<< Chapter < Page Chapter >> Page >

X-ray photoelectron spectroscopy (xps)

XPS confirms the presence of different elements in functionalized SWNTs. This is useful for identification of heteroatom elements such as F and N, and then XPS can be used for quantification with simple substituent groups and used indirectly. Deconvolution of XPS is useful to study fine structures on SWNTs. However, the overlapping of binding energies in the spectrum complicates quantification.


Raman spectroscopy

Raman spectroscopy is very informative and important for characterizing functionalized SWNTs. The tangential G mode ( ca . 1550 – 1600 cm -1 ) is characteristic of sp 2 carbons on the hexagonal graphene network. The D-band, so-called disorder mode (found at ca . 1295 cm -1 ) appears due to disruption of the hexagonal sp 2 network of SWNTs. The D-band was largely used to characterize functionalized SWNTs and ensure functionalization is covalent and occurred at the sidewalls. However, the observation of D band in Raman can also be related to presence of defects such as vacancies, 5-7 pairs, or dopants. Thus, using Raman to provide evidence of covalent functionalization needs to be done with caution. In particular, the use of Raman spectroscopy for a determination of the degree of functionalization is not reliable.

It has been shown that quantification with Raman is complicated by the distribution of functional groups on the sidewall of SWNTs. For example, if fluorinated-SWNTs (F-SWNTs) are functionalized with thiol or thiophene terminated moieties, TGA shows that they have similar level of functionalization. However, their relative intensities of D:G in Raman spectrum are quite different. The use of sulfur substituents allow for gold nanoparticles with 5 nm in diameter to be attached as a “chemical marker” for direct imaging of the distribution of functional groups. AFM and STM suggest that the functional groups of thio-SWNTs are group together while the thiophene groups are widely distributed on the sidewall of SWNTs. Thus the difference is not due to significant difference in substituent concentration but on substituent distribution, while Raman shows different D:G ratio.

Infra red spectroscopy

IR spectroscopy is useful in characterizing functional groups bound to SWNTs. A variety of organic functional groups on sidewall of SWNTs have been identified by IR, such as COOH(R), -CH 2 , -CH 3 , -NH 2 , -OH, etc. However, it is difficult to get direct functionalization information from IR spectroscopy. The C-F group has been identified by IR in F-SWNTs. However, C-C, C-N, C-O groups associated with the side-wall functionalization have not been observed in the appropriately functionalized SWNTs.

Uv/visible spectroscopy

UV/visible spectroscopy is maybe the most accessible technique that provides information about the electronic states of SWNTs, and hence functionalization. The absorption spectrum shows bands at ca . 1400 nm and 1800 nm for pristine SWNTs. A complete loss of such structure is observed after chemical alteration of SWNTs sidewalls. However, such information is not quantitative and also does not show what type of functional moiety is on the sidewall of SWNTs.

Questions & Answers

where is the pectoral gridle located?
Tiania Reply
What is hypotonic
Bright Reply
the difference between the two cells
Obeng Reply
explain the courses and the correction of lon term sightedness and short term sightedness
Isaac Reply
why drinking excess alcohol causes thirst and dehydration
uwikuzo Reply
what is reproduction
smart Reply
it is d act of bringing young ones to life
to ensure survival of a species🚴‍♀️
what is a genotype
what is hazardous
a cell is the smallest unit of a living thing. so we all have cell
It is the formation of a zygote resulting from the fusion of the sperm cell with the ovum.Thus,this results in the production of new species which are genetically dissimilar from their parent cells.
what is size of cell
Mohd Reply
what is size of Hart
nanometers=um sign thingie
monomers and polymers of nucleic acids?
Jyrl Reply
dna and rna involvement
give me the elements of the soil
Iguma Reply
Air, water, organic matter, inorganic matter
soil water humus air
silica, iron
potassium, sulfur, calcium, carbon
what is cell
iyaji Reply
A cell is a smallest fundamental unit of a living organisms.
the basic structural and functional unit of life
what is size of cell
all things are made up of.....all things cannot exist without pre-exisiting cells...check out the 16th ce tury to learn more about microscope use and cells. i will give a hint: Mr. L.
we are all made of cells
Nutrition - sensitive intervention
Therowda Reply
what does the sori In fern mean
arhin Reply
biology is the study .exactly what is life?
i'm sorry , the study of life
how can U identify a person through his blood
Frankyx Reply
through genetic fingerprinting where specific DNA sequences in a person genome can be identified.
by help of genetics and DNA test
can it also be detected using an RNA test
environmental biology
Ojesola Reply
what is phytoplankton
What is anabolism
Treasure Reply
the break down of substance
what does post-translational control refer to?
Teresa Reply
Bioremediation includes
Rachel Reply
advantages of NAA
Sai Reply
how I can reaction of mercury?
Sham Reply

Get the best Physical methods in ch... course in your pocket!

Source:  OpenStax, Physical methods in chemistry and nano science. OpenStax CNX. May 05, 2015 Download for free at http://legacy.cnx.org/content/col10699/1.21
Google Play and the Google Play logo are trademarks of Google Inc.

Notification Switch

Would you like to follow the 'Physical methods in chemistry and nano science' conversation and receive update notifications?