<< Chapter < Page Chapter >> Page >
Two Lewis structures are shown. The left structure shows a sulfur atom with two lone pairs of electrons single bonded to two hydrogen atoms. Near the sulfur is a dipole symbol with a superscripted negative sign. Near each hydrogen is a dipole symbol with a superscripted positive sign. The right structure shows a nitrogen atom with one lone pair of electrons single bonded to three hydrogen atoms. Near the nitrogen is a dipole symbol with a superscripted negative sign. Near each hydrogen is a dipole symbol with a superscripted positive sign.

To summarize, to be polar, a molecule must:

  1. Contain at least one polar covalent bond.
  2. Have a molecular structure such that the sum of the vectors of each bond dipole moment does not cancel.

Properties of polar molecules

Polar molecules tend to align when placed in an electric field with the positive end of the molecule oriented toward the negative plate and the negative end toward the positive plate ( [link] ). We can use an electrically charged object to attract polar molecules, but nonpolar molecules are not attracted. Also, polar solvents are better at dissolving polar substances, and nonpolar solvents are better at dissolving nonpolar substances.

Two diagrams are shown and labeled, “a” and “b.” Diagram a shows two vertical, black lines. The left line is labeled with a negative sign and the right with a positive sign. There are five molecules in between. The molecules are separate from one another and are composed of a hydrogen atom bonded to a fluorine atom. The fluorine atom is labeled with a dipole symbol and a superscripted negative sign while the hydrogen atom is labeled with a dipole symbol and a superscripted positive sign. The molecules are randomly oriented in the space. The right diagram is also bracketed by two vertical, lines, but this time the line labeled as negative is red and the line labeled as positive is blue. The same molecules are present, but this time they are all facing horizontally, with the hydrogen-end of each molecule facing toward the red line.
(a) Molecules are always randomly distributed in the liquid state in the absence of an electric field. (b) When an electric field is applied, polar molecules like HF will align to the dipoles with the field direction.

Polarity simulations

Open the molecule polarity simulation and select the “Three Atoms” tab at the top. This should display a molecule ABC with three electronegativity adjustors. You can display or hide the bond moments, molecular dipoles, and partial charges at the right. Turning on the Electric Field will show whether the molecule moves when exposed to a field, similar to [link] .

Use the electronegativity controls to determine how the molecular dipole will look for the starting bent molecule if:

(a) A and C are very electronegative and B is in the middle of the range.

(b) A is very electronegative, and B and C are not.

Solution

(a) Molecular dipole moment points immediately between A and C.

(b) Molecular dipole moment points along the A–B bond, toward A.

Check your learning

Determine the partial charges that will give the largest possible bond dipoles.

Answer:

The largest bond moments will occur with the largest partial charges. The two solutions above represent how unevenly the electrons are shared in the bond. The bond moments will be maximized when the electronegativity difference is greatest. The controls for A and C should be set to one extreme, and B should be set to the opposite extreme. Although the magnitude of the bond moment will not change based on whether B is the most electronegative or the least, the direction of the bond moment will.

Got questions? Get instant answers now!

Key concepts and summary

VSEPR theory predicts the three-dimensional arrangement of atoms in a molecule. It states that valence electrons will assume an electron-pair geometry that minimizes repulsions between areas of high electron density (bonds and/or lone pairs). Molecular structure, which refers only to the placement of atoms in a molecule and not the electrons, is equivalent to electron-pair geometry only when there are no lone electron pairs around the central atom. A dipole moment measures a separation of charge. For one bond, the bond dipole moment is determined by the difference in electronegativity between the two atoms. For a molecule, the overall dipole moment is determined by both the individual bond moments and how these dipoles are arranged in the molecular structure. Polar molecules (those with an appreciable dipole moment) interact with electric fields, whereas nonpolar molecules do not.

Questions & Answers

how to create a software using Android phone
Wiseman Reply
how
basra
what is the difference between C and C++.
Yan Reply
what is software
Sami Reply
software is a instructions like programs
Shambhu
what is the difference between C and C++.
Yan
yes, how?
Hayder
what is software engineering
Ahmad
software engineering is a the branch of computer science deals with the design,development, testing and maintenance of software applications.
Hayder
who is best bw software engineering and cyber security
Ahmad
Both software engineering and cybersecurity offer exciting career prospects, but your choice ultimately depends on your interests and skills. If you enjoy problem-solving, programming, and designing software syste
Hayder
what's software processes
Ntege Reply
I haven't started reading yet. by device (hardware) or for improving design Lol? Here. Requirement, Design, Implementation, Verification, Maintenance.
Vernon
I can give you a more valid answer by 5:00 By the way gm.
Vernon
it is all about designing,developing, testing, implementing and maintaining of software systems.
Ehenew
hello assalamualaikum
Sami
My name M Sami I m 2nd year student
Sami
what is the specific IDE for flutter programs?
Mwami Reply
jegudgdtgd my Name my Name is M and I have been talking about iey my papa john's university of washington post I tagged I will be in
Mwaqas Reply
yes
usman
how disign photo
atul Reply
hlo
Navya
hi
Michael
yes
Subhan
Show the necessary steps with description in resource monitoring process (CPU,memory,disk and network)
samuel Reply
What is software engineering
Tafadzwa Reply
Software engineering is a branch of computer science directed to writing programs to develop Softwares that can drive or enable the functionality of some hardwares like phone , automobile and others
kelvin
if any requirement engineer is gathering requirements from client and after getting he/she Analyze them this process is called
Alqa Reply
The following text is encoded in base 64. Ik5ldmVyIHRydXN0IGEgY29tcHV0ZXIgeW91IGNhbid0IHRocm93IG91dCBhIHdpbmRvdyIgLSBTdGV2ZSBXb3puaWFr Decode it, and paste the decoded text here
Julian Reply
what to do you mean
Vincent
hello
ALI
how are you ?
ALI
What is the command to list the contents of a directory in Unix and Unix-like operating systems
George Reply
how can i make my own software free of cost
Faizan Reply
like how
usman
hi
Hayder
The name of the author of our software engineering book is Ian Sommerville.
Doha Reply
what is software
Sampson Reply
the set of intruction given to the computer to perform a task
Noor
Got questions? Join the online conversation and get instant answers!
Jobilize.com Reply

Get Jobilize Job Search Mobile App in your pocket Now!

Get it on Google Play Download on the App Store Now




Source:  OpenStax, Chemistry. OpenStax CNX. May 20, 2015 Download for free at http://legacy.cnx.org/content/col11760/1.9
Google Play and the Google Play logo are trademarks of Google Inc.

Notification Switch

Would you like to follow the 'Chemistry' conversation and receive update notifications?

Ask