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The synthesis and reactivity of atomic hydrogen

Atomic hydrogen has the electron configuration of 1s 1 and as such represents the simplest atomic configuration. However, as a consequence there is dispute as to its proper position within the Periodic Table. Its electron configuration is similar to the valence electron configuration of the alkali metals (ns 1 ) suggesting it be listed at the top of Group 1 (1A). However, its reaction chemistry is dissimilar to the alkali metals. Hydrogen is also one electron short of a Nobel gas configuration, and therefore it is possible to think of its relationship to the halogens.

Vapor phase

Atomic hydrogen (H . ) is highly reactive and consequently has a short lifetime due to its reaction chemistry. Consequently, in order to generate and observe the reactivity they must be generate at low pressures. Thermolysis of hydrogen compound (commonly halide) or photolysis at an energy above the bond dissociation energy results in the homoleptic cleavage of the H-X bond to generate the appropriate radical species.

Alternatively, atomic hydrogen can be generated from elemental hydrogen.

The reverse reaction (recombination of two hydrogen atoms) is highly exothermic (-434 kJ.mol -1 ) and forms the basis of the heat generated in arc welding.


Atomic hydrogen may be generated in aqueous solution through the solvation of electrons.

The formation equilibrium constant (K eq ) is very small resulting in very low concentrations being generated (10 -5 M). As expected solvated atomic hydrogen is a strong reducing agent.

Solid state

Hydrogen atoms may be trapped in the solid state lattice upon generation by photolysis of HX. Observation by electron spin resonance (esr) of a signal split by s = 1 / 2 nucleus (i.e., 1 H) results in a doublet with a coupling of 1428 MHz.

Questions & Answers

Is there any normative that regulates the use of silver nanoparticles?
Damian Reply
what king of growth are you checking .?
What fields keep nano created devices from performing or assimulating ? Magnetic fields ? Are do they assimilate ?
Stoney Reply
why we need to study biomolecules, molecular biology in nanotechnology?
Adin Reply
yes I'm doing my masters in nanotechnology, we are being studying all these domains as well..
what school?
biomolecules are e building blocks of every organics and inorganic materials.
anyone know any internet site where one can find nanotechnology papers?
Damian Reply
sciencedirect big data base
Introduction about quantum dots in nanotechnology
Praveena Reply
what does nano mean?
Anassong Reply
nano basically means 10^(-9). nanometer is a unit to measure length.
do you think it's worthwhile in the long term to study the effects and possibilities of nanotechnology on viral treatment?
Damian Reply
absolutely yes
how to know photocatalytic properties of tio2 nanoparticles...what to do now
Akash Reply
it is a goid question and i want to know the answer as well
characteristics of micro business
for teaching engĺish at school how nano technology help us
Do somebody tell me a best nano engineering book for beginners?
s. Reply
there is no specific books for beginners but there is book called principle of nanotechnology
what is fullerene does it is used to make bukky balls
Devang Reply
are you nano engineer ?
fullerene is a bucky ball aka Carbon 60 molecule. It was name by the architect Fuller. He design the geodesic dome. it resembles a soccer ball.
what is the actual application of fullerenes nowadays?
That is a great question Damian. best way to answer that question is to Google it. there are hundreds of applications for buck minister fullerenes, from medical to aerospace. you can also find plenty of research papers that will give you great detail on the potential applications of fullerenes.
what is the Synthesis, properties,and applications of carbon nano chemistry
Abhijith Reply
Mostly, they use nano carbon for electronics and for materials to be strengthened.
is Bucky paper clear?
carbon nanotubes has various application in fuel cells membrane, current research on cancer drug,and in electronics MEMS and NEMS etc
so some one know about replacing silicon atom with phosphorous in semiconductors device?
s. Reply
Yeah, it is a pain to say the least. You basically have to heat the substarte up to around 1000 degrees celcius then pass phosphene gas over top of it, which is explosive and toxic by the way, under very low pressure.
Do you know which machine is used to that process?
how to fabricate graphene ink ?
for screen printed electrodes ?
What is lattice structure?
s. Reply
of graphene you mean?
or in general
in general
Graphene has a hexagonal structure
On having this app for quite a bit time, Haven't realised there's a chat room in it.
what is biological synthesis of nanoparticles
Sanket Reply
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Source:  OpenStax, Hydrogen. OpenStax CNX. Sep 28, 2009 Download for free at http://cnx.org/content/col10984/1.4
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