# 6.1 Determination of sublimation enthalpy and vapor pressure for  (Page 3/3)

 Page 3 / 3

## Data analysis

The basis of analyzing isothermal TGA data involves using the Clausius-Clapeyron relation between vapor pressure (p) and temperature (T), [link] , where ∆H sub is the enthalpy of sublimation and R is the gas constant (8.314 J/K.mol).

Since msub data are obtained from TGA data, it is necessary to utilize the Langmuir equation, [link] , that relates the vapor pressure of a solid with its sublimation rate.

After integrating [link] in log form, substituting in [link] , and consolidating the constants, one obtains the useful equality, [link] .

Hence, the linear slope of a log(m sub T 1/2 ) versus 1/T plot yields ΔH sub . An example of a typical plot and the corresponding ΔH sub value is shown in [link] . In addition, the y intercept of such a plot provides a value for T sub , the calculated sublimation temperature at atmospheric pressure.

[link] lists the typical results using the TGA method for a variety of metal β -diketonates, while [link] lists similar values obtained for gallium chalcogenide cubane compounds.

 Compound ΔH sub (kJ/mol) ΔS sub (J/K.mol) T sub calc. (°C) Calculated vapor pressure @ 150 °C (Torr) Al(acac) 3 93 220 150 3.261 Al(tfac) 3 74 192 111 9.715 Al(hfac) 3 52 152 70 29.120 Cr(acac) 3 91 216 148 3.328 Cr(tfac) 3 71 186 109 9.910 Cr(hfac) 3 46 134 69 29.511 Fe(acac) 3 112 259 161 2.781 Fe(tfac) 3 96 243 121 8.340 Fe(hfac) 3 60 169 81 25.021 Co(acac) 3 138 311 170 1.059 Co(tfac) 3 119 295 131 3.319 Co(hfac) 3 73 200 90 9.132
 Compound ∆H sub (kJ/mol) ∆S sub (J/K. mol) T sub calc. (°C) Calculated vapor pressure @ 150 °C (Torr) [(Me 3 C)GaS] 4 110 300 94 22.75 [(EtMe 2 C)GaS] 4 124 330 102 18.89 [(Et 2 MeC)GaS] 4 137 339 131 1.173 [(Et 3 C)GaS] 4 149 333 175 0.018 [(Me 3 C)GaSe)] 4 119 305 116 3.668 [(EtMe 2 C)GaSe] 4 137 344 124 2.562 [(Et 2 MeC)GaSe] 4 147 359 136 0.815 [(Et 3 C)GaSe] 4 156 339 189 0.005

A common method used to enhance precursor volatility and corresponding efficacy for CVD applications is to incorporate partially ( [link] b) or fully ( [link] c) fluorinated ligands. As may be seen from [link] this substitution does results in significant decrease in the ΔH sub , and thus increased volatility. The observed enhancement in volatility may be rationalized either by an increased amount of intermolecular repulsion due to the additional lone pairs or that the reduced polarizability of fluorine (relative to hydrogen) causes fluorinated ligands to have less intermolecular attractive interactions.

## Determination of sublimation entropy

The entropy of sublimation is readily calculated from the ΔH sub and the calculated T sub data, [link] .

[link] and [link] show typical values for metal β-diketonate compounds and gallium chalcogenide cubane compounds, respectively. The range observed for gallium chalcogenide cubane compounds (ΔS sub = 330 ±20 J/K.mol) is slightly larger than values reported for the metal β-diketonates compounds (ΔS sub = 130 - 330 J/K.mol) and organic compounds (100 - 200 J/K.mol), as would be expected for a transformation giving translational and internal degrees of freedom. For any particular chalcogenide, i.e., [(R)GaS] 4 , the lowest ΔS sub are observed for the Me 3 C derivatives, and the largest ΔS sub for the Et 2 MeC derivatives, see [link] . This is in line with the relative increase in the modes of freedom for the alkyl groups in the absence of crystal packing forces.

## Determination of vapor pressure

While the sublimation temperature is an important parameter to determine the suitability of a potential precursor compounds for CVD, it is often preferable to express a compound's volatility in terms of its vapor pressure. However, while it is relatively straightforward to determine the vapor pressure of a liquid or gas, measurements of solids are difficult (e.g., use of the isoteniscopic method) and few laboratories are equipped to perform such experiments. Given that TGA apparatus are increasingly accessible, it would therefore be desirable to have a simple method for vapor pressure determination that can be accomplished on a TGA.

