# 13.5 Phase changes  (Page 4/15)

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## Vapor pressure, partial pressure, and dalton’s law

Vapor pressure is defined as the pressure at which a gas coexists with its solid or liquid phase. Vapor pressure is created by faster molecules that break away from the liquid or solid and enter the gas phase. The vapor pressure of a substance depends on both the substance and its temperature—an increase in temperature increases the vapor pressure.

Partial pressure is defined as the pressure a gas would create if it occupied the total volume available. In a mixture of gases, the total pressure is the sum of partial pressures of the component gases , assuming ideal gas behavior and no chemical reactions between the components. This law is known as Dalton’s law of partial pressures    , after the English scientist John Dalton (1766–1844), who proposed it. Dalton’s law is based on kinetic theory, where each gas creates its pressure by molecular collisions, independent of other gases present. It is consistent with the fact that pressures add according to Pascal’s Principle . Thus water evaporates and ice sublimates when their vapor pressures exceed the partial pressure of water vapor in the surrounding mixture of gases. If their vapor pressures are less than the partial pressure of water vapor in the surrounding gas, liquid droplets or ice crystals (frost) form.

Is energy transfer involved in a phase change? If so, will energy have to be supplied to change phase from solid to liquid and liquid to gas? What about gas to liquid and liquid to solid? Why do they spray the orange trees with water in Florida when the temperatures are near or just below freezing?

Yes, energy transfer is involved in a phase change. We know that atoms and molecules in solids and liquids are bound to each other because we know that force is required to separate them. So in a phase change from solid to liquid and liquid to gas, a force must be exerted, perhaps by collision, to separate atoms and molecules. Force exerted through a distance is work, and energy is needed to do work to go from solid to liquid and liquid to gas. This is intuitively consistent with the need for energy to melt ice or boil water. The converse is also true. Going from gas to liquid or liquid to solid involves atoms and molecules pushing together, doing work and releasing energy.

## Phet explorations: states of matter—basics

Heat, cool, and compress atoms and molecules and watch as they change between solid, liquid, and gas phases.

## Section summary

• Most substances have three distinct phases: gas, liquid, and solid.
• Phase changes among the various phases of matter depend on temperature and pressure.
• The existence of the three phases with respect to pressure and temperature can be described in a phase diagram.
• Two phases coexist (i.e., they are in thermal equilibrium) at a set of pressures and temperatures. These are described as a line on a phase diagram.
• The three phases coexist at a single pressure and temperature. This is known as the triple point and is described by a single point on a phase diagram.
• A gas at a temperature below its boiling point is called a vapor.
• Vapor pressure is the pressure at which a gas coexists with its solid or liquid phase.
• Partial pressure is the pressure a gas would create if it existed alone.
• Dalton’s law states that the total pressure is the sum of the partial pressures of all of the gases present.

## Conceptual questions

A pressure cooker contains water and steam in equilibrium at a pressure greater than atmospheric pressure. How does this greater pressure increase cooking speed?

Why does condensation form most rapidly on the coldest object in a room—for example, on a glass of ice water?

What is the vapor pressure of solid carbon dioxide (dry ice) at $–\text{78}\text{.}5\text{º}\text{C}$ ?

Can carbon dioxide be liquefied at room temperature ( $\text{20}\text{º}\text{C}$ )? If so, how? If not, why not? (See [link] .)

Oxygen cannot be liquefied at room temperature by placing it under a large enough pressure to force its molecules together. Explain why this is.

What is the distinction between gas and vapor?

Why is the sky blue...?
It's filtered light from the 2 forms of radiation emitted from the sun. It's mainly filtered UV rays. There's a theory titled Scatter Theory that covers this topic
Mike
A heating coil of resistance 30π is connected to a 240v supply for 5min to boil a quantity of water in a vessel of heat capacity 200jk. If the initial temperature of water is 20°c and it specific heat capacity is 4200jkgk calculate the mass of water in a vessel
A thin equi convex lens is placed on a horizontal plane mirror and a pin held 20 cm vertically above the lens concise in position with its own image the space between the undersurface of d lens and the mirror is filled with water (refractive index =1•33)and then to concise with d image d pin has to
Be raised until its distance from d lens is 27cm find d radius of curvature
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A monkey throws a coconut straight upwards from a coconut tree with a velocity of 10 ms-1. The coconut tree is 30 m high. Calculate the maximum height of the coconut from the top of the coconut tree? Can someone answer my question
v2 =u2 - 2gh 02 =10x10 - 2x9.8xh h = 100 ÷ 19.6 answer = 30 - h.
Ramonyai
why is the north side is always referring to n side of magnetic
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A nurse is a person who takes care of the sick
Bukola
a nurse is also like an assistant to the doctor
explain me wheatstone bridge
good app
samuel
Wheatstone bridge is an instrument used to measure an unknown electrical resistance by balancing two legs of a bridge circuit, one leg of which includes the unknown component.
MUHD
Rockwell Software is Rockwell Automation’s "Retro Encabulator". Now, basically the only new principle involved is that instead of power being generated by the relative motion of conductors and fluxes, it’s produced by the modial interaction of magneto-reluctance and capacitive diractance. The origin
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Who knows the formula for binding energy,and what each variable or notation stands for?
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G is the u. constant, as g stands for grav, accelerate at a discreet point
Mark
Olaiya
pls explain in details
Olaiya
G is a universal constant
Mark
g stands for the gravitational acceleration point. hope this helps you.
Mark
balloon TD is at a gravitational acceleration at a specific point
Mark
I'm sorry this doesn't take dictation very well.
Mark
Can anyone explain the Hooke's law of elasticity?
extension of a spring is proportional to the force applied so long as the force applied does not exceed the springs capacity according to my textbook
Amber
does this help?
Amber
Yes, thanks
Olaiya
so any solid can be compressed how compressed is dependent upon how much force is applied F=deltaL
Amber
sorry, the equation is F=KdeltaL delta is the triangle symbol and L is length so the change in length is proportional to amount of Force applied I believe that is what Hookes law means. anyone catch any mistakes here please correct me :)
Amber
I think it is used only for solids and not liquids, isn't it?
Olaiya
basically as long as you dont exceed the elastic limit the object should return to it original form but if you exceed this limit the object will not return to original shape as it will break
Amber
Thanks for the explanation
Olaiya
yh, liquids don't apply here, that should be viscosity
Chiamaka
hope it helps 😅
Amber
also, an object doesnt have to break necessarily, but it will have a new form :)
Amber
Yes
Olaiya
yeah, I think it is for solids but maybe there is a variation for liquids? that I am not sure of
Amber
ok
Olaiya
good luck!
Amber
Same
Olaiya
aplease i need a help on spcific latent heat of vibrations
Bilgate
specific latent heat of vaporisation
Bilgate
how many kilometers makes a mile
Faizyab
Aakash
equal to 1.609344 kilometers.
MUHD