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Would the previous question make any sense for an isochoric process? Explain your answer.

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We ordinarily say that Δ U = 0 size 12{DU=0} {} for an isothermal process. Does this assume no phase change takes place? Explain your answer.

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The temperature of a rapidly expanding gas decreases. Explain why in terms of the first law of thermodynamics. (Hint: Consider whether the gas does work and whether heat transfer occurs rapidly into the gas through conduction.)

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Which cyclical process represented by the two closed loops, ABCFA and ABDEA, on the PV size 12{ ital "PV"} {} diagram in the figure below produces the greatest net work? Is that process also the one with the smallest work input required to return it to point A? Explain your responses.

The figure shows a graph of pressure versus volume. The pressure is along the Y axis and the volume is plotted along the X axis. The graph consists of a rectangle, A B C F, superimposed on a slightly larger rectangle, A B D E. The lines A B, C F, and D E are parallel to the X axis and lines B C D and A F E are parallel to the Y axis.
The two cyclical processes shown on this PV diagram start with and return the system to the conditions at point A, but they follow different paths and produce different amounts of work.
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A real process may be nearly adiabatic if it occurs over a very short time. How does the short time span help the process to be adiabatic?

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It is unlikely that a process can be isothermal unless it is a very slow process. Explain why. Is the same true for isobaric and isochoric processes? Explain your answer.

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Problem exercises

A car tire contains 0 . 0380 m 3 size 12{0 "." "0380"" m" rSup { size 8{3} } } {} of air at a pressure of 2 . 20 × 10 5 N/m 2 size 12{2 "." "20"´"10" rSup { size 8{5} } " N/m" rSup { size 8{2} } } {} (about 32 psi). How much more internal energy does this gas have than the same volume has at zero gauge pressure (which is equivalent to normal atmospheric pressure)?

6 . 77 × 10 3 J size 12{6 "." "77" times "10" rSup { size 8{3} } `J} {}

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A helium-filled toy balloon has a gauge pressure of 0.200 atm and a volume of 10.0 L. How much greater is the internal energy of the helium in the balloon than it would be at zero gauge pressure?

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Steam to drive an old-fashioned steam locomotive is supplied at a constant gauge pressure of 1 . 75 × 10 6 N/m 2 size 12{1 "." "75"´"10" rSup { size 8{6} } " N/m" rSup { size 8{2} } } {} (about 250 psi) to a piston with a 0.200-m radius. (a) By calculating P Δ V size 12{PDV} {} , find the work done by the steam when the piston moves 0.800 m. Note that this is the net work output, since gauge pressure is used. (b) Now find the amount of work by calculating the force exerted times the distance traveled. Is the answer the same as in part (a)?

(a) W = P Δ V = 1 . 76 × 10 5 J size 12{W=PΔV= {underline {1 "." "76" times "10" rSup { size 8{5} } " J"}} } {}

(b) W = Fd = 1 . 76 × 10 5 J size 12{W= ital "Fd"= ital "PAd"= {underline {1 "." "76" times "10" rSup { size 8{5} } " J"}} } {} . Yes, the answer is the same.

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A hand-driven tire pump has a piston with a 2.50-cm diameter and a maximum stroke of 30.0 cm. (a) How much work do you do in one stroke if the average gauge pressure is 2 . 40 × 10 5 N/m 2 size 12{2 "." "40"´"10" rSup { size 8{5} } " N/m" rSup { size 8{2} } } {} (about 35 psi)? (b) What average force do you exert on the piston, neglecting friction and gravitational force?

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Calculate the net work output of a heat engine following path ABCDA in the figure below.

A graph is shown of pressure versus volume, with pressure on the Y axis and volume on the X axis. A parallelogram connects four points are on the graph, A, B, C, and D. A is at y equals 2 point 6 times 10 to the six newtons per meter squared and x equals 1 point zero times ten to the minus three meters cubed. A downward sloping line connects A to B. B is at y equals 2 point zero, x equals four. A vertical line connects B to C. C is at y equals zero point 6, x equals 4. A line connects C to D. D is at y equals one point zero, x equals one point zero. A vertical line connects D to A. A diagonal line also connects D and B.

