<< Chapter < Page Chapter >> Page >

Making connections: take-home experiment—refrigerating a balloon

Inflate a balloon at room temperature. Leave the inflated balloon in the refrigerator overnight. What happens to the balloon, and why?

Calculating the number of molecules in a cubic meter of gas

How many molecules are in a typical object, such as gas in a tire or water in a drink? We can use the ideal gas law to give us an idea of how large N size 12{N} {} typically is.

Calculate the number of molecules in a cubic meter of gas at standard temperature and pressure (STP), which is defined to be 0 º C size 12{0°C} {} and atmospheric pressure.

Strategy

Because pressure, volume, and temperature are all specified, we can use the ideal gas law PV = NkT size 12{ ital "PV"= ital "NkT"} {} , to find N size 12{N} {} .

Solution

1. Identify the knowns.

T = 0 º C = 273 K P = 1 . 01 × 10 5 Pa V = 1 . 00 m 3 k = 1 . 38 × 10 23 J/K

2. Identify the unknown: number of molecules, N size 12{N} {} .

3. Rearrange the ideal gas law to solve for N size 12{N} {} .

PV = NkT N = PV kT alignl { stack { size 12{ ital "PV"= ital "NkT"} {} #size 12{N= { { ital "PV"} over { ital "kT"} } } {} } } {}

4. Substitute the known values into the equation and solve for N size 12{N} {} .

N = PV kT = 1 . 01 × 10 5 Pa 1 . 00 m 3 1 . 38 × 10 23 J/K 273 K = 2 . 68 × 10 25 molecules size 12{N= { { ital "PV"} over { ital "kT"} } = { { left (1 "." "01" times "10" rSup { size 8{5} } " Pa" right ) left (1 "." "00 m" rSup { size 8{3} } right )} over { left (1 "." "38" times "10" rSup { size 8{ - "23"} } " J/K" right ) left ("273 K" right )} } =2 "." "68" times "10" rSup { size 8{"25"} } `"molecules"} {}

Discussion

This number is undeniably large, considering that a gas is mostly empty space. N size 12{N} {} is huge, even in small volumes. For example, 1 cm 3 size 12{1" cm" rSup { size 8{3} } } {} of a gas at STP has 2 . 68 × 10 19 size 12{2 "." "68"´"10" rSup { size 8{"19"} } } {} molecules in it. Once again, note that N size 12{N} {} is the same for all types or mixtures of gases.

Got questions? Get instant answers now!

Moles and avogadro’s number

It is sometimes convenient to work with a unit other than molecules when measuring the amount of substance. A mole    (abbreviated mol) is defined to be the amount of a substance that contains as many atoms or molecules as there are atoms in exactly 12 grams (0.012 kg) of carbon-12. The actual number of atoms or molecules in one mole is called Avogadro’s number     ( N A ) size 12{ \( N rSub { size 8{A} } \) } {} , in recognition of Italian scientist Amedeo Avogadro (1776–1856). He developed the concept of the mole, based on the hypothesis that equal volumes of gas, at the same pressure and temperature, contain equal numbers of molecules. That is, the number is independent of the type of gas. This hypothesis has been confirmed, and the value of Avogadro’s number is

N A = 6 . 02 × 10 23 mol 1 . size 12{N rSub { size 8{A} } =6 "." "02" times "10" rSup { size 8{"23"} } `"mol" rSup { size 8{ - 1} } "." } {}

Avogadro’s number

One mole always contains 6 . 02 × 10 23 size 12{6 "." "02"´"10" rSup { size 8{"23"} } } {} particles (atoms or molecules), independent of the element or substance. A mole of any substance has a mass in grams equal to its molecular mass, which can be calculated from the atomic masses given in the periodic table of elements.

N A = 6 . 02 × 10 23 mol 1 size 12{N rSub { size 8{A} } =6 "." "02" times "10" rSup { size 8{"23"} } `"mol" rSup { size 8{ - 1} } } {}
The illustration shows relatively flat land with a solitary mountain, labeled Mt. Everest, and blue sky above. A double-headed vertical arrow stretches between the land and a point in the sky that is well above the peak of the mountain. The arrow, labeled table tennis balls, serves to indicate that a column of one mole of table tennis balls would reach a point in the sky that is much higher than the peak of Mt. Everest.
How big is a mole? On a macroscopic level, one mole of table tennis balls would cover the Earth to a depth of about 40 km.

