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Typical analysis of gallium obtained as a side product from the Bayer process.
Element Bayer process (ppm) After acid/base leaching (ppm) 500 zone passes (ppm)
aluminum 100-1,000 7 <1
calcium 10-100 not detected not detected
copper 100-1,000 2 <1
iron 100-1,000 7 <1
lead <2000 30 not detected
magnesium 10-100 1 not detected
mercury 10-100 not detected not detected
nickel 10-100 not detected not detected
silicon 10-100 ≈ 1 not detected
tin 10-100 ≈ 1 not detected
titanium 10-100 1 <1
zinc 30,000 ≈ 1 not detected
Schematic representation of a zone refining apparatus.

Isolation and purification of elemental arsenic

Elemental arsenic (L. arsenicum, yellow orpiment) exists in two forms: yellow (cubic, As 4 ) and gray or metallic (rhombohedral). At a natural abundance of 1.8 ppm arsenic is relatively rare, however, this is offset by its presence in a number of common minerals and the relative ease of isolation. Arsenic containing minerals are grouped into three main classes: the sulfides realgar (As 4 S 4 ) and orpiment (As 2 S 3 ), the oxide arsenolite (As 2 O 3 ), and the arsenides and sulfaresenides of the iron, cobalt, and nickel. Minerals in this latter class include: loellinginite (FeAs 2 ), safforlite (CoAs), niccolite (NiAs), rammelsbergite (NiAs 2 ), ansenopyrite or mispickel (FeAsS), cobaltite (CoAsS), enargite (Cu 3 AsS 4 ), gerdsorfite (NiAsS), and the quarturnary sulfide glaucodot [(Co,Fe)AsS]. [link] shows the typical impurities in arsenopyrite.

Typical impurities in arsenopyrite.
Element Concentration (ppm) Element Concentration (ppm)
silver 90 nickel <3,000
gold 8 lead 50
cobalt 30,000 platinum 0.4
copper 200 rhenium 50
germanium 30 selenium 50
manganese 3,000 vanadium 300
molybdenum 60 zinc 400

Arsenic is obtained commercially by smelting either FeAs 2 or FeAsS at 650-700 °C in the absence of air and condensing the sublimed element (T sub = 613 °C), [link] .

The arsenic thus obtained is combined with lead and then sublimed (T sub = 614 °C) which binds any sulfur impurities more strongly than arsenic. Any residual arsenic that remains trapped in the iron sulfide is separated by forming the oxide (As 2 O 3 ) by roasting the sulfide in air. The oxide is sublimed into the flue system during roasting from where it is collected and reduced with charcoal at 700-800 °C to give elemental arsenic. Semiconductor grade arsenic (>99.9999%) is formed by zone refining.

Synthesis and purification of gallium arsenide.

Gallium arsenide can be prepared by the direct reaction of the elements, [link] . However, while conceptually simple the synthesis of GaAs is complicated by the different vapor pressures of the reagents and the highly exothermic nature of the reaction. Furthermore, since the synthesis of GaAs at atmospheric pressure is accompanied by its simultaneous decomposes due to the loss by sublimation, of arsenic, the synthesis must be carried out under an overpressure of arsenic in order to maintain a stoichiometric composition of the synthesized GaAs.

In order to overcome the problems associated with arsenic loss, the reaction is usually carried out in a sealed reaction tube. However, if a stoichiometric quantity of arsenic is used in the reaction a constant temperature of 1238 °C must be employed in order to maintain the desired arsenic overpressure of 1 atm. Practically, it is easier to use a large excess of arsenic heated to a lower temperature. In this situation the pressure in the tube is approximately equal to the equilibrium vapor pressure of the volatile component (arsenic) at the lower temperature. Thus, an over pressure of 1 atm arsenic may be maintained if within a sealed tube elemental arsenic is heated to 600-620 °C while the GaAs is maintained at 1240-1250 °C.

