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E int = i ( K i + U i ) ,

where the summation is over all the molecules of the system, and the bars over K and U indicate average values. The kinetic energy K i of an individual molecule includes contributions due to its rotation and vibration, as well as its translational energy m i v i 2 / 2 , where v i is the molecule’s speed measured relative to the center of mass of the system. The potential energy U i is associated only with the interactions between molecule i and the other molecules of the system. In fact, neither the system’s location nor its motion is of any consequence as far as the internal energy is concerned. The internal energy of the system is not affected by moving it from the basement to the roof of a 100-story building or by placing it on a moving train.

In an ideal monatomic gas, each molecule is a single atom. Consequently, there is no rotational or vibrational kinetic energy and K i = m i v i 2 / 2 . Furthermore, there are no interatomic interactions (collisions notwithstanding), so U i = constant , which we set to zero. The internal energy is therefore due to translational kinetic energy only and

E int = i K i = i 1 2 m i v i 2 ¯ .

From the discussion in the preceding chapter, we know that the average kinetic energy of a molecule in an ideal monatomic gas is

1 2 m i v i 2 = 3 2 k B T ,

where T is the Kelvin temperature of the gas. Consequently, the average mechanical energy per molecule of an ideal monatomic gas is also 3 k B T / 2 , that is,

K i + U i ¯ = K i = 3 2 k B T .

The internal energy is just the number of molecules multiplied by the average mechanical energy per molecule. Thus for n moles of an ideal monatomic gas,

E int = n N A ( 3 2 k B T ) = 3 2 n R T .

Notice that the internal energy of a given quantity of an ideal monatomic gas depends on just the temperature and is completely independent of the pressure and volume of the gas. For other systems, the internal energy cannot be expressed so simply. However, an increase in internal energy can often be associated with an increase in temperature.

We know from the zeroth law of thermodynamics that when two systems are placed in thermal contact, they eventually reach thermal equilibrium, at which point they are at the same temperature. As an example, suppose we mix two monatomic ideal gases. Now, the energy per molecule of an ideal monatomic gas is proportional to its temperature. Thus, when the two gases are mixed, the molecules of the hotter gas must lose energy and the molecules of the colder gas must gain energy. This continues until thermal equilibrium is reached, at which point, the temperature, and therefore the average translational kinetic energy per molecule, is the same for both gases. The approach to equilibrium for real systems is somewhat more complicated than for an ideal monatomic gas. Nevertheless, we can still say that energy is exchanged between the systems until their temperatures are the same.

Summary

  • Positive (negative) work is done by a thermodynamic system when it expands (contracts) under an external pressure.
  • Heat is the energy transferred between two objects (or two parts of a system) because of a temperature difference.
  • Internal energy of a thermodynamic system is its total mechanical energy.

Questions & Answers

What is differential form of Gauss's law?
Rohit Reply
help me out on this question the permittivity of diamond is 1.46*10^-10.( a)what is the dielectric of diamond (b) what its susceptibility
OLUWA Reply
a body is projected vertically upward of 30kmp/h how long will it take to reach a point 0.5km bellow e point of projection
Abu Reply
i have to say. who cares. lol. why know that t all
Jeff
is this just a chat app about the openstax book?
Lord Reply
kya ye b.sc ka hai agar haa to konsa part
MPL Reply
what is charge quantization
Mayowa Reply
it means that the total charge of a body will always be the integral multiples of basic unit charge ( e ) q = ne n : no of electrons or protons e : basic unit charge 1e = 1.602×10^-19
Riya
is the time quantized ? how ?
Mehmet
What do you meanby the statement,"Is the time quantized"
Mayowa
Can you give an explanation.
Mayowa
there are some comment on the time -quantized..
Mehmet
time is integer of the planck time, discrete..
Mehmet
planck time is travel in planck lenght of light..
Mehmet
it's says that charges does not occur in continuous form rather they are integral multiple of the elementary charge of an electron.
Tamoghna
it is just like bohr's theory. Which was angular momentum of electron is intral multiple of h/2π
Aditya
determine absolute zero
OFERE Reply
The properties of a system during a reversible constant pressure non-flow process at P= 1.6bar, changes from constant volume of 0.3m³/kg at 20°C to a volume of 0.55m³/kg at 260°C. its constant pressure process is 3.205KJ/kg°C Determine: 1. Heat added, Work done, Change in Internal Energy and Change in Enthalpy
Opeyemi Reply
U can easily calculate work done by 2.303log(v2/v1)
Abhishek
Amount of heat added through q=ncv^delta t
Abhishek
Change in internal energy through q=Q-w
Abhishek
please how do dey get 5/9 in the conversion of Celsius and Fahrenheit
Gwam Reply
what is copper loss
timileyin Reply
this is the energy dissipated(usually in the form of heat energy) in conductors such as wires and coils due to the flow of current against the resistance of the material used in winding the coil.
Henry
it is the work done in moving a charge to a point from infinity against electric field
Ashok Reply
what is the weight of the earth in space
peterpaul Reply
As w=mg where m is mass and g is gravitational force... Now if we consider the earth is in gravitational pull of sun we have to use the value of "g" of sun, so we can find the weight of eaeth in sun with reference to sun...
Prince
g is not gravitacional forcé, is acceleration of gravity of earth and is assumed constante. the "sun g" can not be constant and you should use Newton gravity forcé. by the way its not the "weight" the physical quantity that matters, is the mass
Jorge
Yeah got it... Earth and moon have specific value of g... But in case of sun ☀ it is just a huge sphere of gas...
Prince
Thats why it can't have a constant value of g ....
Prince
not true. you must know Newton gravity Law . even a cloud of gas it has mass thats al matters. and the distsnce from the center of mass of the cloud and the center of the mass of the earth
Jorge
please why is the first law of thermodynamics greater than the second
Ifeoma Reply
every law is important, but first law is conservation of energy, this state is the basic in physics, in this case first law is more important than other laws..
Mehmet
First Law describes o energy is changed from one form to another but not destroyed, but that second Law talk about entropy of a system increasing gradually
Mayowa
first law describes not destroyer energy to changed the form, but second law describes the fluid drection that is entropy. in this case first law is more basic accorging to me...
Mehmet
define electric image.obtain expression for electric intensity at any point on earthed conducting infinite plane due to a point charge Q placed at a distance D from it.
Mateshwar Reply
explain the lack of symmetry in the field of the parallel capacitor
Phoebe Reply
pls. explain the lack of symmetry in the field of the parallel capacitor
Phoebe
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Source:  OpenStax, University physics volume 2. OpenStax CNX. Oct 06, 2016 Download for free at http://cnx.org/content/col12074/1.3
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