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Section summary

  • The ideal gas law relates the pressure and volume of a gas to the number of gas molecules and the temperature of the gas.
  • The ideal gas law can be written in terms of the number of molecules of gas:
    PV = NkT , size 12{ ital "PV"= ital "NkT"} {}
    where P size 12{P} {} is pressure, V size 12{V} {} is volume, T size 12{T} {} is temperature, N size 12{N} {} is number of molecules, and k size 12{k} {} is the Boltzmann constant
    k = 1 . 38 × 10 23 J/K . size 12{k=1 "." "38" times "10" rSup { size 8{–"38"} } " J/K"} {}
  • A mole is the number of atoms in a 12-g sample of carbon-12.
  • The number of molecules in a mole is called Avogadro’s number N A size 12{N rSub { size 8{A} } } {} ,
    N A = 6 . 02 × 10 23 mol 1 . size 12{N rSub { size 8{A} } =6 "." "02" times "10" rSup { size 8{"23"} } `"mol" rSup { size 8{ - 1} } } {}
  • A mole of any substance has a mass in grams equal to its molecular weight, which can be determined from the periodic table of elements.
  • The ideal gas law can also be written and solved in terms of the number of moles of gas:
    PV = nRT , size 12{ ital "PV"= ital "nRT"} {}
    where n size 12{n} {} is number of moles and R size 12{R} {} is the universal gas constant,
    R = 8 . 31 J/mol K . size 12{R=8 "." "31"`"J/mol" cdot K} {}
  • The ideal gas law is generally valid at temperatures well above the boiling temperature.

Conceptual questions

Find out the human population of Earth. Is there a mole of people inhabiting Earth? If the average mass of a person is 60 kg, calculate the mass of a mole of people. How does the mass of a mole of people compare with the mass of Earth?

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Under what circumstances would you expect a gas to behave significantly differently than predicted by the ideal gas law?

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A constant-volume gas thermometer contains a fixed amount of gas. What property of the gas is measured to indicate its temperature?

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The gauge pressure in your car tires is 2 . 50 × 10 5 N/m 2 size 12{2 "." "50"´"10" rSup { size 8{5} } " N/m" rSup { size 8{2} } } {} at a temperature of 35 . 0 º C size 12{"35" "." 0°C} {} when you drive it onto a ferry boat to Alaska. What is their gauge pressure later, when their temperature has dropped to 40 . 0 º C size 12{ +- "40" "." 0°C} {} ?

1.62 atm

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Convert an absolute pressure of 7 . 00 × 10 5 N/m 2 size 12{7 "." "00" times "10" rSup { size 8{5} } " N/m" rSup { size 8{2} } } {} to gauge pressure in lb/in 2 . size 12{"lb/in" rSup { size 8{2} } "." } {} (This value was stated to be just less than 90 . 0 lb/in 2 size 12{"90" "." "0 lb/in" rSup { size 8{2} } } {} in [link] . Is it?)

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Suppose a gas-filled incandescent light bulb is manufactured so that the gas inside the bulb is at atmospheric pressure when the bulb has a temperature of 20 . 0 º C size 12{"20" "." 0°C} {} . (a) Find the gauge pressure inside such a bulb when it is hot, assuming its average temperature is 60 . 0 º C size 12{"60" "." 0°C} {} (an approximation) and neglecting any change in volume due to thermal expansion or gas leaks. (b) The actual final pressure for the light bulb will be less than calculated in part (a) because the glass bulb will expand. What will the actual final pressure be, taking this into account? Is this a negligible difference?

(a) 0.136 atm

(b) 0.135 atm. The difference between this value and the value from part (a) is negligible.

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Large helium-filled balloons are used to lift scientific equipment to high altitudes. (a) What is the pressure inside such a balloon if it starts out at sea level with a temperature of 10 . 0 º C size 12{"10" "." 0°C} {} and rises to an altitude where its volume is twenty times the original volume and its temperature is 50 . 0 º C size 12{ +- "50" "." 0°C} {} ? (b) What is the gauge pressure? (Assume atmospheric pressure is constant.)

