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An x ray diffraction image of a protein. The image shows an array of small black dots, arranged in slightly curved rows, on a white background. A white arm extends from the top left to the center of the image, where there is a small white disk. This white disk is the shadow of the beam block, which blocks the part of the incident x ray beam that was not diffracted by the crystal.
X-ray diffraction from the crystal of a protein (hen egg lysozyme) produced this interference pattern. Analysis of the pattern yields information about the structure of the protein. (credit: “Del45”/Wikimedia Commons)

Summary

  • Radiation is absorbed and emitted by atomic energy-level transitions.
  • Quantum numbers can be used to estimate the energy, frequency, and wavelength of photons produced by atomic transitions.
  • Atomic fluorescence occurs when an electron in an atom is excited several steps above the ground state by the absorption of a high-energy ultraviolet (UV) photon.
  • X-ray photons are produced when a vacancy in an inner shell of an atom is filled by an electron from the outer shell of the atom.
  • The frequency of X-ray radiation is related to the atomic number Z of an atom.

Conceptual questions

Atomic and molecular spectra are discrete. What does discrete mean, and how are discrete spectra related to the quantization of energy and electron orbits in atoms and molecules?

Atomic and molecular spectra are said to be “discrete,” because only certain spectral lines are observed. In contrast, spectra from a white light source (consisting of many photon frequencies) are continuous because a continuous “rainbow” of colors is observed.

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Discuss the process of the absorption of light by matter in terms of the atomic structure of the absorbing medium.

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NGC1763 is an emission nebula in the Large Magellanic Cloud just outside our Milky Way Galaxy. Ultraviolet light from hot stars ionize the hydrogen atoms in the nebula. As protons and electrons recombine, light in the visible range is emitted. Compare the energies of the photons involved in these two transitions.

UV light consists of relatively high frequency (short wavelength) photons. So the energy of the absorbed photon and the energy transition ( Δ E ) in the atom is relatively large. In comparison, visible light consists of relatively lower-frequency photons. Therefore, the energy transition in the atom and the energy of the emitted photon is relatively small.

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Why are X-rays emitted only for electron transitions to inner shells? What type of photon is emitted for transitions between outer shells?

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How do the allowed orbits for electrons in atoms differ from the allowed orbits for planets around the sun?

For macroscopic systems, the quantum numbers are very large, so the energy difference ( Δ E ) between adjacent energy levels (orbits) is very small. The energy released in transitions between these closely space energy levels is much too small to be detected.

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Problems

What is the minimum frequency of a photon required to ionize: (a) a He + ion in its ground state? (b) A Li 2+ ion in its first excited state?

For He + , one electron “orbits” a nucleus with two protons and two neutrons ( Z = 2 ). Ionization energy refers to the energy required to remove the electron from the atom. The energy needed to remove the electron in the ground state of He + ion to infinity is negative the value of the ground state energy, written:
E = −54.4 eV .
Thus, the energy to ionize the electron is +54.4 eV.
Similarly, the energy needed to remove an electron in the first excited state of Li 2+ ion to infinity is negative the value of the first excited state energy, written:
E = −30.6 eV .
The energy to ionize the electron is 30.6 eV.

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Questions & Answers

what is force
Afework Reply
The different examples for collision
Afework
What is polarization and there are type
Muhammed Reply
Polarization is the process of transforming unpolarized light into polarized light. types of polarization 1. linear polarization. 2. circular polarization. 3. elliptical polarization.
Eze
Describe what you would see when looking at a body whose temperature is increased from 1000 K to 1,000,000 K
Aishwarya Reply
how is tan ninety minus an angle equals to cot an angle?
Niicommey Reply
please I don't understand all about this things going on here
Jeremiah Reply
What is torque?
Matthew Reply
In physics and mechanics, torque is the rotational equivalent of linear force. It is also referred to as the moment, moment of force, rotational force or turning effect, depending on the field of study.
Teka
Torque refers to the rotational force. i.e Torque = Force × radius.
Arun
Torque is the rotational equivalent of force . Specifically, it is a force exerted at a distance from an object's axis of rotation. In the same way that a force applied to an object will cause it to move linearly, a torque applied to an object will cause it to rotate around a pivot point.
Teka
Torque is the rotational equivalence of force . So, a net torque will cause an object to rotate with an angular acceleration. Because all rotational motions have an axis of rotation, a torque must be defined about a rotational axis. A torque is a force applied to a point on an object about the axis
Teka
When a missle is shot from one spaceship towards another, it leaves the first at 0.950c and approaches the other at 0.750c. what is the relative velocity of the two shipd
Marifel Reply
how to convert:m^3/s^2 all divided by kg to cm^3/s^2
Thibaza Reply
Is there any proof of existence of luminiferious aether ?
Zero Reply
mass conversion of 58.73kg =mg
Proactive Reply
is Space time fabric real
Godawari Reply
What's the relationship between the work function and the cut off frequency in the diagram above?
frankline Reply
due to the upthrust weight of the object varise with force in which the body fall into the water pendincular with the reflection of light with it
Gift
n=I/r
Gift
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falanga
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falanga
what is meant by fluctuated
Olasukanmi Reply
If n=cv then how v=cn? and if n=c/v then how v=cn?
Natanim
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Mbah Reply
what is electrolysis
Mbah
Electrolysis is the chemical decomposition of electrolyte either in molten state or solution to conduct electricity
Ayomide
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Ayesha Reply
can someone help explain why v2/c2 is =1/2 Using The Lorentz Transformation For Time Spacecraft S′ is on its way to Alpha Centauri when Spacecraft S passes it at relative speed c /2. The captain of S′ sends a radio signal that lasts 1.2 s according to that ship’s clock. Use the Lorentz transformati
Jennifer
Practice Key Terms 5

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Source:  OpenStax, University physics volume 3. OpenStax CNX. Nov 04, 2016 Download for free at http://cnx.org/content/col12067/1.4
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