30.5 Applications of atomic excitations and de-excitations

Many properties of matter and phenomena in nature are directly related to atomic energy levels and their associated excitations and de-excitations. The color of a rose, the output of a laser, and the transparency of air are but a few examples. (See [link] .) While it may not appear that glow-in-the-dark pajamas and lasers have much in common, they are in fact different applications of similar atomic de-excitations.

The color of a material is due to the ability of its atoms to absorb certain wavelengths while reflecting or reemitting others. A simple red material, for example a tomato, absorbs all visible wavelengths except red. This is because the atoms of its hydrocarbon pigment (lycopene) have levels separated by a variety of energies corresponding to all visible photon energies except red. Air is another interesting example. It is transparent to visible light, because there are few energy levels that visible photons can excite in air molecules and atoms. Visible light, thus, cannot be absorbed. Furthermore, visible light is only weakly scattered by air, because visible wavelengths are so much greater than the sizes of the air molecules and atoms. Light must pass through kilometers of air to scatter enough to cause red sunsets and blue skies.

Fluorescence and phosphorescence

The ability of a material to emit various wavelengths of light is similarly related to its atomic energy levels. [link] shows a scorpion illuminated by a UV lamp, sometimes called a black light. Some rocks also glow in black light, the particular colors being a function of the rock’s mineral composition. Black lights are also used to make certain posters glow.

In the fluorescence process, an atom is excited to a level several steps above its ground state by the absorption of a relatively high-energy UV photon. This is called atomic excitation    . Once it is excited, the atom can de-excite in several ways, one of which is to re-emit a photon of the same energy as excited it, a single step back to the ground state. This is called atomic de-excitation    . All other paths of de-excitation involve smaller steps, in which lower-energy (longer wavelength) photons are emitted. Some of these may be in the visible range, such as for the scorpion in [link] . Fluorescence is defined to be any process in which an atom or molecule, excited by a photon of a given energy, and de-excites by emission of a lower-energy photon.