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Emission and absorption spectra

Emission spectra

You have learnt previously about the structure of an atom. The electrons surrounding the atomic nucleus are arranged in a series of levels of increasing energy. Each element has its own distinct set of energy levels. This arrangement of energy levels serves as the atom's unique fingerprint.

In the early 1900s, scientists found that a liquid or solid heated to high temperatures would give off a broad range of colours of light. However, a gas heated to similar temperatures would emit light only at certain specific colours (wavelengths). The reason for this observation was not understood at the time.

Scientists studied this effect using a discharge tube.

Diagram of a discharge tube. The tube is filled with a gas. When a high enough voltage is applied across the tube, the gas ionises and acts like a conductor, allowing a current to flow through the circuit. The current excites the atoms of the ionised gas. When the atoms fall back to their ground state, they emit photons to carry off the excess energy.

A discharge tube ( [link] ) is a glass gas-filled tube with a metal plate at both ends. If a large enough voltage difference is applied between the two metal plates, the gas atoms inside the tube will absorb enough energy to make some of their electrons come off i.e. the gas atoms are ionised. These electrons start moving through the gas and create a current, which raises some electrons in other atoms to higher energy levels. Then as the electrons in the atoms fall back down, they emit electromagnetic radiation (light). The amount of light emitted at different wavelengths, called the emission spectrum , is shown for a discharge tube filled with hydrogen gas in [link] below. Only certain wavelengths (i.e. colours) of light are seen as shown by the thick black lines in the picture.

Diagram of the emission spectrum of hydrogen in the visible spectrum. Four lines are visible, and are labeled with their wavelengths. The three lines in the 400–500 nm range are in the blue part of the spectrum, while the higher line (656 nm) is in the red/orange part.

Eventually, scientists realized that these lines come from photons of a specific energy, emitted by electrons making transitions between specific energy levels of the atom. [link] shows an example of this happening. When an electron in an atom falls from a higher energy level to a lower energy level, it emits a photon to carry off the extra energy. This photon's energy is equal to the energy difference between the two energy levels. As we previously discussed, the frequency of a photon is related to its energy through the equation E = h f . Since a specific photon frequency (or wavelength) gives us a specific colour, we can see how each coloured line is associated with a specific transition.

In this diagram are shown some of the electron energy levels for the hydrogen atom. The arrows show the electron transitions from higher energy levels to lower energy levels. The energies of the emitted photons are the same as the energy difference between two energy levels. You can think of absorption as the opposite process. The arrows would point upwards and the electrons would jump up to higher levels when they absorp a photon of the right energy.

Questions & Answers

how does the earth revolute
Kevin Reply
What is the momentum
Given Reply
The product of the object's mass and it's velocity
electric field def
how is ester formed
Aubrey Reply
how is n ester formed
Alcohol reacts with a carboxylic acid
and the reaction is catalysed by sulphuric acid
an athlete with a mass of 70kg runs at a velocity of 45km . determine the athlete's momentum
Lesedi Reply
Is that a velocity or something else
45km/h i guess
Change to m/s
45km/h = 12.5 m/s p=mv =70×12.5 =875 kg.m/s
what are the measures of the rates of reaction
Lesego Reply
Volume Concentration Temperature Pressure Surface Area
the principle of superposition of waves
Sfundo Reply
what is work
Kool Reply
is this a group chat
Nobuhle Reply
Hey can y'all define newton's 2nd law
If a resultant force act on an object...the object will accelerate in the direction of a resultant force,the acceleration of the object is directly proportional to the net force and inversely proportional to the mass of the object
how do you calculate tension force
use the formula Fnet=ma if there is tension connecting two objects
to calculate Tension, usually calculate acceleration first Draw separate free body diagrams for each body. Apply Fnet = ma to calculate Tension
Hi people
how does temperature affect the equilibrium position
Blessing Reply
an increased temperature increases the average kinetic energy thus in turn increases the number of effective collisions........
so...which reaction is favored between endothermic and exothermic .when temperature is increased..?
exothermic reaction because energy is realised to the surroundings as heat and light energy ....graphical so much energy is realised as reactants to form product and because temperature is high rate of reaction is fast which means there is a successful collision
an object will continue in a state of rest unless it is acted upon an unbalanced force
Junior Reply
Newton's Law 1
First Newton's Law
Newton's first law
newton first law
Newton's first law
when pressure is increased what happen to volume
Siphelo Reply
care to explain?
if pressure is applied to a pistol , the volume will decrease and particles will collide more frequently with the wall of a container .Each time they collide with the wall they exert a force on them .More collision means more force and the pressure will increase , that Boyle's Law
Because the volume has decreased , the particle will collide more frequently with the wall of a container and each time they collide with the wall of a container they exert a force on them.More collision means more force so the pressure will increase , that Boyle's Law
what is the difference between momentum and a change in momentum?
Chavonne Reply
Change in momentum is the impulse of the object
Momentum is a vector quantity equal to the product of the mass of the particle and its velocity
How to name a branched molecule from right or left?
Vadin Reply
What's Free Fall
Senzo Reply
Free Fall means there is no acting force on that object.
only gravitational force
no external force acting on an object
by only force of gravite
but gravitational force
a motion in which the only force acting is gravitational force
and an object experiencing free fall is referred as a projectile
Do polymers form restrictedly only if compound is saturated, only?
milani Reply

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Source:  OpenStax, Siyavula textbooks: grade 12 physical science. OpenStax CNX. Aug 03, 2011 Download for free at http://cnx.org/content/col11244/1.2
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