The active ingredient in a Tylenol pill is 325 mg of acetaminophen ( C 8 H 9 NO 2 ) size 12{ \( C rSub { size 8{8} } H rSub { size 8{9} } "NO" rSub { size 8{2} } \) } {} . Find the number of active molecules of acetaminophen in a single pill.

We first need to calculate the molar mass (the mass of one mole) of acetaminophen. To do this, we need to multiply the number of atoms of each element by the element’s atomic mass.

( 8 moles of carbon ) ( 12 grams/mole ) + ( 9 moles hydrogen ) ( 1 gram/mole ) + ( 1 mole nitrogen ) ( 14 grams/mole ) + ( 2 moles oxygen ) ( 16 grams/mole ) = 151 g

Then we need to calculate the number of moles in 325 mg.

325 mg 151 grams/mole 1 gram 1000 mg = 2.15 × 10 3 moles

Then use Avogadro’s number to calculate the number of molecules.

N = 2.15 × 10 3 moles 6.02 × 10 23 molecules/mole = 1.30 × 10 21 molecules size 12{N= left (2 "." "15" times "10" rSup { size 8{ - 3} } `"moles" right ) left (6 "." "02" times "10" rSup { size 8{"23"} } `"molecules/mole" right )=1 "." "30" times "10" rSup { size 8{"21"} } `"molecules"} {}
Got questions? Get instant answers now!

Questions & Answers

summarize halerambos & holbon
David Reply
the Three stages of Auguste Comte
Clementina Reply
what are agents of socialization
Antonio Reply
sociology of education
Nuhu Reply
definition of sociology of education
Nuhu
what is culture
Abdulrahim Reply
shared beliefs, values, and practices
AI-Robot
What are the two type of scientific method
ogunniran Reply
I'm willing to join you
Aceng Reply
what are the scientific method of sociology
Man
what is socialization
ogunniran Reply
the process wherein people come to understand societal norms and expectations, to accept society's beliefs, and to be aware of societal values
AI-Robot
scientific method in doing research
ogunniran
defimition of sickness in afica
Anita
Cosmology
ogunniran
Hmmm
ogunniran
list and explain the terms that found in society
REMMY Reply
list and explain the terms that found in society
Mukhtar
what are the agents of socialization
Antonio
Family Peer group Institution
Abdulwajud
I mean the definition
Antonio
ways of perceived deviance indifferent society
Naomi Reply
reasons of joining groups
SAM
to bring development to the nation at large
Hyellafiya
entails of consultative and consensus building from others
Gadama
World first Sociologist?
Abu
What is evolutionary model
Muhammad Reply
Evolution models refer to mathematical and computational representations of the processes involved in biological evolution. These models aim to simulate and understand how species change over time through mechanisms such as natural selection, genetic drift, and mutation. Evolutionary models can be u
faruk
what are the modern trends in religious behaviours
Selekeye Reply
what are social norms
Daniel Reply
shared standards of acceptable behavior by the group or appropriate behavior in a particular institution or those behaviors that are acceptable in a society
Lucius
that is how i understood it
Lucius
examples of societal norms
Diamond
Discuss the characteristics of the research located within positivist and the interpretivist paradigm
Tariro Reply
what is Industrialisation
Selekeye Reply
industrialization
Angelo
Got questions? Join the online conversation and get instant answers!
Jobilize.com Reply
Practice Key Terms 4

Get Jobilize Job Search Mobile App in your pocket Now!

Get it on Google Play Download on the App Store Now




Source:  OpenStax, College physics. OpenStax CNX. Jul 27, 2015 Download for free at http://legacy.cnx.org/content/col11406/1.9
Google Play and the Google Play logo are trademarks of Google Inc.

Notification Switch

Would you like to follow the 'College physics' conversation and receive update notifications?

Ask