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The most likely conditions (or macrostates) for a gas are those we see all the time—a random distribution of atoms in space with a Maxwell-Boltzmann distribution of speeds in random directions, as predicted by kinetic theory. This is the most disorderly and least structured condition we can imagine. In contrast, one type of very orderly and structured macrostate has all of the atoms in one corner of a container with identical velocities. There are very few ways to accomplish this (very few microstates corresponding to it), and so it is exceedingly unlikely ever to occur. (See [link] (b).) Indeed, it is so unlikely that we have a law saying that it is impossible, which has never been observed to be violated—the second law of thermodynamics.

Two states of a container of gas are shown. In state a, the gas molecules, depicted as small green spheres, are randomly distributed in the container, with random velocities (an arrow is attached to each sphere, and the arrows vary in length and direction). This state is labeled likely. In state b, the molecules are clustered in the lower left-hand corner of the container and the arrows are much shorter. This state is labeled highly unlikely.
(a) The ordinary state of gas in a container is a disorderly, random distribution of atoms or molecules with a Maxwell-Boltzmann distribution of speeds. It is so unlikely that these atoms or molecules would ever end up in one corner of the container that it might as well be impossible. (b) With energy transfer, the gas can be forced into one corner and its entropy greatly reduced. But left alone, it will spontaneously increase its entropy and return to the normal conditions, because they are immensely more likely.

The disordered condition is one of high entropy, and the ordered one has low entropy. With a transfer of energy from another system, we could force all of the atoms into one corner and have a local decrease in entropy, but at the cost of an overall increase in entropy of the universe. If the atoms start out in one corner, they will quickly disperse and become uniformly distributed and will never return to the orderly original state ( [link] (b)). Entropy will increase. With such a large sample of atoms, it is possible—but unimaginably unlikely—for entropy to decrease. Disorder is vastly more likely than order.

The arguments that disorder and high entropy are the most probable states are quite convincing. The great Austrian physicist Ludwig Boltzmann (1844–1906)—who, along with Maxwell, made so many contributions to kinetic theory—proved that the entropy of a system in a given state (a macrostate) can be written as

S = k ln W , size 12{S=k" ln"W} {}

where k = 1 . 38 × 10 23 J/K size 12{k=1 "." "38" times "10" rSup { size 8{ - "23"} } "J/K"} {} is Boltzmann’s constant, and ln W size 12{"ln" W} {} is the natural logarithm of the number of microstates W size 12{ W} {} corresponding to the given macrostate. W size 12{ W} {} is proportional to the probability that the macrostate will occur. Thus entropy is directly related to the probability of a state—the more likely the state, the greater its entropy. Boltzmann proved that this expression for S size 12{ S} {} is equivalent to the definition Δ S = Q / T size 12{ ΔS=Q/T} {} , which we have used extensively.

Thus the second law of thermodynamics is explained on a very basic level: entropy either remains the same or increases in every process. This phenomenon is due to the extraordinarily small probability of a decrease, based on the extraordinarily larger number of microstates in systems with greater entropy. Entropy can decrease, but for any macroscopic system, this outcome is so unlikely that it will never be observed.

Questions & Answers

how many subject is in physics
Adeshina Reply
the write question should be " How many Topics are in O- Level Physics, or other branches of physics.
effiom
how many topic are in physics
Praise
yh I need someone to explain something im tryna solve . I'll send the question if u down for it
Tamdy Reply
a ripple tank experiment a vibrating plane is used to generate wrinkles in the water .if the distance between two successive point is 3.5cm and the wave travel a distance of 31.5cm find the frequency of the vibration
Tamdy
the range of objects and phenomena studied in physics is
Bethel Reply
what is Linear motion
Hamza Reply
straight line motion is called linear motion
then what
Amera
linear motion is a motion in a line, be it in a straight line or in a non straight line. It is the rate of change of distance.
Saeedul
Hi
aliyu
your are wrong Saeedul
Richard
Linear motion is a one-dimensional motion along a straight line, and can therefore be described mathematically using only one spatial dimension
Jason
is a one-dimensional motion along a straight line, and can therefore be described mathematically using only one spatial dimensions. 
Praise
what is a classical electrodynamics?
Marga
what is dynamics
Marga
dynamic is the force that stimulates change or progress within the system or process
Oze
what is the formula to calculate wavelength of the incident light
David Reply
if a spring is is stiffness of 950nm-1 what work will be done in extending the spring by 60mmp
Hassan Reply
State the forms of energy
Samzy Reply
machanical
Ridwan
Word : Mechanical wave Definition : The waves, which need a material medium for their propagation, e.g., Sound waves. \n\nOther Definition: The waves, which need a material medium for their propagation, are called mechanical waves. Mechanical waves are also called elastic waves. Sound waves, water waves are examples of mechanical waves.t Definition: wave consisting of periodic motion of matter; e.g. sound wave or water wave as opposed to electromagnetic wave.h
Clement Reply
correct
Akinpelu
what is mechanical wave
Akinpelu Reply
a wave which require material medium for its propagation
syed
The S.I unit for power is what?
Samuel Reply
watt
Okoli
Am I correct
Okoli
it can be in kilowatt, megawatt and so
Femi
yes
Femi
correct
Jaheim
kW
Akinpelu
OK that's right
Samuel
SI.unit of power is.watt=j/c.but kw.and Mw are bigger.umots
syed
What is physics
aish Reply
study of matter and its nature
Akinpelu
The word physics comes from a Greek word Physicos which means Nature.The Knowledge of Nature. It is branch of science which deals with the matter and energy and interaction between them.
Uniform
why in circular motion, a tangential acceleration can change the magnitude of the velocity but not its direction
Syafiqah Reply
reasonable
Femi
because it is balanced by the inward acceleration otherwise known as centripetal acceleration
MUSTAPHA
What is a wave
Mutuma Reply
Tramsmission of energy through a media
Mateo
is the disturbance that carry materials as propagation from one medium to another
Akinpelu
mistakes thanks
Akinpelu
find the triple product of (A*B).C given that A =i + 4j, B=2i - 3j and C = i + k
Favour Reply
Difference between north seeking pole and south seeking pole
Stanley Reply
Practice Key Terms 3

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Source:  OpenStax, College physics. OpenStax CNX. Jul 27, 2015 Download for free at http://legacy.cnx.org/content/col11406/1.9
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