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E n = 1 2 m e v 2 k Zq e 2 r n . size 12{E rSub { size 8{n} } = { {1} over {2} } m rSub { size 8{e} } v rSup { size 8{2} } - k { { ital "Zq" rSub { size 8{e} } rSup { size 8{2} } } over {r rSub { size 8{n} } } } } {}

Now we substitute r n size 12{r rSub { size 8{n} } } {} and v size 12{v} {} from earlier equations into the above expression for energy. Algebraic manipulation yields

E n = Z 2 n 2 E 0 ( n = 1, 2, 3, ... ) size 12{E rSub { size 8{n} } = - { {Z rSup { size 8{2} } } over {n rSup { size 8{2} } } } E rSub { size 8{0} } \( n=1," 2, 3, " "." "." "." \) } {}

for the orbital energies of hydrogen-like atoms    . Here, E 0 size 12{E rSub { size 8{0} } } {} is the ground-state energy n = 1 size 12{ left (n=1 right )} {} for hydrogen Z = 1 size 12{ left (Z=1 right )} {} and is given by

E 0 = 2 π 2 q e 4 m e k 2 h 2 = 13.6 eV.

Thus, for hydrogen,

E n = 13.6 eV n 2 ( n = 1, 2, 3, ...).

[link] shows an energy-level diagram for hydrogen that also illustrates how the various spectral series for hydrogen are related to transitions between energy levels.

An energy level diagram is shown. At the left, there is a vertical arrow showing the energy levels increasing from bottom to top. At the bottom, there is a horizontal line showing the energy levels of Lyman series, n is one. The energy is marked as negative thirteen point six electron volt. Then, in the upper half of the figure, another horizontal line showing Balmer series is shown when the value of n is two. The energy level is labeled as negative three point four zero electron volt. Above it there is another horizontal line showing Paschen series. The energy level is marked as negative one point five one electron volt. Above this line, some more lines are shown in a small area to show energy levels of other values of n.
Energy-level diagram for hydrogen showing the Lyman, Balmer, and Paschen series of transitions. The orbital energies are calculated using the above equation, first derived by Bohr.

Electron total energies are negative, since the electron is bound to the nucleus, analogous to being in a hole without enough kinetic energy to escape. As n size 12{n} {} approaches infinity, the total energy becomes zero. This corresponds to a free electron with no kinetic energy, since r n size 12{r rSub { size 8{n} } } {} gets very large for large n size 12{n} {} , and the electric potential energy thus becomes zero. Thus, 13.6 eV is needed to ionize hydrogen (to go from –13.6 eV to 0, or unbound), an experimentally verified number. Given more energy, the electron becomes unbound with some kinetic energy. For example, giving 15.0 eV to an electron in the ground state of hydrogen strips it from the atom and leaves it with 1.4 eV of kinetic energy.

Finally, let us consider the energy of a photon emitted in a downward transition, given by the equation to be

Δ E = hf = E i E f . size 12{ΔE= ital "hf"=E rSub { size 8{i} } - E rSub { size 8{f} } } {}

Substituting E n = ( 13.6 eV / n 2 ) size 12{E rSub { size 8{n} } = - "13" "." 6``"eV"/n rSup { size 8{2} } } {} , we see that

hf = 13.6 eV 1 n f 2 1 n i 2 . size 12{ ital "hf"= left ("13" "." 6" eV" right ) left ( { {1} over {n rSub { size 8{f} } rSup { size 8{2} } } } - { {1} over {n rSub { size 8{i} } rSup { size 8{2} } } } right )} {}

Dividing both sides of this equation by hc size 12{ ital "hc"} {} gives an expression for 1 / λ size 12{1/λ} {} :

hf hc = f c = 1 λ = 13.6 eV hc 1 n f 2 1 n i 2 . size 12{ { { ital "hf"} over { ital "hc"} } = { {f} over {c} } = { {1} over {λ} } = { { left ("13" "." 6" eV" right )} over { ital "hc"} } left ( { {1} over {n rSub { size 8{f} } rSup { size 8{2} } } } - { {1} over {n rSub { size 8{i} } rSup { size 8{2} } } } right )} {}

It can be shown that

13.6 eV hc = 13.6 eV 1.602 × 10 −19 J/eV 6.626 × 10 −34 J·s 2.998 × 10 8 m/s = 1.097 × 10 7 m –1 = R

is the Rydberg constant    . Thus, we have used Bohr’s assumptions to derive the formula first proposed by Balmer years earlier as a recipe to fit experimental data.

