# 13.5 Phase changes  (Page 2/15)

 Page 2 / 15
Critical temperatures and pressures
Substance Critical temperature Critical pressure
$\text{K}$ $\text{º}\text{C}$ $\text{Pa}$ $\text{atm}$
Water 647.4 374.3 $\text{22}\text{.}\text{12}×{\text{10}}^{6}$ 219.0
Sulfur dioxide 430.7 157.6 $7\text{.}\text{88}×{\text{10}}^{6}$ 78.0
Ammonia 405.5 132.4 $\text{11}\text{.}\text{28}×{\text{10}}^{6}$ 111.7
Carbon dioxide 304.2 31.1 $7\text{.}\text{39}×{\text{10}}^{6}$ 73.2
Oxygen 154.8 −118.4 $5\text{.}\text{08}×{\text{10}}^{6}$ 50.3
Nitrogen 126.2 −146.9 $3\text{.}\text{39}×{\text{10}}^{6}$ 33.6
Hydrogen 33.3 −239.9 $1\text{.}\text{30}×{\text{10}}^{6}$ 12.9
Helium 5.3 −267.9 $0\text{.}\text{229}×{\text{10}}^{6}$ 2.27

## Phase diagrams

The plots of pressure versus temperatures provide considerable insight into thermal properties of substances. There are well-defined regions on these graphs that correspond to various phases of matter, so $\text{PT}$ graphs are called phase diagrams . [link] shows the phase diagram for water. Using the graph, if you know the pressure and temperature you can determine the phase of water. The solid lines—boundaries between phases—indicate temperatures and pressures at which the phases coexist (that is, they exist together in ratios, depending on pressure and temperature). For example, the boiling point of water is $\text{100}\text{º}\text{C}$ at 1.00 atm. As the pressure increases, the boiling temperature rises steadily to $\text{374}\text{º}\text{C}$ at a pressure of 218 atm. A pressure cooker (or even a covered pot) will cook food faster because the water can exist as a liquid at temperatures greater than $\text{100}\text{º}\text{C}$ without all boiling away. The curve ends at a point called the critical point , because at higher temperatures the liquid phase does not exist at any pressure. The critical point occurs at the critical temperature, as you can see for water from [link] . The critical temperature for oxygen is $–\text{118}\text{º}\text{C}$ , so oxygen cannot be liquefied above this temperature.

Similarly, the curve between the solid and liquid regions in [link] gives the melting temperature at various pressures. For example, the melting point is $0\text{º}\text{C}$ at 1.00 atm, as expected. Note that, at a fixed temperature, you can change the phase from solid (ice) to liquid (water) by increasing the pressure. Ice melts from pressure in the hands of a snowball maker. From the phase diagram, we can also say that the melting temperature of ice rises with increased pressure. When a car is driven over snow, the increased pressure from the tires melts the snowflakes; afterwards the water refreezes and forms an ice layer.

At sufficiently low pressures there is no liquid phase, but the substance can exist as either gas or solid. For water, there is no liquid phase at pressures below 0.00600 atm. The phase change from solid to gas is called sublimation    . It accounts for large losses of snow pack that never make it into a river, the routine automatic defrosting of a freezer, and the freeze-drying process applied to many foods. Carbon dioxide, on the other hand, sublimates at standard atmospheric pressure of 1 atm. (The solid form of ${\text{CO}}_{2}$ is known as dry ice because it does not melt. Instead, it moves directly from the solid to the gas state.)

a thick glass cup cracks when hot liquid is poured into it suddenly
because of the sudden contraction that takes place.
Eklu
railway crack has gap between the end of each length because?
For expansion
Eklu
yes
Aiyelabegan
Please i really find it dificult solving equations on physic, can anyone help me out?
sure
Carlee
what is the equation?
Carlee
Sure
Precious
fersnels biprism spectrometer how to determined
how to study the hall effect to calculate the hall effect coefficient of the given semiconductor have to calculate the carrier density by carrier mobility.
Bala
what is the difference between atomic physics and momentum
find the dimensional equation of work,power,and moment of a force show work?
What's sup guys
Peter
cul and you all
Okeh
cool you bro
Nana
so what is going on here
Nana
hello peeps
Joseph
Michelson Morley experiment
how are you
Naveed
am good
Celine
you
Celine
hi
Bala
Hi
Ahmed
Calculate the final velocity attained, when a ball is given a velocity of 2.5m/s, acceleration of 0.67m/s² and reaches its point in 10s. Good luck!!!
2.68m/s
Doc
vf=vi+at vf=2.5+ 0.67*10 vf= 2.5 + 6.7 vf = 9.2
babar
s = vi t +1/2at sq s=58.5 s=v av X t vf= 9.2
babar
how 2.68
babar
v=u+at where v=final velocity u=initial velocity a=acceleration t=time
Eklu
OBERT
my project is Sol gel process how to prepare this process pls tell me
Bala
the dimension of work and energy is ML2T2 find the unit of work and energy hence drive for work?
KgM2S2
Acquah
Two bodies P and Quarter each of mass 1000g. Moved in the same direction with speed of 10m/s and 20m/s respectively. Calculate the impulse of P and Q obeying newton's 3rd law of motion
kk
Doc
the answer is 0.03n according to the 3rd law of motion if the are in same direction meaning they interact each other.
OBERT
definition for wave?
A disturbance that travel from one medium to another and without causing permanent change to its displacement
Fagbenro
In physics, a wave is a disturbance that transfers energy through matter or space, with little or no associated mass transport (Mass transfer). ... There are two main types ofwaves: mechanical and electromagnetic. Mechanicalwaves propagate through a physical matter, whose substance is being deformed
Devansh
K
Manyo
thanks jare
Doc
Thanks
Note: LINEAR MOMENTUM Linear momentum is defined as the product of a system’s mass multiplied by its velocity: size 12{p=mv} {}
what is physic
zalmia
Study of matter and energy
Fagbenro
physics is the science of matter and energy and their interactions
Acquah
physics is the technology behind air and matter
Doc
Okay
William
hi sir
Bala
how easy to understanding physics sir
Bala
Easy to learn
William
31. Calculate the initial (from rest) acceleration of a proton in a 5.00×106 N/C electric field (such as created by a research Van de Graaff). Explicitly show how you follow the steps in the Problem-Solving Strategy for electrostatics.
A tennis ball is projected at an angle and attains a range of 78. if the velocity is 30metres per second, calculate the angle
Shimolla
what friction
question on friction
Wisdom
the rubbing of one object or surface against another.
author
momentum is the product of mass and it's velocity.
Algayawi
what are bioelements?
Edina
Friction is a force that exist between two objects in contact. e.g. friction between road and car tires.
Eklu