Explain the function of a catalyst in terms of reaction mechanisms and potential energy diagrams
List examples of catalysis in natural and industrial processes
We have seen that the rate of many reactions can be accelerated by catalysts. A catalyst speeds up the rate of a reaction by lowering the activation energy; in addition, the catalyst is regenerated in the process. Several reactions that are thermodynamically favorable in the absence of a catalyst only occur at a reasonable rate when a catalyst is present. One such reaction is catalytic hydrogenation, the process by which hydrogen is added across an alkene C=C bond to afford the saturated alkane product. A comparison of the reaction coordinate diagrams (also known as energy diagrams) for catalyzed and uncatalyzed alkene hydrogenation is shown in
[link] .
This graph compares the reaction coordinates for catalyzed and uncatalyzed alkene hydrogenation.
Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps, as depicted in the reaction diagrams shown in
[link] . This lower activation energy results in an increase in rate as described by the Arrhenius equation. Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence
accelerates both the forward and the reverse reactions . Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant (see the later chapter on chemical equilibrium).
This potential energy diagram shows the effect of a catalyst on the activation energy. The catalyst provides a different reaction path with a lower activation energy. As shown, the catalyzed pathway involves a two-step mechanism (note the presence of two transition states) and an intermediate species (represented by the valley between the two transitions states).
Using reaction diagrams to compare catalyzed reactions
The two reaction diagrams here represent the same reaction: one without a catalyst and one with a catalyst. Identify which diagram suggests the presence of a catalyst, and determine the activation energy for the catalyzed reaction:
Solution
A catalyst does not affect the energy of reactant or product, so those aspects of the diagrams can be ignored; they are, as we would expect, identical in that respect. There is, however, a noticeable difference in the transition state, which is distinctly lower in diagram (b) than it is in (a). This indicates the use of a catalyst in diagram (b). The activation energy is the difference between the energy of the starting reagents and the transition state—a maximum on the reaction coordinate diagram. The reagents are at 6 kJ and the transition state is at 20 kJ, so the activation energy can be calculated as follows:
Check your learning
Determine which of the two diagrams here (both for the same reaction) involves a catalyst, and identify the activation energy for the catalyzed reaction:
Answer:
Diagram (b) is a catalyzed reaction with an activation energy of about 70 kJ.
Astronomy (from Ancient Greek ἀστρονομία (astronomía) 'science that studies the laws of the stars') is a natural science that studies celestial objects and phenomena. It uses mathematics, physics, and chemistry in order to explain their origin and evolution.
Rafael
vjuvu
Elgoog
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Rosemary
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Rosemary
No
Richard
the big bang theory is a theory which states that all matter was compressed together in one place the matter got so unstable it exploded releasing All its contents in the form of hydrogen
according to the theory of astronomers why the moon is always appear in an elliptical orbit?
Gatjuol
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Govinda
hello
Jackson
hi
Elyana
we're all stars and galaxies a part of sun. how can science prove thx with respect old ancient times picture or books..or anything with respect to present time .but we r a part of that universe
there many theory to born universe but what is the reality of big bang theory to born universe
Asmit
what is the exact value of π?
Nagalakshmi
by big bang
universal
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Aarya
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Michele
from where on earth could u observe all the stars during the during the course of an year
is that so. the question was in the end of this chapter
Karuna
in theory, you could see them all from the equator (though over the course of a year, not at pne time). stars are measured in "declination", which is how far N or S of the equator (90* to -90*). Polaris is the North star, and is ALMOST 90* (+89*).
So it would just barely creep over the horizon.
Christopher
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