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CoO ( s ) + 2HNO 3 ( a q ) Co ( NO 3 ) 2 ( a q ) + H 2 O ( l )
Sc 2 O 3 ( s ) + 6HCl ( a q ) 2ScCl 3 ( a q ) + 3H 2 O ( l )

The oxides of metals with oxidation states of 4+ are amphoteric, and most are not soluble in either acids or bases. Vanadium(V) oxide, chromium(VI) oxide, and manganese(VII) oxide are acidic. They react with solutions of hydroxides to form salts of the oxyanions VO 4 3− , CrO 4 2− , and MnO 4 . For example, the complete ionic equation for the reaction of chromium(VI) oxide with a strong base is given by:

CrO 3 ( s ) + 2Na + ( a q ) + 2OH ( a q ) 2Na + ( a q ) + CrO 4 2− ( a q ) + H 2 O ( l )

Chromium(VI) oxide and manganese(VII) oxide react with water to form the acids H 2 CrO 4 and HMnO 4 , respectively.

Hydroxides

When a soluble hydroxide is added to an aqueous solution of a salt of a transition metal of the first transition series, a gelatinous precipitate forms. For example, adding a solution of sodium hydroxide to a solution of cobalt sulfate produces a gelatinous pink or blue precipitate of cobalt(II) hydroxide. The net ionic equation is:

Co 2+ ( a q ) + 2OH ( a q ) Co ( OH ) 2 ( s )

In this and many other cases, these precipitates are hydroxides containing the transition metal ion, hydroxide ions, and water coordinated to the transition metal. In other cases, the precipitates are hydrated oxides composed of the metal ion, oxide ions, and water of hydration:

4Fe 3+ ( a q ) + 6OH ( a q ) + n H 2 O ( l ) 2 Fe 2 O 3 · ( n + 3 ) H 2 O ( s )

These substances do not contain hydroxide ions. However, both the hydroxides and the hydrated oxides react with acids to form salts and water. When precipitating a metal from solution, it is necessary to avoid an excess of hydroxide ion, as this may lead to complex ion formation as discussed later in this chapter. The precipitated metal hydroxides can be separated for further processing or for waste disposal.

Carbonates

Many of the elements of the first transition series form insoluble carbonates. It is possible to prepare these carbonates by the addition of a soluble carbonate salt to a solution of a transition metal salt. For example, nickel carbonate can be prepared from solutions of nickel nitrate and sodium carbonate according to the following net ionic equation:

Ni 2+ ( a q ) + CO 3 2− NiCO 3 ( s )

The reactions of the transition metal carbonates are similar to those of the active metal carbonates. They react with acids to form metals salts, carbon dioxide, and water. Upon heating, they decompose, forming the transition metal oxides.

Other salts

In many respects, the chemical behavior of the elements of the first transition series is very similar to that of the main group metals. In particular, the same types of reactions that are used to prepare salts of the main group metals can be used to prepare simple ionic salts of these elements.

A variety of salts can be prepared from metals that are more active than hydrogen by reaction with the corresponding acids: Scandium metal reacts with hydrobromic acid to form a solution of scandium bromide:

2Sc ( s ) + 6HBr ( a q ) 2 ScBr 3 ( a q ) + 3H 2 ( g )

The common compounds that we have just discussed can also be used to prepare salts. The reactions involved include the reactions of oxides, hydroxides, or carbonates with acids. For example:

Questions & Answers

I don't use to see the messages
Adazion Reply
how can you determine the electronegativity of a compound or in molecules
Shalom Reply
when u move from left to right in a periodic table the negativity increases
reeza
Are you trying to say that the elctronegativity increases down the group and decreases across the period?
Ohanaka
yes and also increases across the period
reeza
for instance when you look at one group of elements in a periodic table electronegativity decreases when you go across the table electronegativity increases. hydrogen is more electronegative than sodium, potassium of that group. oxygen is more electronegative than carbon.
reeza
i hope we all know that organic compounds have carbon as their back bone
Madueke
OK,Thank you so much for the answer. I am happy now
Adazion Reply
can I ask you a question now
Osakue
yes
hanna
what is the oxidation number of nitrogen, oxygen and sulphur
Osakue
5, -2 & -2
hanna
What is an atom?
Adazion Reply
is a smallest particle of a chemical element that can exist
Osakue
can I ask a question
Osakue
it is a substance that cannot be broken down into simpler units by any chemical reaction
Madueke
An atom is the smallest part of an element dat can take part in chemical reaction.
Idris
an atom is the smallest part of an element that can take part in a chemical reaction nd still retain it chemical properties
Precious
what are the branches of an atomic mass
Adazion Reply
Still waiting for answers for a very long time now
Adazion
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Adazion
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Osakue
most of the questions I asked wasn't answered what's the problem guys?
Adazion Reply
hi, there is no problems ooo
Osakue
between H2SO4 and HCL which is the strongest dehydrating agent ?
Ibirogba
HCl is the strongest dehydrating agent
Osakue
ᴡʜᴀᴛ ᴡɪʟʟ ᴏʙsᴇʀᴠᴇᴅ ɪғ ʟᴇᴀᴅ(ɪɪ)ɴɪᴛʀᴀᴛᴇs ɪs ᴀᴅᴅᴇᴅ ᴏɴ ᴛᴏ sᴏᴅɪᴜᴍ ɪᴏᴅɪᴅᴇ sᴏʟᴜᴛɪᴏɴ
Gawaar Reply
what is the functional group of alkanals
Frankyx Reply
can someone explain salt analysis properly
Frankyx
Find the number of calcium atoms present in a sample weighing 2.0*10 raise to the power of -3g
Mfoniso Reply
What does avogadro's law states?
Debora Reply
what is chemistry?
Adazion Reply
Is a branch of science that deals with matter in relation to energy
Kata
permanent hardness of water can be removed by ?
Okorie Reply
***watertreatmentbasics.com/temporary-and-permanent-hardness-of-water/
caco3
Owoyomi
ʜᴏᴡ
Gawaar
What are the basic area in in chemistry
John Reply
acid, base and salt
John
Why do people study chemistry
John
becuz chemistry is the study of elements, nature and etc
John
and also the study of matter and atom
John
is chemistry hard
Jojolade
the answer to that question depends on you
John
what kind of question are u asking fam?
Ibirogba
his asking if chemistry is hard
John
not really just a matter of you willing to study
Okorie
how is Akalis prepared from ashes?
Emmyrae Reply
it could be prepared by extraction with water.
Bra
If you extract it
John
what is brown rings test
Ayo Reply
it is a test to confirm the presence of nitrate ion in solutions
fitzgerald
the types of hydrocarbons
Ohanaka Reply
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Emmanuel

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Source:  OpenStax, Chemistry. OpenStax CNX. May 20, 2015 Download for free at http://legacy.cnx.org/content/col11760/1.9
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