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Confirm that the units of nRT size 12{ ital "nRT"} {} are those of energy for each value of R size 12{R} {} : (a) 8 . 31 J/mol K size 12{8 "." "31"" J/mol" cdot K} {} , (b) 1 . 99 cal/mol K size 12{1 "." "99 cal/mol" cdot K} {} , and (c) 0 . 0821 L atm/mol K size 12{0 "." "0821 L" cdot "atm/mol" cdot K} {} .

(a) nRT = ( mol ) ( J/mol K ) ( K ) = J size 12{ ital "nRT" = \( "mol" \) \( "J/mol" cdot K \) \( K \) =" J"} {}

(b) nRT = ( mol ) ( cal/mol K ) ( K ) = cal size 12{ ital "nRT" = \( "mol" \) \( "cal/mol" cdot K \) \( K \) =" cal"} {}

(c) nRT = ( mol ) ( L atm/mol K ) ( K ) = L atm = ( m 3 ) ( N/m 2 ) = N m = J

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Questions & Answers

What does mean ohms law imply
Victoria Reply
what is matter
folajin Reply
Anything that occupies space
Any thing that has weight and occupies space
Anything which we can feel by any of our 5 sense organs
what is a sulphate
any answers
the time rate of increase in velocity is called
Blessing Reply
What is uniform velocity
Greetings,users of that wonderful app.
Frank Reply
how to solve pressure?
Cruz Reply
how do we calculate weight and eara eg an elefant that weight 2000kg has four fits or legs search of surface eara is 0.1m2(1metre square) incontact with the ground=10m2(g =10m2)
can someone derive the formula a little bit deeper?
what is coplanar force?
what is accuracy and precision
Peace Reply
How does a current follow?
Vineeta Reply
which one dc or ac current.
how does a current following?
AC current
AC current follows due to changing electric field and magnetic field.
you guys are just saying follow is flow not follow please
ok bro thanks
but i wanted to understand him/her in his own language
but I think the statement is written in English not any other language
my mean that in which form he/she written this,will understand better in this form, i write.
ok thanks bro. my mistake
u are welcome
what is a semiconductor
Vineeta Reply
substances having lower forbidden gap between valence band and conduction band
what is a conductor?
replace lower by higher only
convert 56°c to kelvin
How does a current follow?
A semiconductor is any material whose conduction lies between that of a conductor and an insulator.
what is Atom? what is molecules? what is ions?
Abubakar Reply
What is a molecule
Samuel Reply
Is a unit of a compound that has two or more atoms either of the same or different atoms
A molecule is the smallest indivisible unit of a compound, Just like the atom is the smallest indivisible unit of an element.
what is a molecule?
what is a vector
smith Reply
A quantity that has both a magnitude AND a direction. E.g velocity, acceleration, force are all vector quantities. Hope this helps :)
what is the difference between velocity and relative velocity?
Velocity is the rate of change of displacement with time. Relative velocity on the other hand is the velocity observed by an observer with respect to a reference point.
what do u understand by Ultraviolet catastrophe?
A certain freely falling object, released from rest, requires 1.5seconds to travel the last 30metres before it hits the ground. (a) Find the velocity of the object when it is 30metres above the ground.
A vector is a quantity that has both magnitude and direction
the velocity Is 20m/s-2
derivation of electric potential
Rugunda Reply
V = Er = (kq/r^2)×r V = kq/r Where V: electric potential.
what is the difference between simple motion and simple harmonic motion ?
simple harmonic motion is a motion of tro and fro of simple pendulum and the likes while simple motion is a linear motion on a straight line.
a body acceleration uniform from rest a 6m/s -2 for 8sec and decelerate uniformly to rest in the next 5sec,the magnitude of the deceleration is ?
Patricia Reply
The wording not very clear kindly
the magnitude of deceleration =-9.8ms-2. first find the final velocity using the known acceleration and time. next use the calculated velocity to find the size of deceleration.
Firstly, calculate final velocity of the body and then the deceleration. The final ans is,-9.6ms-2
8x6= 48m/-2 use v=u + at 48÷5=9.6
can i define motion like this motion can be define as the continuous change of an object or position
Shuaib Reply
Any object in motion will come to rest after a time duration. Different objects may cover equal distance in different time duration. Therefore, motion is defined as a change in position depending on time.
Practice Key Terms 4

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Source:  OpenStax, College physics. OpenStax CNX. Jul 27, 2015 Download for free at http://legacy.cnx.org/content/col11406/1.9
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