There must be reasons that real macroscopic processes cannot be reversible. We can imagine them going in reverse. For example, heat transfer occurs spontaneously from hot to cold and never spontaneously the reverse. Yet it would not violate the first law of thermodynamics for this to happen. In fact, all spontaneous processes, such as bubbles bursting, never go in reverse. There is a second thermodynamic law that forbids them from going in reverse. When we study this law, we will learn something about nature and also find that such a law limits the efficiency of heat engines. We will find that heat engines with the greatest possible theoretical efficiency would have to use reversible processes, and even they cannot convert all heat transfer into doing work.
[link] summarizes the simpler thermodynamic processes and their definitions.
Summary of simple thermodynamic processes
Isobaric
Constant pressure
Isochoric
Constant volume
Isothermal
Constant temperature
Adiabatic
No heat transfer
Phet explorations: states of matter
Watch different types of molecules form a solid, liquid, or gas. Add or remove heat and watch the phase change. Change the temperature or volume of a container and see a pressure-temperature diagram respond in real time. Relate the interaction potential to the forces between molecules.
Section summary
One of the important implications of the first law of thermodynamics is that machines can be harnessed to do work that humans previously did by hand or by external energy supplies such as running water or the heat of the Sun. A machine that uses heat transfer to do work is known as a heat engine.
There are several simple processes, used by heat engines, that flow from the first law of thermodynamics. Among them are the isobaric, isochoric, isothermal and adiabatic processes.
These processes differ from one another based on how they affect pressure, volume, temperature, and heat transfer.
If the work done is performed on the outside environment, work (
) will be a positive value. If the work done is done to the heat engine system, work (
) will be a negative value.
Some thermodynamic processes, including isothermal and adiabatic processes, are reversible in theory; that is, both the thermodynamic system and the environment can be returned to their initial states. However, because of loss of energy owing to the second law of thermodynamics, complete reversibility does not work in practice.
Conceptual questions
A great deal of effort, time, and money has been spent in the quest for the so-called perpetual-motion machine, which is defined as a hypothetical machine that operates or produces useful work indefinitely and/or a hypothetical machine that produces more work or energy than it consumes. Explain, in terms of heat engines and the first law of thermodynamics, why or why not such a machine is likely to be constructed.
One method of converting heat transfer into doing work is for heat transfer into a gas to take place, which expands, doing work on a piston, as shown in the figure below. (a) Is the heat transfer converted directly to work in an isobaric process, or does it go through another form first? Explain your answer. (b) What about in an isothermal process? (c) What about in an adiabatic process (where heat transfer occurred prior to the adiabatic process)?
A golfer on a fairway is 70 m away from the green, which sits below the level of the fairway by 20 m. If the golfer hits the ball at an angle of 40° with an initial speed of 20 m/s, how close to the green does she come?
A mouse of mass 200 g falls 100 m down a vertical mine shaft and lands at the bottom with a speed of 8.0 m/s. During its fall, how much work is done on the mouse by air resistance
Chemistry is a branch of science that deals with the study of matter,it composition,it structure and the changes it undergoes
Adjei
please, I'm a physics student and I need help in physics
Adjanou
chemistry could also be understood like the sexual attraction/repulsion of the male and female elements. the reaction varies depending on the energy differences of each given gender. + masculine -female.
Pedro
A ball is thrown straight up.it passes a 2.0m high window 7.50 m off the ground on it path up and takes 1.30 s to go past the window.what was the ball initial velocity
2. A sled plus passenger with total mass 50 kg is pulled 20 m across the snow (0.20) at constant velocity by a force directed 25° above the horizontal. Calculate (a) the work of the applied force, (b) the work of friction, and (c) the total work.
you have been hired as an espert witness in a court case involving an automobile accident. the accident involved car A of mass 1500kg which crashed into stationary car B of mass 1100kg. the driver of car A applied his brakes 15 m before he skidded and crashed into car B. after the collision, car A s
can someone explain to me, an ignorant high school student, why the trend of the graph doesn't follow the fact that the higher frequency a sound wave is, the more power it is, hence, making me think the phons output would follow this general trend?
Nevermind i just realied that the graph is the phons output for a person with normal hearing and not just the phons output of the sound waves power, I should read the entire thing next time
Joseph
Follow up question, does anyone know where I can find a graph that accuretly depicts the actual relative "power" output of sound over its frequency instead of just humans hearing
Joseph
"Generation of electrical energy from sound energy | IEEE Conference Publication | IEEE Xplore" ***ieeexplore.ieee.org/document/7150687?reload=true
A string is 3.00 m long with a mass of 5.00 g. The string is held taut with a tension of 500.00 N applied to the string. A pulse is sent down the string. How long does it take the pulse to travel the 3.00 m of the string?