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Thus, when we say two objects (a thermodynamic system and its environment, for example) are in thermal equilibrium    , we mean that they are at the same temperature, as we discussed in Temperature and Heat . Let us consider three objects at temperatures T 1 , T 2 , and T 3 , respectively. How do we know whether they are in thermal equilibrium? The governing principle here is the zeroth law of thermodynamics    , as described in Temperature and Heat on temperature and heat:

If object 1 is in thermal equilibrium with objects 2 and 3, respectively, then objects 2 and 3 must also be in thermal equilibrium.

Mathematically, we can simply write the zeroth law of thermodynamics as

If T 1 = T 2 and T 1 = T 3 , then T 2 = T 3 .

This is the most fundamental way of defining temperature: Two objects must be at the same temperature thermodynamically if the net heat transfer between them is zero when they are put in thermal contact and have reached a thermal equilibrium.

The zeroth law of thermodynamics is equally applicable to the different parts of a closed system and requires that the temperature everywhere inside the system be the same if the system has reached a thermal equilibrium. To simplify our discussion, we assume the system is uniform with only one type of material—for example, water in a tank. The measurable properties of the system at least include its volume, pressure, and temperature. The range of specific relevant variables depends upon the system. For example, for a stretched rubber band, the relevant variables would be length, tension, and temperature. The relationship between these three basic properties of the system is called the equation of state    of the system and is written symbolically for a closed system as

f ( p , V , T ) = 0 ,

where V , p , and T are the volume, pressure, and temperature of the system at a given condition.

In principle, this equation of state exists for any thermodynamic system but is not always readily available. The forms of f ( p , V , T ) = 0 for many materials have been determined either experimentally or theoretically. In the preceding chapter, we saw an example of an equation of state for an ideal gas, f ( p , V , T ) = p V n R T = 0 .

We have so far introduced several physical properties that are relevant to the thermodynamics of a thermodynamic system, such as its volume, pressure, and temperature. We can separate these quantities into two generic categories. The quantity associated with an amount of matter is an extensive variable    , such as the volume and the number of moles. The other properties of a system are intensive variable     s , such as the pressure and temperature. An extensive variable doubles its value if the amount of matter in the system doubles, provided all the intensive variables remain the same. For example, the volume or total energy of the system doubles if we double the amount of matter in the system while holding the temperature and pressure of the system unchanged.

Summary

  • A thermodynamic system, its boundary, and its surroundings must be defined with all the roles of the components fully explained before we can analyze a situation.
  • Thermal equilibrium is reached with two objects if a third object is in thermal equilibrium with the other two separately.
  • A general equation of state for a closed system has the form f ( p , V , T ) = 0 , with an ideal gas as an illustrative example.

Conceptual questions

Consider these scenarios and state whether work is done by the system on the environment (SE) or by the environment on the system (ES): (a) opening a carbonated beverage; (b) filling a flat tire; (c) a sealed empty gas can expands on a hot day, bowing out the walls.

a. SE; b. ES; c. ES

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Problems

A gas follows p V = b p + c T on an isothermal curve, where p is the pressure, V is the volume, b is a constant, and c is a function of temperature. Show that a temperature scale under an isochoric process can be established with this gas and is identical to that of an ideal gas.

p ( V b ) = c T is the temperature scale desired and mirrors the ideal gas if under constant volume.

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A mole of gas has isobaric expansion coefficient d V / d T = R / p and isochoric pressure-temperature coefficient d p / d T = p / T . Find the equation of state of the gas.

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Find the equation of state of a solid that has an isobaric expansion coefficient d V / d T = 2 c T b p and an isothermal pressure-volume coefficient d V / d p = b T .

V b p T + c T 2 = 0

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Questions & Answers

What is differential form of Gauss's law?
Rohit Reply
help me out on this question the permittivity of diamond is 1.46*10^-10.( a)what is the dielectric of diamond (b) what its susceptibility
OLUWA Reply
a body is projected vertically upward of 30kmp/h how long will it take to reach a point 0.5km bellow e point of projection
Abu Reply
i have to say. who cares. lol. why know that t all
Jeff
is this just a chat app about the openstax book?
Lord Reply
kya ye b.sc ka hai agar haa to konsa part
MPL Reply
what is charge quantization
Mayowa Reply
it means that the total charge of a body will always be the integral multiples of basic unit charge ( e ) q = ne n : no of electrons or protons e : basic unit charge 1e = 1.602×10^-19
Riya
is the time quantized ? how ?
Mehmet
What do you meanby the statement,"Is the time quantized"
Mayowa
Can you give an explanation.
Mayowa
there are some comment on the time -quantized..
Mehmet
time is integer of the planck time, discrete..
Mehmet
planck time is travel in planck lenght of light..
Mehmet
it's says that charges does not occur in continuous form rather they are integral multiple of the elementary charge of an electron.
Tamoghna
it is just like bohr's theory. Which was angular momentum of electron is intral multiple of h/2π
Aditya
determine absolute zero
OFERE Reply
The properties of a system during a reversible constant pressure non-flow process at P= 1.6bar, changes from constant volume of 0.3m³/kg at 20°C to a volume of 0.55m³/kg at 260°C. its constant pressure process is 3.205KJ/kg°C Determine: 1. Heat added, Work done, Change in Internal Energy and Change in Enthalpy
Opeyemi Reply
U can easily calculate work done by 2.303log(v2/v1)
Abhishek
Amount of heat added through q=ncv^delta t
Abhishek
Change in internal energy through q=Q-w
Abhishek
please how do dey get 5/9 in the conversion of Celsius and Fahrenheit
Gwam Reply
what is copper loss
timileyin Reply
this is the energy dissipated(usually in the form of heat energy) in conductors such as wires and coils due to the flow of current against the resistance of the material used in winding the coil.
Henry
it is the work done in moving a charge to a point from infinity against electric field
Ashok Reply
what is the weight of the earth in space
peterpaul Reply
As w=mg where m is mass and g is gravitational force... Now if we consider the earth is in gravitational pull of sun we have to use the value of "g" of sun, so we can find the weight of eaeth in sun with reference to sun...
Prince
g is not gravitacional forcé, is acceleration of gravity of earth and is assumed constante. the "sun g" can not be constant and you should use Newton gravity forcé. by the way its not the "weight" the physical quantity that matters, is the mass
Jorge
Yeah got it... Earth and moon have specific value of g... But in case of sun ☀ it is just a huge sphere of gas...
Prince
Thats why it can't have a constant value of g ....
Prince
not true. you must know Newton gravity Law . even a cloud of gas it has mass thats al matters. and the distsnce from the center of mass of the cloud and the center of the mass of the earth
Jorge
please why is the first law of thermodynamics greater than the second
Ifeoma Reply
every law is important, but first law is conservation of energy, this state is the basic in physics, in this case first law is more important than other laws..
Mehmet
First Law describes o energy is changed from one form to another but not destroyed, but that second Law talk about entropy of a system increasing gradually
Mayowa
first law describes not destroyer energy to changed the form, but second law describes the fluid drection that is entropy. in this case first law is more basic accorging to me...
Mehmet
define electric image.obtain expression for electric intensity at any point on earthed conducting infinite plane due to a point charge Q placed at a distance D from it.
Mateshwar Reply
explain the lack of symmetry in the field of the parallel capacitor
Phoebe Reply
pls. explain the lack of symmetry in the field of the parallel capacitor
Phoebe

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Source:  OpenStax, University physics volume 2. OpenStax CNX. Oct 06, 2016 Download for free at http://cnx.org/content/col12074/1.3
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