# 13.1 The first law of thermodynamics  (Page 6/9)

 Page 6 / 9

The first law of thermodynamics and the conservation of energy, as discussed in Conservation of Energy , are clearly related. How do they differ in the types of energy considered?

Heat transfer $Q$ and work done $W$ are always energy in transit, whereas internal energy $U$ is energy stored in a system. Give an example of each type of energy, and state specifically how it is either in transit or resides in a system.

How do heat transfer and internal energy differ? In particular, which can be stored as such in a system and which cannot?

If you run down some stairs and stop, what happens to your kinetic energy and your initial gravitational potential energy?

Give an explanation of how food energy (calories) can be viewed as molecular potential energy (consistent with the atomic and molecular definition of internal energy).

Identify the type of energy transferred to your body in each of the following as either internal energy, heat transfer, or doing work: (a) basking in sunlight; (b) eating food; (c) riding an elevator to a higher floor.

## Problems&Exercises

What is the change in internal energy of a car if you put 12.0 gal of gasoline into its tank? The energy content of gasoline is $1\text{.}3×{\text{10}}^{8}\phantom{\rule{0.25em}{0ex}}\text{J/gal}$ . All other factors, such as the car’s temperature, are constant.

$1\text{.}6×{\text{10}}^{9}\phantom{\rule{0.25em}{0ex}}\text{J}$

How much heat transfer occurs from a system, if its internal energy decreased by 150 J while it was doing 30.0 J of work?

A system does $1\text{.}\text{80}×{\text{10}}^{8}\phantom{\rule{0.25em}{0ex}}\text{J}$ of work while $7\text{.}\text{50}×{\text{10}}^{8}\phantom{\rule{0.25em}{0ex}}\text{J}$ of heat transfer occurs to the environment. What is the change in internal energy of the system assuming no other changes (such as in temperature or by the addition of fuel)?

$-9\text{.}\text{30}×{\text{10}}^{8}\phantom{\rule{0.25em}{0ex}}\text{J}$

What is the change in internal energy of a system which does $4\text{.}\text{50}×{\text{10}}^{5}\phantom{\rule{0.25em}{0ex}}\text{J}$ of work while $3\text{.}\text{00}×{\text{10}}^{6}\phantom{\rule{0.25em}{0ex}}\text{J}$ of heat transfer occurs into the system, and $8\text{.}\text{00}×{\text{10}}^{6}\phantom{\rule{0.25em}{0ex}}\text{J}$ of heat transfer occurs to the environment?

Suppose a woman does 500 J of work and 9500 J of heat transfer occurs into the environment in the process. (a) What is the decrease in her internal energy, assuming no change in temperature or consumption of food? (That is, there is no other energy transfer.) (b) What is her efficiency?

(a) $-1\text{.}0×{\text{10}}^{4}\phantom{\rule{0.25em}{0ex}}\text{J}$ , or $-2\text{.}\text{39 kcal}$

(b) 5.00%

(a) How much food energy will a man metabolize in the process of doing 35.0 kJ of work with an efficiency of 5.00%? (b) How much heat transfer occurs to the environment to keep his temperature constant? Explicitly show how you follow the steps in the Problem-Solving Strategy for thermodynamics found in Problem-Solving Strategies for Thermodynamics .

(a) What is the average metabolic rate in watts of a man who metabolizes 10,500 kJ of food energy in one day? (b) What is the maximum amount of work in joules he can do without breaking down fat, assuming a maximum efficiency of 20.0%? (c) Compare his work output with the daily output of a 187-W (0.250-horsepower) motor.

(a) 122 W

(b) $2\text{.}\text{10}×{\text{10}}^{6}\phantom{\rule{0.25em}{0ex}}\text{J}$

(c) Work done by the motor is $1\text{.}\text{61}×{\text{10}}^{7}\phantom{\rule{0.25em}{0ex}}\text{J}$ ;thus the motor produces 7.67 times the work done by the man

(a) How long will the energy in a 1470-kJ (350-kcal) cup of yogurt last in a woman doing work at the rate of 150 W with an efficiency of 20.0% (such as in leisurely climbing stairs)? (b) Does the time found in part (a) imply that it is easy to consume more food energy than you can reasonably expect to work off with exercise?

(a) A woman climbing the Washington Monument metabolizes $6\text{.}\text{00}×{\text{10}}^{2}\phantom{\rule{0.25em}{0ex}}\text{kJ}$ of food energy. If her efficiency is 18.0%, how much heat transfer occurs to the environment to keep her temperature constant? (b) Discuss the amount of heat transfer found in (a). Is it consistent with the fact that you quickly warm up when exercising?

(a) 492 kJ

(b) This amount of heat is consistent with the fact that you warm quickly when exercising. Since the body is inefficient, the excess heat produced must be dissipated through sweating, breathing, etc.

#### Questions & Answers

Is there any normative that regulates the use of silver nanoparticles?
what king of growth are you checking .?
Renato
What fields keep nano created devices from performing or assimulating ? Magnetic fields ? Are do they assimilate ?
why we need to study biomolecules, molecular biology in nanotechnology?
?
Kyle
yes I'm doing my masters in nanotechnology, we are being studying all these domains as well..
why?
what school?
Kyle
biomolecules are e building blocks of every organics and inorganic materials.
Joe
anyone know any internet site where one can find nanotechnology papers?
research.net
kanaga
sciencedirect big data base
Ernesto
Introduction about quantum dots in nanotechnology
what does nano mean?
nano basically means 10^(-9). nanometer is a unit to measure length.
Bharti
do you think it's worthwhile in the long term to study the effects and possibilities of nanotechnology on viral treatment?
absolutely yes
Daniel
how to know photocatalytic properties of tio2 nanoparticles...what to do now
it is a goid question and i want to know the answer as well
Maciej
characteristics of micro business
Abigail
for teaching engĺish at school how nano technology help us
Anassong
Do somebody tell me a best nano engineering book for beginners?
there is no specific books for beginners but there is book called principle of nanotechnology
NANO
what is fullerene does it is used to make bukky balls
are you nano engineer ?
s.
fullerene is a bucky ball aka Carbon 60 molecule. It was name by the architect Fuller. He design the geodesic dome. it resembles a soccer ball.
Tarell
what is the actual application of fullerenes nowadays?
Damian
That is a great question Damian. best way to answer that question is to Google it. there are hundreds of applications for buck minister fullerenes, from medical to aerospace. you can also find plenty of research papers that will give you great detail on the potential applications of fullerenes.
Tarell
what is the Synthesis, properties,and applications of carbon nano chemistry
Mostly, they use nano carbon for electronics and for materials to be strengthened.
Virgil
is Bucky paper clear?
CYNTHIA
carbon nanotubes has various application in fuel cells membrane, current research on cancer drug,and in electronics MEMS and NEMS etc
NANO
so some one know about replacing silicon atom with phosphorous in semiconductors device?
Yeah, it is a pain to say the least. You basically have to heat the substarte up to around 1000 degrees celcius then pass phosphene gas over top of it, which is explosive and toxic by the way, under very low pressure.
Harper
Do you know which machine is used to that process?
s.
how to fabricate graphene ink ?
for screen printed electrodes ?
SUYASH
What is lattice structure?
of graphene you mean?
Ebrahim
or in general
Ebrahim
in general
s.
Graphene has a hexagonal structure
tahir
On having this app for quite a bit time, Haven't realised there's a chat room in it.
Cied
what is biological synthesis of nanoparticles
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