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Brunauer, L. S. Deming, W. E. Deming, and E. Teller, J. Am. Chem. Soc. , 1940, 62 , 1723.

Type iv isotherm

Type IV isotherms ( [link] ) occur when capillary condensation occurs. Gases condense in the tiny capillary pores of the solid at pressures below the saturation pressure of the gas. At the lower pressure regions, it shows the formation of a monolayer followed by a formation of multilayers. BET surface area characterization of mesoporous materials, which are materials with pore diameters between 2 - 50 nm, gives this type of isotherm.

Brunauer, L. S. Deming, W. E. Deming, and E. Teller, J. Am. Chem. Soc. , 1940, 62 , 1723.

Type v isotherm

Type V isotherms ( [link] ) are very similar to type IV isotherms and are not applicable to BET.

Brunauer L. S. Deming, W. E. Deming, and E. Teller, J. Am. Chem. Soc. , 1940, 62 , 1723.


The BET equation, [link] , uses the information from the isotherm to determine the surface area of the sample, where X is the weight of nitrogen adsorbed at a given relative pressure (P/Po), X m is monolayer capacity, which is the volume of gas adsorbed at standard temperature and pressure (STP), and C is constant. STP is defined as 273 K and 1 atm.

Multi-point bet

Ideally five data points, with a minimum of three data points, in the P/P 0 range 0.025 to 0.30 should be used to successfully determine the surface area using the BET equation. At relative pressures higher than 0.5, there is the onset of capillary condensation, and at relative pressures that are too low, only monolayer formation is occurring. When the BET equation is plotted, the graph should be of linear with a positive slope. If such a graph is not obtained, then the BET method was insufficient in obtaining the surface area.

  • The slope and y-intercept can be obtained using least squares regression.
  • The monolayer capacity X m can be calculated with [link] .
  • Once X m is determined, the total surface area S t can be calculated with the following equation, where L av is Avogadro’s number, A m is the cross sectional area of the adsorbate and equals 0.162 nm 2 for an absorbed nitrogen molecule, and M v is the molar volume and equals 22414 mL, [link] .

Single point BET can also be used by setting the intercept to 0 and ignoring the value of C. The data point at the relative pressure of 0.3 will match up the best with a multipoint BET. Single point BET can be used over the more accurate multipoint BET to determine the appropriate relative pressure range for multi-point BET.

Sample preparation and experimental setup

Prior to any measurement the sample must be degassed to remove water and other contaminants before the surface area can be accurately measured. Samples are degassed in a vacuum at high temperatures. The highest temperature possible that will not damage the sample’s structure is usually chosen in order to shorten the degassing time. IUPAC recommends that samples be degassed for at least 16 hours to ensure that unwanted vapors and gases are removed from the surface of the sample. Generally, samples that can withstand higher temperatures without structural changes have smaller degassing times. A minimum of 0.5 g of sample is required for the BET to successfully determine the surface area.

Questions & Answers

anyone know any internet site where one can find nanotechnology papers?
Damian Reply
Introduction about quantum dots in nanotechnology
Praveena Reply
what does nano mean?
Anassong Reply
nano basically means 10^(-9). nanometer is a unit to measure length.
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Damian Reply
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Akash Reply
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s. Reply
there is no specific books for beginners but there is book called principle of nanotechnology
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Devang Reply
are you nano engineer ?
fullerene is a bucky ball aka Carbon 60 molecule. It was name by the architect Fuller. He design the geodesic dome. it resembles a soccer ball.
what is the actual application of fullerenes nowadays?
That is a great question Damian. best way to answer that question is to Google it. there are hundreds of applications for buck minister fullerenes, from medical to aerospace. you can also find plenty of research papers that will give you great detail on the potential applications of fullerenes.
what is the Synthesis, properties,and applications of carbon nano chemistry
Abhijith Reply
Mostly, they use nano carbon for electronics and for materials to be strengthened.
is Bucky paper clear?
carbon nanotubes has various application in fuel cells membrane, current research on cancer drug,and in electronics MEMS and NEMS etc
so some one know about replacing silicon atom with phosphorous in semiconductors device?
s. Reply
Yeah, it is a pain to say the least. You basically have to heat the substarte up to around 1000 degrees celcius then pass phosphene gas over top of it, which is explosive and toxic by the way, under very low pressure.
Do you know which machine is used to that process?
how to fabricate graphene ink ?
for screen printed electrodes ?
What is lattice structure?
s. Reply
of graphene you mean?
or in general
in general
Graphene has a hexagonal structure
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what is biological synthesis of nanoparticles
Sanket Reply
what's the easiest and fastest way to the synthesize AgNP?
Damian Reply
types of nano material
abeetha Reply
I start with an easy one. carbon nanotubes woven into a long filament like a string
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advantages of NAA
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