# 15.7 Statistical interpretation of entropy and the second law of  (Page 2/8)

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The two most orderly possibilities are 5 heads or 5 tails. (They are more structured than the others.) They are also the least likely, only 2 out of 32 possibilities. The most disorderly possibilities are 3 heads and 2 tails and its reverse. (They are the least structured.) The most disorderly possibilities are also the most likely, with 20 out of 32 possibilities for the 3 heads and 2 tails and its reverse. If we start with an orderly array like 5 heads and toss the coins, it is very likely that we will get a less orderly array as a result, since 30 out of the 32 possibilities are less orderly. So even if you start with an orderly state, there is a strong tendency to go from order to disorder, from low entropy to high entropy. The reverse can happen, but it is unlikely.

100-coin toss
Macrostate Number of microstates
Heads Tails ( W )
100 0 1
99 1 $1\text{.}0×{\text{10}}^{2}$
95 5 $7\text{.}5×{\text{10}}^{7}$
90 10 $1\text{.}7×{\text{10}}^{\text{13}}$
75 25 $2\text{.}4×{\text{10}}^{\text{23}}$
60 40 $1\text{.}4×{\text{10}}^{\text{28}}$
55 45 $6\text{.}1×{\text{10}}^{\text{28}}$
51 49 $9\text{.}9×{\text{10}}^{\text{28}}$
50 50 $1\text{.}0×{\text{10}}^{\text{29}}$
49 51 $9\text{.}9×{\text{10}}^{\text{28}}$
45 55 $6\text{.}1×{\text{10}}^{\text{28}}$
40 60 $1\text{.}4×{\text{10}}^{\text{28}}$
25 75 $2\text{.}4×{\text{10}}^{\text{23}}$
10 90 $1\text{.}7×{\text{10}}^{\text{13}}$
5 95 $7\text{.}5×{\text{10}}^{7}$
1 99 $1\text{.}0×{\text{10}}^{2}$
0 100 1
Total: $1\text{.}\text{27}×{\text{10}}^{\text{30}}$

This result becomes dramatic for larger systems. Consider what happens if you have 100 coins instead of just 5. The most orderly arrangements (most structured) are 100 heads or 100 tails. The least orderly (least structured) is that of 50 heads and 50 tails. There is only 1 way (1 microstate) to get the most orderly arrangement of 100 heads. There are 100 ways (100 microstates) to get the next most orderly arrangement of 99 heads and 1 tail (also 100 to get its reverse). And there are $1.0×{\text{10}}^{\text{29}}$ ways to get 50 heads and 50 tails, the least orderly arrangement. [link] is an abbreviated list of the various macrostates and the number of microstates for each macrostate. The total number of microstates—the total number of different ways 100 coins can be tossed—is an impressively large $1\text{.}\text{27}×{\text{10}}^{\text{30}}$ . Now, if we start with an orderly macrostate like 100 heads and toss the coins, there is a virtual certainty that we will get a less orderly macrostate. If we keep tossing the coins, it is possible, but exceedingly unlikely, that we will ever get back to the most orderly macrostate. If you tossed the coins once each second, you could expect to get either 100 heads or 100 tails once in $2×{\text{10}}^{\text{22}}$ years! This period is 1 trillion ( ${\text{10}}^{\text{12}}$ ) times longer than the age of the universe, and so the chances are essentially zero. In contrast, there is an 8% chance of getting 50 heads, a 73% chance of getting from 45 to 55 heads, and a 96% chance of getting from 40 to 60 heads. Disorder is highly likely.

## Disorder in a gas

The fantastic growth in the odds favoring disorder that we see in going from 5 to 100 coins continues as the number of entities in the system increases. Let us now imagine applying this approach to perhaps a small sample of gas. Because counting microstates and macrostates involves statistics, this is called statistical analysis    . The macrostates of a gas correspond to its macroscopic properties, such as volume, temperature, and pressure; and its microstates correspond to the detailed description of the positions and velocities of its atoms. Even a small amount of gas has a huge number of atoms: of an ideal gas at 1.0 atm and $0º C$ has $2\text{.}7×{\text{10}}^{\text{19}}$ atoms. So each macrostate has an immense number of microstates. In plain language, this means that there are an immense number of ways in which the atoms in a gas can be arranged, while still having the same pressure, temperature, and so on.

#### Questions & Answers

yh I need someone to explain something im tryna solve . I'll send the question if u down for it
Tamdy Reply
a ripple tank experiment a vibrating plane is used to generate wrinkles in the water .if the distance between two successive point is 3.5cm and the wave travel a distance of 31.5cm find the frequency of the vibration
Tamdy
the range of objects and phenomena studied in physics is
Bethel Reply
what is Linear motion
Hamza Reply
straight line motion is called linear motion
then what
Amera
linear motion is a motion in a line, be it in a straight line or in a non straight line. It is the rate of change of distance.
Saeedul
Hi
aliyu
your are wrong Saeedul
Richard
Linear motion is a one-dimensional motion along a straight line, and can therefore be described mathematically using only one spatial dimension
Jason
what is the formula to calculate wavelength of the incident light
David Reply
if a spring is is stiffness of 950nm-1 what work will be done in extending the spring by 60mmp
Hassan Reply
State the forms of energy
Samzy Reply
machanical
Ridwan
Word : Mechanical wave Definition : The waves, which need a material medium for their propagation, e.g., Sound waves. \n\nOther Definition: The waves, which need a material medium for their propagation, are called mechanical waves. Mechanical waves are also called elastic waves. Sound waves, water waves are examples of mechanical waves.t Definition: wave consisting of periodic motion of matter; e.g. sound wave or water wave as opposed to electromagnetic wave.h
Clement Reply
correct
Akinpelu
what is mechanical wave
Akinpelu Reply
a wave which require material medium for its propagation
syed
The S.I unit for power is what?
Samuel Reply
watt
Okoli
Am I correct
Okoli
it can be in kilowatt, megawatt and so
Femi
yes
Femi
correct
Jaheim
kW
Akinpelu
OK that's right
Samuel
SI.unit of power is.watt=j/c.but kw.and Mw are bigger.umots
syed
What is physics
aish Reply
study of matter and its nature
Akinpelu
The word physics comes from a Greek word Physicos which means Nature.The Knowledge of Nature. It is branch of science which deals with the matter and energy and interaction between them.
Uniform
why in circular motion, a tangential acceleration can change the magnitude of the velocity but not its direction
Syafiqah Reply
reasonable
Femi
because it is balanced by the inward acceleration otherwise known as centripetal acceleration
MUSTAPHA
What is a wave
Mutuma Reply
Tramsmission of energy through a media
Mateo
is the disturbance that carry materials as propagation from one medium to another
Akinpelu
mistakes thanks
Akinpelu
find the triple product of (A*B).C given that A =i + 4j, B=2i - 3j and C = i + k
Favour Reply
Difference between north seeking pole and south seeking pole
Stanley Reply
if the earth Suddenly contract s then
Swami Reply
please formula for density is what
Akinpelu
mass/volume
Jaja

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