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The ideal gas law can be considered to be another manifestation of the law of conservation of energy (see Conservation of Energy ). Work done on a gas results in an increase in its energy, increasing pressure and/or temperature, or decreasing volume. This increased energy can also be viewed as increased internal kinetic energy, given the gas’s atoms and molecules.

The ideal gas law and energy

Let us now examine the role of energy in the behavior of gases. When you inflate a bike tire by hand, you do work by repeatedly exerting a force through a distance. This energy goes into increasing the pressure of air inside the tire and increasing the temperature of the pump and the air.

The ideal gas law is closely related to energy: the units on both sides are joules. The right-hand side of the ideal gas law in PV = NkT size 12{ ital "PV"= ital "NkT"} {} is NkT size 12{ ital "NkT"} {} . This term is roughly the amount of translational kinetic energy of N size 12{N} {} atoms or molecules at an absolute temperature T size 12{T} {} , as we shall see formally in Kinetic Theory: Atomic and Molecular Explanation of Pressure and Temperature . The left-hand side of the ideal gas law is PV size 12{ ital "PV"} {} , which also has the units of joules. We know from our study of fluids that pressure is one type of potential energy per unit volume, so pressure multiplied by volume is energy. The important point is that there is energy in a gas related to both its pressure and its volume. The energy can be changed when the gas is doing work as it expands—something we explore in Heat and Heat Transfer Methods —similar to what occurs in gasoline or steam engines and turbines.

Problem-solving strategy: the ideal gas law

Step 1 Examine the situation to determine that an ideal gas is involved. Most gases are nearly ideal.

Step 2 Make a list of what quantities are given, or can be inferred from the problem as stated (identify the known quantities). Convert known values into proper SI units (K for temperature, Pa for pressure, m 3 size 12{m rSup { size 8{3} } } {} for volume, molecules for N size 12{N} {} , and moles for n size 12{n} {} ).

Step 3 Identify exactly what needs to be determined in the problem (identify the unknown quantities). A written list is useful.

Step 4 Determine whether the number of molecules or the number of moles is known, in order to decide which form of the ideal gas law to use. The first form is PV = NkT size 12{ ital "PV"= ital "NkT"} {} and involves N size 12{N} {} , the number of atoms or molecules. The second form is PV = nRT size 12{ ital "PV"= ital "nRT"} {} and involves n size 12{n} {} , the number of moles.

Step 5 Solve the ideal gas law for the quantity to be determined (the unknown quantity). You may need to take a ratio of final states to initial states to eliminate the unknown quantities that are kept fixed.

Step 6 Substitute the known quantities, along with their units, into the appropriate equation, and obtain numerical solutions complete with units. Be certain to use absolute temperature and absolute pressure.

Step 7 Check the answer to see if it is reasonable: Does it make sense?

Liquids and solids have densities about 1000 times greater than gases. Explain how this implies that the distances between atoms and molecules in gases are about 10 times greater than the size of their atoms and molecules.

Atoms and molecules are close together in solids and liquids. In gases they are separated by empty space. Thus gases have lower densities than liquids and solids. Density is mass per unit volume, and volume is related to the size of a body (such as a sphere) cubed. So if the distance between atoms and molecules increases by a factor of 10, then the volume occupied increases by a factor of 1000, and the density decreases by a factor of 1000.

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Questions & Answers

Pls guys am having problem on these topics: latent heat of fusion, specific heat capacity and the sub topics under them.Pls who can help?
hamidat Reply
Thanks George,I appreciate.
hamidat
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Abolarin
Most especially it is the calculatory aspects that is giving me issue, but with these new strength that you guys have given me,I will put in my best to understand it again.
hamidat
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Abolarin
the distance between two suasive crests of water wave traveling of 3.6ms1 is 0.45m calculate the frequency of the wave
Idris Reply
v=f×lemda where the velocity is given and lends also given so simply u can calculate the frequency
Abdul
You are right my brother, make frequency the subject of formula and equate the values of velocity and lamda into the equation, that all.
hamidat
lExplain what happens to the energy carried by light that it is dimmed by passing it through two crossed polarizing filters.
Christoper Reply
When light is reflected at Brewster's angle from a smooth surface, it is 100% polarizedparallel to the surface. Part of the light will be refracted into the surface.
Ekram
What is specific heat capacity?
hamidat Reply
Specific heat capacity is the amount of heat required to raise the temperature of one (Kg) of a substance through one Kelvin
Paluutar
formula for measuring Joules
Rowshan Reply
I don't understand, do you mean the S.I unit of work and energy?
hamidat
what are the effects of electric current
ADAMS Reply
What limits the Magnification of an optical instrument?
Naeem Reply
Lithography is 2 micron
Venkateshwarlu
what is expression for energy possessed by water ripple
Prabesh Reply
what is hydrolic press
Mark Reply
An hydraulic press is a type of machine that is operated by different pressure of water on pistons.
hamidat
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Patrock Reply
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sharon Reply
What is Boyles law
Pascal Reply
it can simple defined as constant temperature
Muhammad
Boyles law states that the volume of a fixed amount of a gas is inversely proportional to the pressure acting on in provided that the temperature is constant.that is V=k(1/p) or V=k/p
FADILAT
what is motion
Mua Reply
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Anderson
what is escape velocity
Shuaibu Reply
the minimum thrust that an object must have in oder yo escape the gravitational pull
Joshua
what is a dimer
Mua
what is a atom
ADAMS
how to calculate tension
Deena Reply
what are the laws of motion
Mua
Practice Key Terms 4

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Source:  OpenStax, College physics. OpenStax CNX. Jul 27, 2015 Download for free at http://legacy.cnx.org/content/col11406/1.9
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