# 29.7 Patterns in spectra reveal more quantization  (Page 2/9)

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We already know that the magnitude of angular momentum is quantized for electron orbits in atoms. The new insight is that the direction of the orbital angular momentum is also quantized . The fact that the orbital angular momentum can have only certain directions is called space quantization    . Like many aspects of quantum mechanics, this quantization of direction is totally unexpected. On the macroscopic scale, orbital angular momentum, such as that of the moon around the earth, can have any magnitude and be in any direction.

Detailed treatment of space quantization began to explain some complexities of atomic spectra, but certain patterns seemed to be caused by something else. As mentioned, spectral lines are actually closely spaced doublets, a characteristic called fine structure    , as shown in [link] . The doublet changes when a magnetic field is applied, implying that whatever causes the doublet interacts with a magnetic field. In 1925, Sem Goudsmit and George Uhlenbeck, two Dutch physicists, successfully argued that electrons have properties analogous to a macroscopic charge spinning on its axis. Electrons, in fact, have an internal or intrinsic angular momentum called intrinsic spin     $\mathbf{\text{S}}$ . Since electrons are charged, their intrinsic spin creates an intrinsic magnetic field     ${\mathbf{\text{B}}}_{\text{int}}$ , which interacts with their orbital magnetic field ${\mathbf{\text{B}}}_{\text{orb}}$ . Furthermore, electron intrinsic spin is quantized in magnitude and direction , analogous to the situation for orbital angular momentum. The spin of the electron can have only one magnitude, and its direction can be at only one of two angles relative to a magnetic field, as seen in [link] . We refer to this as spin up or spin down for the electron. Each spin direction has a different energy; hence, spectroscopic lines are split into two. Spectral doublets are now understood as being due to electron spin.

These two new insights—that the direction of angular momentum, whether orbital or spin, is quantized, and that electrons have intrinsic spin—help to explain many of the complexities of atomic and molecular spectra. In magnetic resonance imaging, it is the way that the intrinsic magnetic field of hydrogen and biological atoms interact with an external field that underlies the diagnostic fundamentals.

## Section summary

• The Zeeman effect—the splitting of lines when a magnetic field is applied—is caused by other quantized entities in atoms.
• Both the magnitude and direction of orbital angular momentum are quantized.
• The same is true for the magnitude and direction of the intrinsic spin of electrons.

## Conceptual questions

What is the Zeeman effect, and what type of quantization was discovered because of this effect?

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yeah
Joseph
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Lohitha
where we get a research paper on Nano chemistry....?
nanopartical of organic/inorganic / physical chemistry , pdf / thesis / review
Ali
what are the products of Nano chemistry?
There are lots of products of nano chemistry... Like nano coatings.....carbon fiber.. And lots of others..
learn
Even nanotechnology is pretty much all about chemistry... Its the chemistry on quantum or atomic level
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da
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Bhagvanji
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Giriraj
Preparation and Applications of Nanomaterial for Drug Delivery
revolt
da
Application of nanotechnology in medicine
has a lot of application modern world
Kamaluddeen
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narayan
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ya I also want to know the raman spectra
Bhagvanji
I only see partial conversation and what's the question here!
what about nanotechnology for water purification
please someone correct me if I'm wrong but I think one can use nanoparticles, specially silver nanoparticles for water treatment.
Damian
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Professor
I think
Professor
Nasa has use it in the 60's, copper as water purification in the moon travel.
Alexandre
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Alexandre
what is the stm
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Rafiq
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Damian
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What is meant by 'nano scale'?
What is STMs full form?
LITNING
scanning tunneling microscope
Sahil
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Santosh
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Rafiq
what is differents between GO and RGO?
Mahi
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Rafiq
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Anam
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Anam
Any one who tell me about Preparation and application of Nanomaterial for drug Delivery
Hafiz
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write examples of Nano molecule?
Bob
The nanotechnology is as new science, to scale nanometric
brayan
nanotechnology is the study, desing, synthesis, manipulation and application of materials and functional systems through control of matter at nanoscale
Damian
Is there any normative that regulates the use of silver nanoparticles?
what king of growth are you checking .?
Renato
how did you get the value of 2000N.What calculations are needed to arrive at it
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