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ICP-AES is a spectral technique that is used to both determine the presence of metal analyte and the concentrations thereof. The ICP-AES method is introduced and a practical example is presented. This will help the reader to use this method for their own research work.

What is icp-aes?

Inductively coupled plasma atomic emission spectroscopy (ICP-AES) is a spectral method used to determine very precisely the elemental composition of samples; it can also be used to quantify the elemental concentration with the sample. ICP-AES uses high-energy plasma from an inert gas like argon to burn analytes very rapidly. The color that is emitted from the analyte is indicative of the elements present, and the intensity of the spectral signal is indicative of the concentration of the elements that is present. A schematic view of a typical experimental set-up is shown in [link] .

Schematic representation of an ICP-AES set-up.

How does icp-aes work?

ICP-AES works by the emission of photons from analytes that are brought to an excited state by the use of high-energy plasma. The plasma source is induced when passing argon gas through an alternating electric field that is created by an inductively couple coil. When the analyte is excited the electrons try to dissipate the induced energy moving to a ground state of lower energy, in doing this they emit the excess energy in the form of light. The wavelength of light emitted depends on the energy gap between the excited energy level and the ground state. This is specific to the element based on the number of electrons the element has and electron orbital’s are filled. In this way the wavelength of light can be used to determine what elements are present by detection of the light at specific wavelengths.

As a simple example consider the situation when placing a piece of copper wire into the flame of a candle. The flame turns green due to the emission of excited electrons within the copper metal, as the electrons try to dissipate the energy incurred from the flame, they move to a more stable state emitting energy in the form of light. The energy gap between the excited state to the ground state (ΔE) dictates the color of the light or wavelength of the light, [link] , where h is Plank's constant (6.626×10 -34 m 2 kg/s), and ν is the frequency of the emitted light.

The wavelength of light is indicative of the element present. If another metal is placed in the flame such as iron a different color flame will be emitted because the electronic structure of iron is different from that of copper. This is a very simple analogy for what is happening in ICP-AES and how it is used to determine what elements are present. By detecting the wavelength of light that is emitted from the analyte one can deduce what elements are be present.

Naturally if there is a lot of the material present then there will be an accumulative effect making the intensity of the signal large. However, if there were very little materials present the signal would be low. By this rationale one can create a calibration curve from analyte solutions of known concentrations, whereby the intensity of the signal changes as a function of the concentration of the material that is present. When measuring the intensity from a sample of unknown concentration the intensity from this sample can be compared to that from the calibration curve, so this can be used to determine the concentration of the analytes within the sample.

Questions & Answers

where we get a research paper on Nano chemistry....?
Maira Reply
what are the products of Nano chemistry?
Maira Reply
There are lots of products of nano chemistry... Like nano coatings.....carbon fiber.. And lots of others..
learn
Even nanotechnology is pretty much all about chemistry... Its the chemistry on quantum or atomic level
learn
Google
da
no nanotechnology is also a part of physics and maths it requires angle formulas and some pressure regarding concepts
Bhagvanji
Preparation and Applications of Nanomaterial for Drug Delivery
Hafiz Reply
revolt
da
Application of nanotechnology in medicine
what is variations in raman spectra for nanomaterials
Jyoti Reply
I only see partial conversation and what's the question here!
Crow Reply
what about nanotechnology for water purification
RAW Reply
please someone correct me if I'm wrong but I think one can use nanoparticles, specially silver nanoparticles for water treatment.
Damian
yes that's correct
Professor
I think
Professor
Nasa has use it in the 60's, copper as water purification in the moon travel.
Alexandre
nanocopper obvius
Alexandre
what is the stm
Brian Reply
is there industrial application of fullrenes. What is the method to prepare fullrene on large scale.?
Rafiq
industrial application...? mmm I think on the medical side as drug carrier, but you should go deeper on your research, I may be wrong
Damian
How we are making nano material?
LITNING Reply
what is a peer
LITNING Reply
What is meant by 'nano scale'?
LITNING Reply
What is STMs full form?
LITNING
scanning tunneling microscope
Sahil
how nano science is used for hydrophobicity
Santosh
Do u think that Graphene and Fullrene fiber can be used to make Air Plane body structure the lightest and strongest. Rafiq
Rafiq
what is differents between GO and RGO?
Mahi
what is simplest way to understand the applications of nano robots used to detect the cancer affected cell of human body.? How this robot is carried to required site of body cell.? what will be the carrier material and how can be detected that correct delivery of drug is done Rafiq
Rafiq
if virus is killing to make ARTIFICIAL DNA OF GRAPHENE FOR KILLED THE VIRUS .THIS IS OUR ASSUMPTION
Anam
analytical skills graphene is prepared to kill any type viruses .
Anam
Any one who tell me about Preparation and application of Nanomaterial for drug Delivery
Hafiz
what is Nano technology ?
Bob Reply
write examples of Nano molecule?
Bob
The nanotechnology is as new science, to scale nanometric
brayan
nanotechnology is the study, desing, synthesis, manipulation and application of materials and functional systems through control of matter at nanoscale
Damian
Is there any normative that regulates the use of silver nanoparticles?
Damian Reply
what king of growth are you checking .?
Renato
What fields keep nano created devices from performing or assimulating ? Magnetic fields ? Are do they assimilate ?
Stoney Reply
why we need to study biomolecules, molecular biology in nanotechnology?
Adin Reply
?
Kyle
yes I'm doing my masters in nanotechnology, we are being studying all these domains as well..
Adin
why?
Adin
what school?
Kyle
biomolecules are e building blocks of every organics and inorganic materials.
Joe

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Source:  OpenStax, Nanomaterials and nanotechnology. OpenStax CNX. May 07, 2014 Download for free at http://legacy.cnx.org/content/col10700/1.13
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