0.3 Reaction equilibrium in the gas phase

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Foundation

In beginning our study of the reactions of gases, we will assume a knowledge of the physical properties ofgases as described by the Ideal Gas Law and an understanding of these properties as given by the postulates and conclusions of the Kinetic Molecular Theory . We assume that we have developed a dynamic model of phase equilibrium in terms of competing rates. We willalso assume an understanding of the bonding, structure, and properties of individual molecules.

Goals

In performing stoichiometric calculations, we assume that we can calculate the amount of product of a reactionfrom the amount of the reactants we start with. For example, if we burn methane gas, $C{H}_{4}\left(g\right)$ , in excess oxygen, the reaction

$C{H}_{4}\left(g\right)+2{O}_{2}\left(g\right)\to C{O}_{2}\left(g\right)+2{H}_{2}O\left(g\right)$

occurs, and the number of moles of $C{O}_{2}\left(g\right)$ produced is assumed to equal the number of moles of $C{H}_{4}\left(g\right)$ we start with.

From our study of phase transitions we have learned the concept of equilibrium. We observed that, in thetransition from one phase to another for a substance, under certain conditions both phases are found to coexist, and we refer to thisas phase equilibrium. It should not surprise us that these same concepts of equilibrium apply to chemical reactions as well. In the reaction , therefore, we should examine whether the reaction actually producesexactly one mole of $C{O}_{2}$ for every mole of $C{H}_{4}$ we start with or whether we wind up with an equilibrium mixture containing both $C{O}_{2}$ and $C{H}_{4}$ . We will find that different reactions provide us with varyinganswers. In many cases, virtually all reactants are consumed, producing the stoichiometric amount of product. However, in manyother cases, substantial amounts of reactant are still present when the reaction achieves equilibrium, and in other cases, almost noproduct is produced at equilibrium. Our goal will be to understand, describe and predict the reaction equilibrium.

An important corollary to this goal is to attempt to control the equilibrium. We will find that varying theconditions under which the reaction occurs can vary the amounts of reactants and products present at equilibrium. We will develop ageneral principle for predicting how the reaction conditions affect the amount of product produced at equilibrium.

Observation 1: reaction equilibrium

We begin by analyzing a significant industrial chemical process, the synthesis of ammonia gas, $N{H}_{3}$ , from nitrogen and hydrogen:

${N}_{2}\left(g\right)+3{H}_{2}\left(g\right)\to 2N{H}_{3}\left(g\right)$

If we start with 1 mole of ${N}_{2}$ and 3 moles of ${H}_{2}$ , the balanced equation predicts that we will produce 2 moles of $N{H}_{3}$ . In fact, if we carry out this reaction starting with thesequantities of nitrogen and hydrogen at 298K in a 100.0L reaction vessel, we observe that the number of moles of $N{H}_{3}$ produced is 1.91 mol. This "yield" is less than predicted by the balanced equation, but the difference is not dueto a limiting reagent factor. Recall that, in stoichiometry, the limiting reagent is the one that is present in less than the ratioof moles given by the balanced equation. In this case, neither ${N}_{2}$ nor ${H}_{2}$ is limiting because they are present initially in a 1:3 ratio, exactly matching the stoichiometry. Note also that this seemingdeficit in the yield is not due to any experimental error or imperfection, nor is it due to poor measurements or preparation.Rather, the observation that, at 298K, 1.91 moles rather than 2 moles are produced is completely reproducible: every measurement ofthis reaction at this temperature in this volume starting with 1 mole of ${N}_{2}$ and 3 moles of ${H}_{2}$ gives this result. We conclude that the reaction achieves reaction equilibrium in which all three gases are present in the gas mixture. We can determine the amountsof each gas at equilibrium from the stoichiometry of the reaction. When ${n}_{N{H}_{3}}=1.91\mathrm{mol}$ are created, the number of moles of ${N}_{2}$ remaining at equilibrium is ${n}_{{N}_{2}}=0.045\mathrm{mol}$ and ${n}_{{H}_{2}}=0.135\mathrm{mol}$ .

where we get a research paper on Nano chemistry....?
nanopartical of organic/inorganic / physical chemistry , pdf / thesis / review
Ali
what are the products of Nano chemistry?
There are lots of products of nano chemistry... Like nano coatings.....carbon fiber.. And lots of others..
learn
Even nanotechnology is pretty much all about chemistry... Its the chemistry on quantum or atomic level
learn
da
no nanotechnology is also a part of physics and maths it requires angle formulas and some pressure regarding concepts
Bhagvanji
hey
Giriraj
Preparation and Applications of Nanomaterial for Drug Delivery
revolt
da
Application of nanotechnology in medicine
what is variations in raman spectra for nanomaterials
ya I also want to know the raman spectra
Bhagvanji
I only see partial conversation and what's the question here!
what about nanotechnology for water purification
please someone correct me if I'm wrong but I think one can use nanoparticles, specially silver nanoparticles for water treatment.
Damian
yes that's correct
Professor
I think
Professor
Nasa has use it in the 60's, copper as water purification in the moon travel.
Alexandre
nanocopper obvius
Alexandre
what is the stm
is there industrial application of fullrenes. What is the method to prepare fullrene on large scale.?
Rafiq
industrial application...? mmm I think on the medical side as drug carrier, but you should go deeper on your research, I may be wrong
Damian
How we are making nano material?
what is a peer
What is meant by 'nano scale'?
What is STMs full form?
LITNING
scanning tunneling microscope
Sahil
how nano science is used for hydrophobicity
Santosh
Do u think that Graphene and Fullrene fiber can be used to make Air Plane body structure the lightest and strongest. Rafiq
Rafiq
what is differents between GO and RGO?
Mahi
what is simplest way to understand the applications of nano robots used to detect the cancer affected cell of human body.? How this robot is carried to required site of body cell.? what will be the carrier material and how can be detected that correct delivery of drug is done Rafiq
Rafiq
if virus is killing to make ARTIFICIAL DNA OF GRAPHENE FOR KILLED THE VIRUS .THIS IS OUR ASSUMPTION
Anam
analytical skills graphene is prepared to kill any type viruses .
Anam
Any one who tell me about Preparation and application of Nanomaterial for drug Delivery
Hafiz
what is Nano technology ?
write examples of Nano molecule?
Bob
The nanotechnology is as new science, to scale nanometric
brayan
nanotechnology is the study, desing, synthesis, manipulation and application of materials and functional systems through control of matter at nanoscale
Damian
Is there any normative that regulates the use of silver nanoparticles?
what king of growth are you checking .?
Renato
What fields keep nano created devices from performing or assimulating ? Magnetic fields ? Are do they assimilate ?
why we need to study biomolecules, molecular biology in nanotechnology?
?
Kyle
yes I'm doing my masters in nanotechnology, we are being studying all these domains as well..
why?
what school?
Kyle
biomolecules are e building blocks of every organics and inorganic materials.
Joe
how did you get the value of 2000N.What calculations are needed to arrive at it
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