# 15.7 Statistical interpretation of entropy and the second law of  (Page 3/8)

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The most likely conditions (or macrostates) for a gas are those we see all the time—a random distribution of atoms in space with a Maxwell-Boltzmann distribution of speeds in random directions, as predicted by kinetic theory. This is the most disorderly and least structured condition we can imagine. In contrast, one type of very orderly and structured macrostate has all of the atoms in one corner of a container with identical velocities. There are very few ways to accomplish this (very few microstates corresponding to it), and so it is exceedingly unlikely ever to occur. (See [link] (b).) Indeed, it is so unlikely that we have a law saying that it is impossible, which has never been observed to be violated—the second law of thermodynamics.

The disordered condition is one of high entropy, and the ordered one has low entropy. With a transfer of energy from another system, we could force all of the atoms into one corner and have a local decrease in entropy, but at the cost of an overall increase in entropy of the universe. If the atoms start out in one corner, they will quickly disperse and become uniformly distributed and will never return to the orderly original state ( [link] (b)). Entropy will increase. With such a large sample of atoms, it is possible—but unimaginably unlikely—for entropy to decrease. Disorder is vastly more likely than order.

The arguments that disorder and high entropy are the most probable states are quite convincing. The great Austrian physicist Ludwig Boltzmann (1844–1906)—who, along with Maxwell, made so many contributions to kinetic theory—proved that the entropy of a system in a given state (a macrostate) can be written as

$S=k\text{ln}W\text{,}$

where $k=1\text{.}\text{38}×{\text{10}}^{-\text{23}}\phantom{\rule{0.25em}{0ex}}\text{J/K}$ is Boltzmann’s constant, and $\text{ln}W$ is the natural logarithm of the number of microstates $W$ corresponding to the given macrostate. $W$ is proportional to the probability that the macrostate will occur. Thus entropy is directly related to the probability of a state—the more likely the state, the greater its entropy. Boltzmann proved that this expression for $S$ is equivalent to the definition $\Delta S=Q/T$ , which we have used extensively.

Thus the second law of thermodynamics is explained on a very basic level: entropy either remains the same or increases in every process. This phenomenon is due to the extraordinarily small probability of a decrease, based on the extraordinarily larger number of microstates in systems with greater entropy. Entropy can decrease, but for any macroscopic system, this outcome is so unlikely that it will never be observed.

how many subject is in physics
the write question should be " How many Topics are in O- Level Physics, or other branches of physics.
effiom
how many topic are in physics
Praise
yh I need someone to explain something im tryna solve . I'll send the question if u down for it
a ripple tank experiment a vibrating plane is used to generate wrinkles in the water .if the distance between two successive point is 3.5cm and the wave travel a distance of 31.5cm find the frequency of the vibration
Tamdy
the range of objects and phenomena studied in physics is
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straight line motion is called linear motion
then what
Amera
linear motion is a motion in a line, be it in a straight line or in a non straight line. It is the rate of change of distance.
Saeedul
Hi
aliyu
Richard
Linear motion is a one-dimensional motion along a straight line, and can therefore be described mathematically using only one spatial dimension
Jason
is a one-dimensional motion along a straight line, and can therefore be described mathematically using only one spatial dimensions.
Praise
what is a classical electrodynamics?
Marga
what is dynamics
Marga
dynamic is the force that stimulates change or progress within the system or process
Oze
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machanical
Ridwan
Word : Mechanical wave Definition : The waves, which need a material medium for their propagation, e.g., Sound waves. \n\nOther Definition: The waves, which need a material medium for their propagation, are called mechanical waves. Mechanical waves are also called elastic waves. Sound waves, water waves are examples of mechanical waves.t Definition: wave consisting of periodic motion of matter; e.g. sound wave or water wave as opposed to electromagnetic wave.h
correct
Akinpelu
what is mechanical wave
a wave which require material medium for its propagation
syed
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watt
Okoli
Am I correct
Okoli
it can be in kilowatt, megawatt and so
Femi
yes
Femi
correct
Jaheim
kW
Akinpelu
OK that's right
Samuel
SI.unit of power is.watt=j/c.but kw.and Mw are bigger.umots
syed
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study of matter and its nature
Akinpelu
The word physics comes from a Greek word Physicos which means Nature.The Knowledge of Nature. It is branch of science which deals with the matter and energy and interaction between them.
Uniform
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reasonable
Femi
because it is balanced by the inward acceleration otherwise known as centripetal acceleration
MUSTAPHA
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Tramsmission of energy through a media
Mateo
is the disturbance that carry materials as propagation from one medium to another
Akinpelu
mistakes thanks
Akinpelu
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