cool gas through which light passes, which of the following statements correctly explains the dark lines?

  1. The cooler, denser surface material scatters certain wavelengths of light, forming dark lines.
  2. The atoms at the surface absorb certain wavelengths of light, causing the dark lines at those wavelengths.
  3. The atoms in the Sun’s interior emit light of specific wavelength, so that parts of the spectrum are dark.
  4. The atoms at the surface are excited by the high interior temperatures, so that the dark lines are merely wavelengths at which those atoms don’t emit energy.

(b)

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A log in a fireplace burns for nearly an hour, at which point it consists mostly of small, hot embers. These embers glow a bright orange and whitish-yellow color. Describe the characteristics of the energy of this system, both in terms of energy transfer and the quantum behavior of blackbodies.

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Section summary

  • The first indication that energy is sometimes quantized came from blackbody radiation, which is the emission of EM radiation by an object with an emissivity of 1.
  • Planck recognized that the energy levels of the emitting atoms and molecules were quantized, with only the allowed values of E = n + 1 2 hf , size 12{E= left (n+ { { size 8{1} } over { size 8{2} } } right ) ital "hf"} {} where n size 12{n} {} is any non-negative integer (0, 1, 2, 3, …).
  • h size 12{h} {} is Planck’s constant, whose value is h = 6 . 626 × 10 –34 J s. size 12{h = 6 "." "626" times " 10" rSup { size 8{"–34"} } " J " cdot " s"} {}
  • Thus, the oscillatory absorption and emission energies of atoms and molecules in a blackbody could increase or decrease only in steps of size Δ E = hf size 12{ΔE = ital "hf"} {} where f size 12{f} {} is the frequency of the oscillatory nature of the absorption and emission of EM radiation.
  • Another indication of energy levels being quantized in atoms and molecules comes from the lines in atomic spectra, which are the EM emissions of individual atoms and molecules.

Conceptual questions

Give an example of a physical entity that is quantized. State specifically what the entity is and what the limits are on its values.

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Give an example of a physical entity that is not quantized, in that it is continuous and may have a continuous range of values.

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What aspect of the blackbody spectrum forced Planck to propose quantization of energy levels in its atoms and molecules?

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If Planck’s constant were large, say 10 34 size 12{"10" rSup { size 8{"34"} } } {} times greater than it is, we would observe macroscopic entities to be quantized. Describe the motions of a child’s swing under such circumstances.

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Why don’t we notice quantization in everyday events?

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Problems&Exercises

A LiBr molecule oscillates with a frequency of 1 . 7 × 10 13 Hz. size 12{1 "." 7 times "10" rSup { size 8{"13"} } " Hz"} {} (a) What is the difference in energy in eV between allowed oscillator states? (b) What is the approximate value of n size 12{n} {} for a state having an energy of 1.0 eV?

(a) 0.070 eV

(b) 14

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The difference in energy between allowed oscillator states in HBr molecules is 0.330 eV. What is the oscillation frequency of this molecule?

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A physicist is watching a 15-kg orangutan at a zoo swing lazily in a tire at the end of a rope. He (the physicist) notices that each oscillation takes 3.00 s and hypothesizes that the energy is quantized. (a) What is the difference in energy in joules between allowed oscillator states? (b) What is the value of n size 12{n} {} for a state where the energy is 5.00 J? (c) Can the quantization be observed?

(a) 2 . 21 × 10 34 J size 12{2 "." "21" times "10" rSup { size 8{"34"} } " J"} {}

(b) 2 . 26 × 10 34 size 12{2 "." "26" times "10" rSup { size 8{"34"} } } {}

(c) No

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Questions & Answers

What are the factors that affect demand for a commodity
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In economics, a perfect market refers to a theoretical construct where all participants have perfect information, goods are homogenous, there are no barriers to entry or exit, and prices are determined solely by supply and demand. It's an idealized model used for analysis,
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other things being equal
AI-Robot
When MP₁ becomes negative, TP start to decline. Extuples Suppose that the short-run production function of certain cut-flower firm is given by: Q=4KL-0.6K2 - 0.112 • Where is quantity of cut flower produced, I is labour input and K is fixed capital input (K-5). Determine the average product of lab
Kelo
Extuples Suppose that the short-run production function of certain cut-flower firm is given by: Q=4KL-0.6K2 - 0.112 • Where is quantity of cut flower produced, I is labour input and K is fixed capital input (K-5). Determine the average product of labour (APL) and marginal product of labour (MPL)
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What is different between quantity demand and demand?
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Quantity demanded refers to the specific amount of a good or service that consumers are willing and able to purchase at a give price and within a specific time period. Demand, on the other hand, is a broader concept that encompasses the entire relationship between price and quantity demanded
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Economic growth as an increase in the production and consumption of goods and services within an economy.but Economic development as a broader concept that encompasses not only economic growth but also social & human well being.
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it is a curve that we get after connecting the pareto optimal combinations of two consumers after their mutually beneficial trade offs
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In economics, the contract curve refers to the set of points in an Edgeworth box diagram where both parties involved in a trade cannot be made better off without making one of them worse off. It represents the Pareto efficient allocations of goods between two individuals or entities, where neither p
Cornelius
In economics, the contract curve refers to the set of points in an Edgeworth box diagram where both parties involved in a trade cannot be made better off without making one of them worse off. It represents the Pareto efficient allocations of goods between two individuals or entities,
Cornelius
Suppose a consumer consuming two commodities X and Y has The following utility function u=X0.4 Y0.6. If the price of the X and Y are 2 and 3 respectively and income Constraint is birr 50. A,Calculate quantities of x and y which maximize utility. B,Calculate value of Lagrange multiplier. C,Calculate quantities of X and Y consumed with a given price. D,alculate optimum level of output .
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Answer
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c
Jabir
the market for lemon has 10 potential consumers, each having an individual demand curve p=101-10Qi, where p is price in dollar's per cup and Qi is the number of cups demanded per week by the i th consumer.Find the market demand curve using algebra. Draw an individual demand curve and the market dema
Gsbwnw Reply
suppose the production function is given by ( L, K)=L¼K¾.assuming capital is fixed find APL and MPL. consider the following short run production function:Q=6L²-0.4L³ a) find the value of L that maximizes output b)find the value of L that maximizes marginal product
Abdureman
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Source:  OpenStax, College physics for ap® courses. OpenStax CNX. Nov 04, 2016 Download for free at https://legacy.cnx.org/content/col11844/1.14
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