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[link] is a schematic representation of the two fundamental parts of any voltage source. The emf (represented by a script E in the figure) and internal resistance r size 12{r} {} are in series. The smaller the internal resistance for a given emf, the more current and the more power the source can supply.

This diagram shows a battery with a schematic indicating the e m f, represented by script E, and the internal resistance r of the battery. The voltage output of the battery is measured between the input and output terminals and is equal to the e m f minus the product of the current and the internal resistance.
Any voltage source (in this case, a carbon-zinc dry cell) has an emf related to its source of potential difference, and an internal resistance r size 12{r} {} related to its construction. (Note that the script E stands for emf.). Also shown are the output terminals across which the terminal voltage V size 12{V} {} is measured. Since V = emf Ir size 12{V="emf" - ital "Ir"} {} , terminal voltage equals emf only if there is no current flowing.

The internal resistance r size 12{r} {} can behave in complex ways. As noted, r size 12{r} {} increases as a battery is depleted. But internal resistance may also depend on the magnitude and direction of the current through a voltage source, its temperature, and even its history. The internal resistance of rechargeable nickel-cadmium cells, for example, depends on how many times and how deeply they have been depleted.

Things great and small: the submicroscopic origin of battery potential

Various types of batteries are available, with emfs determined by the combination of chemicals involved. We can view this as a molecular reaction (what much of chemistry is about) that separates charge.

The lead-acid battery used in cars and other vehicles is one of the most common types. A single cell (one of six) of this battery is seen in [link] . The cathode (positive) terminal of the cell is connected to a lead oxide plate, while the anode (negative) terminal is connected to a lead plate. Both plates are immersed in sulfuric acid, the electrolyte for the system.

A simplified view of a battery shows a rectangular container of sulfuric acid with two thin upright metal plates immersed in it, one made of lead and the other made of lead oxide. Each plate projects above the liquid line, providing a positive or negative terminal above the battery. The positive terminal is labeled as the cathode, and the negative terminal is labeled as the anode.
Artist’s conception of a lead-acid cell. Chemical reactions in a lead-acid cell separate charge, sending negative charge to the anode, which is connected to the lead plates. The lead oxide plates are connected to the positive or cathode terminal of the cell. Sulfuric acid conducts the charge as well as participating in the chemical reaction.

The details of the chemical reaction are left to the reader to pursue in a chemistry text, but their results at the molecular level help explain the potential created by the battery. [link] shows the result of a single chemical reaction. Two electrons are placed on the anode, making it negative, provided that the cathode supplied two electrons. This leaves the cathode positively charged, because it has lost two electrons. In short, a separation of charge has been driven by a chemical reaction.

Note that the reaction will not take place unless there is a complete circuit to allow two electrons to be supplied to the cathode. Under many circumstances, these electrons come from the anode, flow through a resistance, and return to the cathode. Note also that since the chemical reactions involve substances with resistance, it is not possible to create the emf without an internal resistance.

The diagram shows a simplified view of a battery depicting a rectangular container containing two thin upright metal plates immersed in a liquid. An enlarged view of the metal plates is also shown. One plate has positive charges on it shown as small spheres enclosing a positive sign. The other plate has negative charge on it shown as small spheres enclosing an electron. The electrons are shown to move from the positive plate to the negative plate using arrows through a molecular reaction in the liquid.
Artist’s conception of two electrons being forced onto the anode of a cell and two electrons being removed from the cathode of the cell. The chemical reaction in a lead-acid battery places two electrons on the anode and removes two from the cathode. It requires a closed circuit to proceed, since the two electrons must be supplied to the cathode.

Questions & Answers

resistance of thermometer in relation to temperature
Ifeanyi Reply
how
Bernard
that resistance is not measured yet, it may be probably in the next generation of scientists
Paul
Is fundamental quantities under physical quantities?
Igwe Reply
please I didn't not understand the concept of the physical therapy
John Reply
physiotherapy - it's a practice of exercising for healthy living.
Paul
what chapter is this?
Anderson
this is not in this book, it's from other experiences.
Paul
please I have probably with calculate please can you please and help me out
John Reply
Sure
Gift
What is Boyce law
Sly Reply
how to convert meter per second to kilometers per hour
grace Reply
Divide with 3.6
Mateo
multiply by (km/1000m) x (3600 s/h) -> 3.6
Muhammad
2 how heat loss is prevented in a vacuum flask
Abdullah Reply
what is science
Helen
logical reasoning for a particular phenomenon.
Ajay
I don't know anything about it 😔. I'm sorry, please forgive 😔
Adarsh
due to non in contact mean no conduction and no convection bec of non conducting base and walls and also their is a grape between the layer like to take the example of thermo flask
Abdul
dimensions v²=u²+2at
Lagben Reply
what if time is not given in finding the average velocity?
Alan Reply
the magnetic circuit of a certain of the flux paths in each of the long and short sides being 25cm and 20cm reprectielectrove. there is an air gap of 2mm long in one the long sides if a flux density of 0.8weber/m is to produce in the magnet of 1500 turns..
Daniel Reply
How do you calculate precision
Sacky Reply
what module is that?
Fillemon
Chemisty 1A?
Fillemon
No it has something to do with measurements bro... What we did today in class
Sacky
Tah bra honestly I didn't understand a thing in that class..when re your Tutorials?
Fillemon
Friday bro... But the topics we did are in this app... Just try to master them quickly before the test dates... Are you done with the Maths sheet
Sacky
I eat ass
Anderson
I'll work on the maths sheet tomorrow bra @Sacky Malyenge but I'll try mastering them
Fillemon
I'll eat your mom's ass with a side of tendies
Anderson
@Fillemon Nanwaapo
Anderson
lol, hush
Emi
There are very large numbers of charged particles in most objects. Why, then, don’t most objects exhibit static electricity?
Bilkisu Reply
Because there's an equal number of negative and positive charges... objects are neutral in nature
NELSON
when a ball rolls on a smooth level ground,the motion of its centre is?
Mary Reply
what is electro magnetic field?
Mary
electromagnetic field is a special type of field been produced by electric charges..!!! like the word electro from Electricity and the word magnetic from Magnetism.. so it is more of a join field..!!!
NELSON
Electromagnetic field is caused by moving electric charge
Muhammad
when a ball rolls on a smooth level ground,the motion of its centre is?
Mumeh
what's the relationship btw displacement and position
Declan Reply
displacement is the change of position 8======✊=D 💦💦
Anderson
what is the meaning of elasticity
Pele Reply
is the ability of a material to or any object to expand to a limit point
king
this is about kinematics you bonk
Emi
discuss under damped
Prince Reply
Practice Key Terms 4

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Source:  OpenStax, College physics. OpenStax CNX. Jul 27, 2015 Download for free at http://legacy.cnx.org/content/col11406/1.9
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