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Introduction

All chemical reactions involve energy changes. In some reactions, we are able to observe these energy changes as either an increase or a decrease in the overall energy of the system.

What causes the energy changes in chemical reactions?

When a chemical reaction occurs, bonds in the reactants break , while new bonds form in the product. The following example may help to explain this. Hydrogen reacts with oxygen to form water, according to the following equation:

2 H 2 + O 2 2 H 2 O

In this reaction, the bond between the two hydrogen atoms in the H 2 molecule will break , as will the bond between the oxygen atoms in the O 2 molecule. New bonds will form between the two hydrogen atoms and the single oxygen atom in the water molecule that is formed as the product.

For bonds to break , energy must be absorbed . When new bonds form , energy is released . The energy that is needed to break a bond is called the bond energy or bond dissociation energy . Bond energies are measured in units of kJ.mol - 1 .

Bond energy

Bond energy is a measure of bond strength in a chemical bond. It is the amount of energy (in kJ.mol - 1 ) that is needed to break the chemical bond between two atoms.

Exothermic and endothermic reactions

In some reactions, the energy that must be absorbed to break the bonds in the reactants, is less than the total energy that is released when new bonds are formed. This means that in the overall reaction, energy is released as either heat or light. This type of reaction is called an exothermic reaction. Another way of describing an exothermic reaction is that it is one in which the energy of the product is less than the energy of the reactants, because energy has been released during the reaction. We can represent this using the following general formula:

Reactants Product + Energy

Exothermic reaction

An exothermic reaction is one that releases energy in the form of heat or light.

In other reactions,the energy that must be absorbed to break the bonds in the reactants, is more than the total energy that is released when new bonds are formed. This means that in the overall reaction, energy must be absorbed from the surroundings. This type of reaction is known as an endothermic reaction. Another way of describing an endothermic reaction is that it is one in which the energy of the product is greater than the energy of the reactants, because energy has been absorbed during the reaction. This can be represented by the following formula:

Reactants + Energy Product

Endothermic reaction

An endothermic reaction is one that absorbs energy in the form of heat or light.

The difference in energy (E) between the reactants and the products is known as the heat of the reaction . It is also sometimes referred to as the enthalpy change of the system.

Demonstration : endothermic and exothermic reactions 1

Apparatus and materials:

You will need citric acid, sodium bicarbonate, a glass beaker, the lid of an ice-cream container, thermometer, glass stirring rod and a pair of scissors. Note that citric acid is found in citrus fruits such as lemons. Sodium bicarbonate is actually bicarbonate of soda (baking soda), the baking ingredient that helps cakes to rise.

Questions & Answers

what is the formula for calculating tension
Kagiso Reply
You can use simultaneous equations or T=mg+ma
sibahle
- Which formula can you use if you want to calculate acceleration?
Pretty
to calculate acceleration you use formula Vf -Vi divided by the time (t)
sholan
What is the formula of calculating tension
sibahle Reply
I don't think there's a formula u just have to use all information in that type of situation
Gwebzi
can a mixture of atoms make a molecule
Keamogetse Reply
define the term "resultant"
Austin Reply
the sum of all the forces acting on an object
Think
carring out an investigation of the relationship of acceleration and net force with mass kept constant
Ronald
how to calculate coefficient of kinetic force
Bhereza Reply
kinetic friction × Normal force
Murunwa
how to get a valency electron
Really Reply
how to calculate acceleration due to gravity
Mpho Reply
how to calculate inertia and it's definition
sibahle Reply
how to draw a box of tall the force that act on the box mass is 5 .00 and lies a ramp with 30°
Thando Reply
how to determine Gravitational acceleration
Raman Reply
what is a force
Edith Reply
A force is a pull or push action that affects the shape, motion and direction of an object
Chauke
the different types of friction forces
Bhereza
different types of frictional forces are static frictional force(the object is stationery)and kinetic frictional force(the object is moving)
Raymond
static
Dineo
what is a vector
Nosihle Reply
a vector is a physical quantity that have both magnitude and direction
Edith
how to calculate the magnitude and direction if, P=500N,10°,Q=200N,30°,R=300N,60°
Asavela Reply
Describe relationship between the net force exerted on an object and acceleration of the object in words
Motshidisi Reply
Newton's second law of motion states that the acceleration of an object is equal to the net force exerted on the objectdivided by the object's mass. The direction of acceleration is the same as the direction of thenet force.
Sebastian
what is close vector diagram
Lebogang
can you describe the relationship between the netf exterted on an object and A of the object for me plz
Lebogang
the are directly proportional When one increase the other will roo
Gwebzi
too
Gwebzi
and the mass is inversely proportional
Murunwa
what is an intermolecular
Senzo Reply
is the forces that act in the molecules
Lebogang

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Source:  OpenStax, Siyavula textbooks: grade 11 physical science. OpenStax CNX. Jul 29, 2011 Download for free at http://cnx.org/content/col11241/1.2
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