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A material contains many atoms and their arrangement affects the magnetization of that material. In [link] (a) a magnetic moment m is contained in unit volume. This has a magnetization of m Am. [link] (b) shows two such units, with the moments aligned parallel. The vector sum of moments is 2m in this case, but as the both the moment and volume are doubled M remains the same. In [link] (c) the moments are aligned antiparallel. The vector sum of moments is now 0 and hence the magnetization is 0 Am.

Effect of moment alignment on magnetization: (a) Single magnetic moment, (b) two identical moments aligned parallel and (c) antiparallel to each other. Adapted from J. Bland Thesis M. Phys (Hons)., 'A Mossbauer spectroscopy and magnetometry study of magnetic multilayers and oxides.' Oliver Lodge Labs, Dept. Physics, University of Liverpool

Scenarios (b) and (c) are a simple representation of ferro- and antiferromagnetic ordering. Hence we would expect a large magnetization in a ferromagnetic material such as pure iron and a small magnetization in an antiferromagnet such as γ-Fe 2 O 3

Magnetic response

When a material is passed through a magnetic field it is affected in two ways:

  1. Through its susceptibility.
  2. Through its permeability.

Magnetic susceptibility

The concept of magnetic moment is the starting point when discussing the behavior of magnetic materials within a field. If you place a bar magnet in a field it will experience a torque or moment tending to align its axis in the direction of the field. A compass needle behaves in the same way. This torque increases with the strength of the poles and their distance apart. So the value of magnetic moment tells you, in effect, 'how big a magnet' you have.

Schematic representation of the torque or moment that a magnet experiences when it is placed in a magnetic field. The magnetic will try to align with the magnetic field.

If you place a material in a weak magnetic field, the magnetic field may not overcome the binding energies that keep the material in a non magnetic state. This is because it is energetically more favorable for the material to stay exactly the same. However, if the strength of the magnetic moment is increased, the torque acting on the smaller moments in the material, it may become energetically more preferable for the material to become magnetic. The reasons that the material becomes magnetic depends on factors such as crystal structure the temperature of the material and the strength of the field that it is in. However a simple explanation of this is that as the magnetic moment strength increases it becomes more favorable for the small fields to align themselves along the path of the magnetic field, instead of being opposed to the system. For this to occur the material must rearrange its magnetic makeup at the atomic level to lower the energy of the system and restore a balance.

It is important to remember that when we consider the magnetic susceptibility and take into account how a material changes on the atomic level when it is placed in a magnetic field with a certain moment. The moment that we are measuring with our magnetometer is the total moment of that sample.

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Source:  OpenStax, Nanomaterials and nanotechnology. OpenStax CNX. May 07, 2014 Download for free at http://legacy.cnx.org/content/col10700/1.13
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