Substitution of [link] into [link] allows for the calculation of the vapor pressure (p) as a function of temperature (T). For example, [link] shows the calculated temperature dependence of the vapor pressure for [(Me 3 C)GaS] 4 . The calculated vapor pressures at 150 °C for metal β-diketonates compounds and gallium chalcogenide cubane compounds are given in [link] and [link] .

The TGA approach to show reasonable agreement with previous measurements. For example, while the value calculated for Fe(acac) 3 (2.78 Torr @ 113 °C) is slightly higher than that measured directly by the isoteniscopic method (0.53 Torr @ 113 °C); however, it should be noted that measurements using the sublimation bulb method obtained values much lower (8 x 10 -3 Torr @ 113 °C). The TGA method offers a suitable alternative to conventional (direct) measurements of vapor pressure.

## Bibliography

• P. W. Atkins, Physical Chemistry, 5th ed., W. H. Freeman, New York (1994).
• G. Beech and R. M. Lintonbon, Thermochim. Acta, 1971, 3 , 97.
• B. D. Fahlman and A. R. Barron, Adv. Mater. Optics Electron ., 2000, 10 , 223.
• E. G. Gillan, S. G. Bott, and A. R. Barron, Chem. Mater., 1997, 9 , 3, 796.
• J. O. Hill and J. P. Murray, Rev. Inorg. Chem., 1993, 13 , 125.
• J. P. Murray, K. J. Cavell and J. O. Hill, Thermochim. Acta, 1980, 36 , 97.
• M. A. V. Ribeiro da Silva and M. L. C. C. H. Ferrao, J. Chem. Thermodyn., 1994, 26 , 315.
• R. Sabbah, D. Tabet, S. Belaadi, Thermochim. Acta, 1994, 247 , 193.
• L. A. Torres-Gomez, G. Barreiro-Rodriquez, and A. Galarza-Mondragon, Thermochim. Acta, 1988, 124 , 229.

how can chip be made from sand
are nano particles real
yeah
Joseph
Hello, if I study Physics teacher in bachelor, can I study Nanotechnology in master?
no can't
Lohitha
where we get a research paper on Nano chemistry....?
nanopartical of organic/inorganic / physical chemistry , pdf / thesis / review
Ali
what are the products of Nano chemistry?
There are lots of products of nano chemistry... Like nano coatings.....carbon fiber.. And lots of others..
learn
Even nanotechnology is pretty much all about chemistry... Its the chemistry on quantum or atomic level
learn
da
no nanotechnology is also a part of physics and maths it requires angle formulas and some pressure regarding concepts
Bhagvanji
hey
Giriraj
Preparation and Applications of Nanomaterial for Drug Delivery
revolt
da
Application of nanotechnology in medicine
has a lot of application modern world
Kamaluddeen
yes
narayan
what is variations in raman spectra for nanomaterials
ya I also want to know the raman spectra
Bhagvanji
I only see partial conversation and what's the question here!
what about nanotechnology for water purification
please someone correct me if I'm wrong but I think one can use nanoparticles, specially silver nanoparticles for water treatment.
Damian
yes that's correct
Professor
I think
Professor
Nasa has use it in the 60's, copper as water purification in the moon travel.
Alexandre
nanocopper obvius
Alexandre
what is the stm
is there industrial application of fullrenes. What is the method to prepare fullrene on large scale.?
Rafiq
industrial application...? mmm I think on the medical side as drug carrier, but you should go deeper on your research, I may be wrong
Damian
How we are making nano material?
what is a peer
What is meant by 'nano scale'?
What is STMs full form?
LITNING
scanning tunneling microscope
Sahil
how nano science is used for hydrophobicity
Santosh
Do u think that Graphene and Fullrene fiber can be used to make Air Plane body structure the lightest and strongest. Rafiq
Rafiq
what is differents between GO and RGO?
Mahi
what is simplest way to understand the applications of nano robots used to detect the cancer affected cell of human body.? How this robot is carried to required site of body cell.? what will be the carrier material and how can be detected that correct delivery of drug is done Rafiq
Rafiq
if virus is killing to make ARTIFICIAL DNA OF GRAPHENE FOR KILLED THE VIRUS .THIS IS OUR ASSUMPTION
Anam
analytical skills graphene is prepared to kill any type viruses .
Anam
Any one who tell me about Preparation and application of Nanomaterial for drug Delivery
Hafiz
what is Nano technology ?
write examples of Nano molecule?
Bob
The nanotechnology is as new science, to scale nanometric
brayan
nanotechnology is the study, desing, synthesis, manipulation and application of materials and functional systems through control of matter at nanoscale
Damian
Got questions? Join the online conversation and get instant answers!