W = 4 . 5 × 10 3 J size 12{W=4 "." 5 times "10" rSup { size 8{3} } `J} {}

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What is the net work output of a heat engine that follows path ABDA in the figure above, with a straight line from B to D? Why is the work output less than for path ABCDA? Explicitly show how you follow the steps in the Problem-Solving Strategies for Thermodynamics .

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Unreasonable Results

What is wrong with the claim that a cyclical heat engine does 4.00 kJ of work on an input of 24.0 kJ of heat transfer while 16.0 kJ of heat transfers to the environment?

W size 12{W} {} is not equal to the difference between the heat input and the heat output.

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(a) A cyclical heat engine, operating between temperatures of 450º C size 12{"450"°C} {} and 150º C size 12{"150"°C} {} produces 4.00 MJ of work on a heat transfer of 5.00 MJ into the engine. How much heat transfer occurs to the environment? (b) What is unreasonable about the engine? (c) Which premise is unreasonable?

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Construct Your Own Problem

Consider a car’s gasoline engine. Construct a problem in which you calculate the maximum efficiency this engine can have. Among the things to consider are the effective hot and cold reservoir temperatures. Compare your calculated efficiency with the actual efficiency of car engines.

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Construct Your Own Problem

Consider a car trip into the mountains. Construct a problem in which you calculate the overall efficiency of the car for the trip as a ratio of kinetic and potential energy gained to fuel consumed. Compare this efficiency to the thermodynamic efficiency quoted for gasoline engines and discuss why the thermodynamic efficiency is so much greater. Among the factors to be considered are the gain in altitude and speed, the mass of the car, the distance traveled, and typical fuel economy.

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Questions & Answers

What is the difference between a principle and a law
the law is universally proved. The principal depends on certain conditions.
Dr
state Faraday first law
aliyu Reply
it states that mass of an element deposited during electrolysis is directly proportional to the quantity of electricity discharge
Olamide
what does the speedometer of a car measure ?
Jyoti Reply
Car speedometer measures the rate of change of distance per unit time.
Moses
describe how a Michelson interferometer can be used to measure the index of refraction of a gas (including air)
WILLIAM Reply
using the law of reflection explain how powder takes the shine off a person's nose. what is the name of the optical effect?
WILLIAM
is higher resolution of microscope using red or blue light?.explain
WILLIAM
what is dimensional consistent
Mohammed
In engineering and science, dimensional analysis is the analysis of the relationships between different physical quantities by identifying their base quantities and units of measure and tracking these dimensions as calculations or comparisons are performed
syed
can sound wave in air be polarized?
WILLIAM Reply
Unlike transverse waves such as electromagnetic waves, longitudinal waves such as sound waves cannot be polarized. ... Since sound waves vibrate along their direction of propagation, they cannot be polarized
Astronomy
A proton moves at 7.50×107m/s perpendicular to a magnetic field. The field causes the proton to travel in a circular path of radius 0.800 m. What is the field strength?
Celedonio Reply
derived dimenionsal formula
Ajak Reply
what is the difference between mass and weight
Isru Reply
assume that a boy was born when his father was eighteen years.if the boy is thirteen years old now, how is his father in
Isru
31yrs
Olamide
what is head-on collision
Javaid Reply
what is airflow
Godswill Reply
derivative of first differential equation
Haruna Reply
why static friction is greater than Kinetic friction
Ali Reply
draw magnetic field pattern for two wire carrying current in the same direction
Ven Reply
An American traveler in New Zealand carries a transformer to convert New Zealand’s standard 240 V to 120 V so that she can use some small appliances on her trip.
nkombo Reply
What is the ratio of turns in the primary and secondary coils of her transformer?
nkombo
what is energy
Yusuf
How electric lines and equipotential surface are mutually perpendicular?
Abid Reply
The potential difference between any two points on the surface is zero that implies È.Ŕ=0, Where R is the distance between two different points &E= Electric field intensity. From which we have cos þ =0, where þ is the angle between the directions of field and distance line, as E andR are zero. Thus
MAHADEV
sorry..E and R are non zero...
MAHADEV
Practice Key Terms 6

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Source:  OpenStax, College physics. OpenStax CNX. Jul 27, 2015 Download for free at http://legacy.cnx.org/content/col11406/1.9
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