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  • State the expressions of the second law of thermodynamics.
  • Calculate the efficiency and carbon dioxide emission of a coal-fired electricity plant, using second law characteristics.
  • Describe and define the Otto cycle.
Photograph of melting ice floes in the Arctic.
These ice floes melt during the Arctic summer. Some of them refreeze in the winter, but the second law of thermodynamics predicts that it would be extremely unlikely for the water molecules contained in these particular floes to reform the distinctive alligator-like shape they formed when the picture was taken in the summer of 2009. (credit: Patrick Kelley, U.S. Coast Guard, U.S. Geological Survey)

The second law of thermodynamics deals with the direction taken by spontaneous processes. Many processes occur spontaneously in one direction only—that is, they are irreversible, under a given set of conditions. Although irreversibility is seen in day-to-day life—a broken glass does not resume its original state, for instance—complete irreversibility is a statistical statement that cannot be seen during the lifetime of the universe. More precisely, an irreversible process    is one that depends on path. If the process can go in only one direction, then the reverse path differs fundamentally and the process cannot be reversible. For example, as noted in the previous section, heat involves the transfer of energy from higher to lower temperature. A cold object in contact with a hot one never gets colder, transferring heat to the hot object and making it hotter. Furthermore, mechanical energy, such as kinetic energy, can be completely converted to thermal energy by friction, but the reverse is impossible. A hot stationary object never spontaneously cools off and starts moving. Yet another example is the expansion of a puff of gas introduced into one corner of a vacuum chamber. The gas expands to fill the chamber, but it never regroups in the corner. The random motion of the gas molecules could take them all back to the corner, but this is never observed to happen. (See [link] .)

Part a of the figure shows spontaneous heat transfers. A rectangular section is divided down the center, and then marked hot on the left end and cold on the right. Heat Q is shown to flow from the hot end to the cold end as shown by a bold arrow toward the right. Part b of the figure shows a car moving on a horizontal road toward the right with initial velocity v. The car brake is applied after some time. The final velocity v sub f is shown equal to zero. Heat is released by the car. Part c of the figure shows two parts. The first part shows a burst of gas let into a vacuum chamber using a sprayer. The molecules of gas are shown to move in a random manner shown as dashed zigzag arrows. The second part of the same diagram shows the next stage after the air burst is sprayed. The molecules of air are shown to be arranged in uniform distribution as shown by horizontal, parallel dashed curves in the medium.
Examples of one-way processes in nature. (a) Heat transfer occurs spontaneously from hot to cold and not from cold to hot. (b) The brakes of this car convert its kinetic energy to heat transfer to the environment. The reverse process is impossible. (c) The burst of gas let into this vacuum chamber quickly expands to uniformly fill every part of the chamber. The random motions of the gas molecules will never return them to the corner.

The fact that certain processes never occur suggests that there is a law forbidding them to occur. The first law of thermodynamics would allow them to occur—none of those processes violate conservation of energy. The law that forbids these processes is called the second law of thermodynamics. We shall see that the second law can be stated in many ways that may seem different, but which in fact are equivalent. Like all natural laws, the second law of thermodynamics gives insights into nature, and its several statements imply that it is broadly applicable, fundamentally affecting many apparently disparate processes.

Questions & Answers

what is displacement
Xolani Reply
movement in a direction
Jason
Explain why magnetic damping might not be effective on an object made of several thin conducting layers separated by insulation? can someone please explain this i need it for my final exam
anas Reply
Hi
saeid
hi
Yimam
What is thê principle behind movement of thê taps control
Oluwakayode Reply
what is atomic mass
thomas Reply
this is the mass of an atom of an element in ratio with the mass of carbon-atom
Chukwuka
show me how to get the accuracies of the values of the resistors for the two circuits i.e for series and parallel sides
Jesuovie Reply
Explain why it is difficult to have an ideal machine in real life situations.
Isaac Reply
tell me
Promise
what's the s . i unit for couple?
Promise
its s.i unit is Nm
Covenant
Force×perpendicular distance N×m=Nm
Oluwakayode
İt iş diffucult to have idêal machine because of FRİCTİON definitely reduce thê efficiency
Oluwakayode
if the classica theory of specific heat is valid,what would be the thermal energy of one kmol of copper at the debye temperature (for copper is 340k)
Zaharadeen Reply
can i get all formulas of physics
BPH Reply
yes
haider
what affects fluid
Doreen Reply
pressure
Oluwakayode
Dimension for force MLT-2
Promise Reply
what is the dimensions of Force?
Osueke Reply
how do you calculate the 5% uncertainty of 4cm?
melia Reply
4cm/100×5= 0.2cm
haider
how do you calculate the 5% absolute uncertainty of a 200g mass?
melia Reply
= 200g±(5%)10g
haider
use the 10g as the uncertainty?
melia
which topic u discussing about?
haider
topic of question?
haider
the relationship between the applied force and the deflection
melia
sorry wrong question i meant the 5% uncertainty of 4cm?
melia
its 0.2 cm or 2mm
haider
thank you
melia
Hello group...
Chioma
hi
haider
well hello there
sean
hi
Noks
hii
Chibueze
10g
Olokuntoye
0.2m
Olokuntoye
hi guys
thomas
the meaning of phrase in physics
Chovwe Reply
is the meaning of phrase in physics
Chovwe
write an expression for a plane progressive wave moving from left to right along x axis and having amplitude 0.02m, frequency of 650Hz and speed if 680ms-¹
Gabriel Reply
Practice Key Terms 4

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Source:  OpenStax, College physics. OpenStax CNX. Jul 27, 2015 Download for free at http://legacy.cnx.org/content/col11406/1.9
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