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[link] is a schematic representation of the two fundamental parts of any voltage source. The emf (represented by a script E in the figure) and internal resistance r size 12{r} {} are in series. The smaller the internal resistance for a given emf, the more current and the more power the source can supply.

This diagram shows a battery with a schematic indicating the e m f, represented by script E, and the internal resistance r of the battery. The voltage output of the battery is measured between the input and output terminals and is equal to the e m f minus the product of the current and the internal resistance.
Any voltage source (in this case, a carbon-zinc dry cell) has an emf related to its source of potential difference, and an internal resistance r size 12{r} {} related to its construction. (Note that the script E stands for emf.). Also shown are the output terminals across which the terminal voltage V size 12{V} {} is measured. Since V = emf Ir size 12{V="emf" - ital "Ir"} {} , terminal voltage equals emf only if there is no current flowing.

The internal resistance r size 12{r} {} can behave in complex ways. As noted, r size 12{r} {} increases as a battery is depleted. But internal resistance may also depend on the magnitude and direction of the current through a voltage source, its temperature, and even its history. The internal resistance of rechargeable nickel-cadmium cells, for example, depends on how many times and how deeply they have been depleted.

Things great and small: the submicroscopic origin of battery potential

Various types of batteries are available, with emfs determined by the combination of chemicals involved. We can view this as a molecular reaction (what much of chemistry is about) that separates charge.

The lead-acid battery used in cars and other vehicles is one of the most common types. A single cell (one of six) of this battery is seen in [link] . The cathode (positive) terminal of the cell is connected to a lead oxide plate, while the anode (negative) terminal is connected to a lead plate. Both plates are immersed in sulfuric acid, the electrolyte for the system.

A simplified view of a battery shows a rectangular container of sulfuric acid with two thin upright metal plates immersed in it, one made of lead and the other made of lead oxide. Each plate projects above the liquid line, providing a positive or negative terminal above the battery. The positive terminal is labeled as the cathode, and the negative terminal is labeled as the anode.
Artist’s conception of a lead-acid cell. Chemical reactions in a lead-acid cell separate charge, sending negative charge to the anode, which is connected to the lead plates. The lead oxide plates are connected to the positive or cathode terminal of the cell. Sulfuric acid conducts the charge as well as participating in the chemical reaction.

The details of the chemical reaction are left to the reader to pursue in a chemistry text, but their results at the molecular level help explain the potential created by the battery. [link] shows the result of a single chemical reaction. Two electrons are placed on the anode, making it negative, provided that the cathode supplied two electrons. This leaves the cathode positively charged, because it has lost two electrons. In short, a separation of charge has been driven by a chemical reaction.

Note that the reaction will not take place unless there is a complete circuit to allow two electrons to be supplied to the cathode. Under many circumstances, these electrons come from the anode, flow through a resistance, and return to the cathode. Note also that since the chemical reactions involve substances with resistance, it is not possible to create the emf without an internal resistance.

The diagram shows a simplified view of a battery depicting a rectangular container containing two thin upright metal plates immersed in a liquid. An enlarged view of the metal plates is also shown. One plate has positive charges on it shown as small spheres enclosing a positive sign. The other plate has negative charge on it shown as small spheres enclosing an electron. The electrons are shown to move from the positive plate to the negative plate using arrows through a molecular reaction in the liquid.
Artist’s conception of two electrons being forced onto the anode of a cell and two electrons being removed from the cathode of the cell. The chemical reaction in a lead-acid battery places two electrons on the anode and removes two from the cathode. It requires a closed circuit to proceed, since the two electrons must be supplied to the cathode.

Questions & Answers

draw magnetic field pattern for two wire carrying current in the same direction
Ven Reply
An American traveler in New Zealand carries a transformer to convert New Zealand’s standard 240 V to 120 V so that she can use some small appliances on her trip.
nkombo Reply
What is the ratio of turns in the primary and secondary coils of her transformer?
nkombo
How electric lines and equipotential surface are mutually perpendicular?
Abid Reply
The potential difference between any two points on the surface is zero that implies È.Ŕ=0, Where R is the distance between two different points &E= Electric field intensity. From which we have cos þ =0, where þ is the angle between the directions of field and distance line, as E andR are zero. Thus
MAHADEV
sorry..E and R are non zero...
MAHADEV
By how much leeway (both percentage and mass) would you have in the selection of the mass of the object in the previous problem if you did not wish the new period to be greater than 2.01 s or less than 1.99 s?
Elene Reply
what Is linear momentum
Victoria Reply
why no diagrams
Blessing Reply
where
Fayyaz
Myanmar
Pyae
hi
Iroko
hello
Abdu
Describe an experiment to determine short half life
Tyson Reply
what is science
Kenedy Reply
it's a natural phenomena
Hassan
sap
Emmanuel
please can someone help me with explanations of wave
Benedine
A 20MH coil has a resistance of 50 ohms and us connected in series with a capacitor to a 520MV supply
Musa Reply
what is physics
Caya Reply
it is the science which we used in our daily life
Sujitha
Physics is the branch of science that deals with the study of matter and the interactions it undergoes with energy
Junior
it is branch of science which deals with study of happening in the human life
AMIT
A 20MH coil has a resistance of 50 ohms and is connected in series with a capacitor to a 250MV supply if the circuit is to resonate at 100KHZ, Determine 1: the capacitance of the capacitor 2: the working voltage of the circuit, given that pie =3.142
Musa
Physics is the branch of science that deals with the study of matter and the interactions it undergoes with energy
Kelly
Heat is transfered by thermal contact but if it is transfered by conduction or radiation, is it possible to reach in thermal equilibrium?
Eden Reply
Yes, It is possible by conduction if Surface is Adiabatic
Astronomy
Yeah true ilwith d help of Adiabatic
Kelly
what are the fundamentals qualities
Magret Reply
what is physic3
Kalilu
what is physic
Kalilu
Physics? Is a branch of science dealing with matter in relation to energy.
Moses
Physic... Is a purging medicine, which stimulates evacuation of the bowels.
Moses
are you asking for qualities or quantities?
Noman
give examples of three dimensional frame of reference
Ekwunazor Reply
Universe
Noman
Yes the Universe itself
Astronomy
Examine different types of shoes, including sports shoes and thongs. In terms of physics, why are the bottom surfaces designed as they are? What differences will dry and wet conditions make for these surfaces?
Lathan Reply
sports shoes are designed in such a way they are gripped well with your feet and their bases have and high friction surfaces, Thong shoes are for comfort, these are easily removed and light weight. these are usually low friction surfaces but in wet conditions they offer greater friction.
Noman
thong sleepers are usually used in restrooms.
Noman
what is wave
Ochigbo Reply
The phenomenon of transfer of energy
Noman
Practice Key Terms 4

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Source:  OpenStax, College physics. OpenStax CNX. Jul 27, 2015 Download for free at http://legacy.cnx.org/content/col11406/1.9
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