1 λ = R 1 n f 2 1 n i 2 size 12{ { {1} over {λ} } =R left ( { {1} over {n rSub { size 8{f} } rSup { size 8{2} } } } - { {1} over {n rSub { size 8{i} } rSup { size 8{2} } } } right )} {}

We see that Bohr’s theory of the hydrogen atom answers the question as to why this previously known formula describes the hydrogen spectrum. It is because the energy levels are proportional to 1 / n 2 size 12{1/n rSup { size 8{2} } } {} , where n size 12{n} {} is a non-negative integer. A downward transition releases energy, and so n i size 12{n rSub { size 8{i} } } {} must be greater than n f size 12{n rSub { size 8{f} } } {} . The various series are those where the transitions end on a certain level. For the Lyman series, n f = 1 size 12{n rSub { size 8{f} } =1} {} — that is, all the transitions end in the ground state (see also [link] ). For the Balmer series, n f = 2 size 12{n rSub { size 8{f} } =2} {} , or all the transitions end in the first excited state; and so on. What was once a recipe is now based in physics, and something new is emerging—angular momentum is quantized.

Triumphs and limits of the bohr theory

Bohr did what no one had been able to do before. Not only did he explain the spectrum of hydrogen, he correctly calculated the size of the atom from basic physics. Some of his ideas are broadly applicable. Electron orbital energies are quantized in all atoms and molecules. Angular momentum is quantized. The electrons do not spiral into the nucleus, as expected classically (accelerated charges radiate, so that the electron orbits classically would decay quickly, and the electrons would sit on the nucleus—matter would collapse). These are major triumphs.

Questions & Answers

Why is the sky blue...?
Star Reply
It's filtered light from the 2 forms of radiation emitted from the sun. It's mainly filtered UV rays. There's a theory titled Scatter Theory that covers this topic
A heating coil of resistance 30π is connected to a 240v supply for 5min to boil a quantity of water in a vessel of heat capacity 200jk. If the initial temperature of water is 20°c and it specific heat capacity is 4200jkgk calculate the mass of water in a vessel
fasawe Reply
A thin equi convex lens is placed on a horizontal plane mirror and a pin held 20 cm vertically above the lens concise in position with its own image the space between the undersurface of d lens and the mirror is filled with water (refractive index =1•33)and then to concise with d image d pin has to
Azummiri Reply
Be raised until its distance from d lens is 27cm find d radius of curvature
what happens when a nuclear bomb and atom bomb bomb explode add the same time near each other
FlAsH Reply
A monkey throws a coconut straight upwards from a coconut tree with a velocity of 10 ms-1. The coconut tree is 30 m high. Calculate the maximum height of the coconut from the top of the coconut tree? Can someone answer my question
Fatinizzah Reply
v2 =u2 - 2gh 02 =10x10 - 2x9.8xh h = 100 ÷ 19.6 answer = 30 - h.
why is the north side is always referring to n side of magnetic
sam Reply
who is a nurse
Chilekwa Reply
A nurse is a person who takes care of the sick
a nurse is also like an assistant to the doctor
explain me wheatstone bridge
Malik Reply
good app
Wheatstone bridge is an instrument used to measure an unknown electrical resistance by balancing two legs of a bridge circuit, one leg of which includes the unknown component.
Rockwell Software is Rockwell Automation’s "Retro Encabulator". Now, basically the only new principle involved is that instead of power being generated by the relative motion of conductors and fluxes, it’s produced by the modial interaction of magneto-reluctance and capacitive diractance. The origin
what refractive index
Adjah Reply
write a comprehensive note on primary colours
Harrison Reply
relationship between refractive index, angle of minimum deviation and angle of prism
Who knows the formula for binding energy,and what each variable or notation stands for?
Agina Reply
1. A black thermocouple measures the temperature in the chamber with black walls.if the air around the thermocouple is 200 C,the walls are at 1000 C,and the heat transfer constant is 15.compute the temperature gradient
Tikiso Reply
what is the relationship between G and g
Olaiya Reply
G is the u. constant, as g stands for grav, accelerate at a discreet point
Is that all about it?
pls explain in details
G is a universal constant
g stands for the gravitational acceleration point. hope this helps you.
balloon TD is at a gravitational acceleration at a specific point
I'm sorry this doesn't take dictation very well.
Can anyone explain the Hooke's law of elasticity?
Olaiya Reply
extension of a spring is proportional to the force applied so long as the force applied does not exceed the springs capacity according to my textbook
does this help?
Yes, thanks
so any solid can be compressed how compressed is dependent upon how much force is applied F=deltaL
sorry, the equation is F=KdeltaL delta is the triangle symbol and L is length so the change in length is proportional to amount of Force applied I believe that is what Hookes law means. anyone catch any mistakes here please correct me :)
I think it is used only for solids and not liquids, isn't it?
basically as long as you dont exceed the elastic limit the object should return to it original form but if you exceed this limit the object will not return to original shape as it will break
Thanks for the explanation
yh, liquids don't apply here, that should be viscosity
hope it helps 😅
also, an object doesnt have to break necessarily, but it will have a new form :)
yeah, I think it is for solids but maybe there is a variation for liquids? that I am not sure of
good luck!
aplease i need a help on spcific latent heat of vibrations
specific latent heat of vaporisation
how many kilometers makes a mile
Margaret Reply
about 1.6 kilometres.
near about 1.67 kilometers
equal to 1.609344 kilometers.
Practice Key Terms 7

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