[link] shows the sealed tube configuration that is typically used for the synthesis of GaAs. The tube is heated within a two-zone furnace. The boats holding the reactants are usually made of quartz, however, graphite is also used since the latter has a closer thermal expansion match to the GaAs product. If higher purity is required then pyrolytic boron nitride (PBN) is used. One of the boats is loaded with pure gallium the other with arsenic. A plug of quartz wool may be placed between the boats to act as a diffuser. The tube is then evacuated and sealed. Once brought to the correct reaction temperatures ( [link] ), the arsenic vapor is transported to the gallium, and they react to form GaAs in a controlled manner. [link] gives the typical impurity concentrations found in polycrystalline GaAs.

Schematic representation of a sealed tube synthesis of GaAs.
Impurity concentrations found in polycrystalline GaAs.
Element Concentration (ppm) Element Concentration (ppm)
boron 0.1 silicon 0.02
carbon 0.7 phosphorus 0.1
nitrogen 0.1 sulfur 0.01
oxygen 0.5 chlorine 0.08
fluorine 0.2 nickel 0.04
magnesium 0.02 copper 0.01
aluminum 0.02 zinc 0.05

Polycrystalline GaAs, formed in from the direct reaction of the elements is often used as the starting material for single crystal growth via Bridgeman or Czochralski crystal growth. It is also possible to prepare single crystals of GaAs directly from the elements using in-situ, or direct, compounding within a high-pressure liquid encapsulated Czochralski (HPLEC) technique.


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  • J. Krauskopf, J. D. Meyer, B. Wiedemann, M. Waldschmidt, K. Bethge, G. Wolf, and W. Schültze, 5th Conference on Semi-insulating III-V Materials, Malmo, Sweden, 1988, Eds. G. Grossman and L. Ledebo, Adam-Hilger, New York (1988).
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Questions & Answers

what is Nano technology ?
Bob Reply
write examples of Nano molecule?
The nanotechnology is as new science, to scale nanometric
nanotechnology is the study, desing, synthesis, manipulation and application of materials and functional systems through control of matter at nanoscale
Is there any normative that regulates the use of silver nanoparticles?
Damian Reply
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Stoney Reply
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Adin Reply
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Damian Reply
sciencedirect big data base
Introduction about quantum dots in nanotechnology
Praveena Reply
what does nano mean?
Anassong Reply
nano basically means 10^(-9). nanometer is a unit to measure length.
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Damian Reply
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Akash Reply
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characteristics of micro business
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Do somebody tell me a best nano engineering book for beginners?
s. Reply
there is no specific books for beginners but there is book called principle of nanotechnology
what is fullerene does it is used to make bukky balls
Devang Reply
are you nano engineer ?
fullerene is a bucky ball aka Carbon 60 molecule. It was name by the architect Fuller. He design the geodesic dome. it resembles a soccer ball.
what is the actual application of fullerenes nowadays?
That is a great question Damian. best way to answer that question is to Google it. there are hundreds of applications for buck minister fullerenes, from medical to aerospace. you can also find plenty of research papers that will give you great detail on the potential applications of fullerenes.
what is the Synthesis, properties,and applications of carbon nano chemistry
Abhijith Reply
Mostly, they use nano carbon for electronics and for materials to be strengthened.
is Bucky paper clear?
carbon nanotubes has various application in fuel cells membrane, current research on cancer drug,and in electronics MEMS and NEMS etc
so some one know about replacing silicon atom with phosphorous in semiconductors device?
s. Reply
Yeah, it is a pain to say the least. You basically have to heat the substarte up to around 1000 degrees celcius then pass phosphene gas over top of it, which is explosive and toxic by the way, under very low pressure.
Do you know which machine is used to that process?
how to fabricate graphene ink ?
for screen printed electrodes ?
What is lattice structure?
s. Reply
of graphene you mean?
or in general
in general
Graphene has a hexagonal structure
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Source:  OpenStax, Chemistry of electronic materials. OpenStax CNX. Aug 09, 2011 Download for free at http://cnx.org/content/col10719/1.9
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