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Introduction

All chemical reactions involve energy changes. In some reactions, we are able to observe these energy changes as either an increase or a decrease in the overall energy of the system.

What causes the energy changes in chemical reactions?

When a chemical reaction occurs, bonds in the reactants break , while new bonds form in the product. The following example may help to explain this. Hydrogen reacts with oxygen to form water, according to the following equation:

2 H 2 + O 2 2 H 2 O

In this reaction, the bond between the two hydrogen atoms in the H 2 molecule will break , as will the bond between the oxygen atoms in the O 2 molecule. New bonds will form between the two hydrogen atoms and the single oxygen atom in the water molecule that is formed as the product.

For bonds to break , energy must be absorbed . When new bonds form , energy is released . The energy that is needed to break a bond is called the bond energy or bond dissociation energy . Bond energies are measured in units of kJ.mol - 1 .

Bond energy

Bond energy is a measure of bond strength in a chemical bond. It is the amount of energy (in kJ.mol - 1 ) that is needed to break the chemical bond between two atoms.

Exothermic and endothermic reactions

In some reactions, the energy that must be absorbed to break the bonds in the reactants, is less than the total energy that is released when new bonds are formed. This means that in the overall reaction, energy is released as either heat or light. This type of reaction is called an exothermic reaction. Another way of describing an exothermic reaction is that it is one in which the energy of the product is less than the energy of the reactants, because energy has been released during the reaction. We can represent this using the following general formula:

Reactants Product + Energy

Exothermic reaction

An exothermic reaction is one that releases energy in the form of heat or light.

In other reactions,the energy that must be absorbed to break the bonds in the reactants, is more than the total energy that is released when new bonds are formed. This means that in the overall reaction, energy must be absorbed from the surroundings. This type of reaction is known as an endothermic reaction. Another way of describing an endothermic reaction is that it is one in which the energy of the product is greater than the energy of the reactants, because energy has been absorbed during the reaction. This can be represented by the following formula:

Reactants + Energy Product

Endothermic reaction

An endothermic reaction is one that absorbs energy in the form of heat or light.

The difference in energy (E) between the reactants and the products is known as the heat of the reaction . It is also sometimes referred to as the enthalpy change of the system.

Demonstration : endothermic and exothermic reactions 1

Apparatus and materials:

You will need citric acid, sodium bicarbonate, a glass beaker, the lid of an ice-cream container, thermometer, glass stirring rod and a pair of scissors. Note that citric acid is found in citrus fruits such as lemons. Sodium bicarbonate is actually bicarbonate of soda (baking soda), the baking ingredient that helps cakes to rise.

Questions & Answers

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sakhumzi Reply
state Faraday's law in word
Emkay Reply
which rules do you have to follow to identify oxidation numbers
sessy Reply
Why do vectors have arrows?
vanessa Reply
vector quantity has both direction and magnitude so arrows illustrate the direction of the vector
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how to calculate net electric field at a point
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what are controlled variables
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Independent variables in an experiment which influence the outcome results
Boss
Such as temperature when dealing with ohms law
Boss
variables whose amount is determined by the person doing the experiment
Clemencia
how to calculate exodation number
Cphiwe Reply
Calculate relative atomic mass
Lindo Reply
what is chemical bonding?
Lefa Reply
Chemical Bonding is a mutual attraction between two atoms resulting from the simultaneous attraction between their nuclei and the outer elections
Sydney
How would you go about finding the resistance of an unknown resistor using only power supply, a voltmeter and a known resistance
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who is the scientist who discovered electromagnetism
Zivele Reply
what happens to the galvanometer when the switch is closed ?
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hey
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@zivele in your products the element with an oxidation number less than 0 is a reducing and the one with an oxidation number greater than 0 is oxidising
sessy
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Vihanga Reply
Formula for concentration
Kabelo Reply
c=m/MV
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Source:  OpenStax, Siyavula textbooks: grade 11 physical science. OpenStax CNX. Jul 29, 2011 Download for free at http://cnx.org/content/col11241/1.2
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