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Introduction

The Lewis model of chemical bonding is one of the most powerful models in all of Chemistry. With the simple concepts of the octet rule and the sharing of an electron pair to form a chemical bond, we can predict what combinations of atoms and which molecular structures are likely to be stable or unstable. For example, we can predict that the molecular formula C 4 H 10 should correspond to a stable molecular structure, since it possible to draw a Lewis structure in which all four carbon atoms have an octet of valence electrons and each hydrogen atom has two valence electrons. In fact, we can even predict that there should be two such molecular structures corresponding to two different stable compounds, butane and methyl propane (often called isobutane). Lewis structures also allow us to predict the relative strengths and lengths of chemical bonds. For example, we can predict that in the molecule propene C 3 H 6 , one of the C-C bonds is a single bond and the other is a double bond; correspondingly, we can predict that the double bond is shorter and stronger than the single bond.

In general, for any molecule containing some combination of atoms of C, N, H, O, and any of the halogens (F, Cl, Br, or I), we can predict with confidence that the molecule will be a stable compound if we can draw a Lewis structure in which the C, N, O, and halogen atoms all have an octet of valence electrons. This is a very significant statement, since the overwhelming majority of the molecules of organic chemistry are composed of only these atoms. The converse is also generally true: if we cannot draw a Lewis structure in which these atoms have an octet of valence electrons, we will predict fairly confidently that a stable compound of that molecular formula probably does not exist. Note that “stable” does not mean “non-reactive.” In this context, “stable” means that the compound exists and can be isolated for long periods of time. Methane CH 4 is a stable compound which can be manufactured, captured, stored, and transported. However, it is also a reactive compound, reacting rapidly with oxygen gas in one of the most common combustion reactions in the world.

These are the reasons why we say that the Lewis structure model of covalent bonding is one of the most important models in all of Chemistry. However, like most good models, the understanding we get from the model comes with even more questions we might want to ask. In this Concept Development Study, we will address several of these, while others will wait for later studies. First, why does sharing a pair of electrons create a chemical bonding? More pointedly, what does it even mean to “share” an electron between two atoms? And why do atoms prefer to share a pair of electrons, rather than one or three? Of course, we’ve also seen that atoms can share more than one pair of electrons, creating double or triple bonds. We might have guessed that, with more electrons being shared, these electrons would repel each other, leading to a higher energy, but this is not the case. Why does sharing more than one pair of electrons produce a stronger bond?

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Source:  OpenStax, Concept development studies in chemistry 2013. OpenStax CNX. Oct 07, 2013 Download for free at http://legacy.cnx.org/content/col11579/1.1
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