15.2 The first law of thermodynamics and some simple processes  (Page 5/12)

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There must be reasons that real macroscopic processes cannot be reversible. We can imagine them going in reverse. For example, heat transfer occurs spontaneously from hot to cold and never spontaneously the reverse. Yet it would not violate the first law of thermodynamics for this to happen. In fact, all spontaneous processes, such as bubbles bursting, never go in reverse. There is a second thermodynamic law that forbids them from going in reverse. When we study this law, we will learn something about nature and also find that such a law limits the efficiency of heat engines. We will find that heat engines with the greatest possible theoretical efficiency would have to use reversible processes, and even they cannot convert all heat transfer into doing work. [link] summarizes the simpler thermodynamic processes and their definitions.

 Isobaric Constant pressure $W=P\Delta V$ Isochoric Constant volume $W=0$ Isothermal Constant temperature $Q=W$ Adiabatic No heat transfer $Q=0$

Phet explorations: states of matter

Watch different types of molecules form a solid, liquid, or gas. Add or remove heat and watch the phase change. Change the temperature or volume of a container and see a pressure-temperature diagram respond in real time. Relate the interaction potential to the forces between molecules.

Section summary

• One of the important implications of the first law of thermodynamics is that machines can be harnessed to do work that humans previously did by hand or by external energy supplies such as running water or the heat of the Sun. A machine that uses heat transfer to do work is known as a heat engine.
• There are several simple processes, used by heat engines, that flow from the first law of thermodynamics. Among them are the isobaric, isochoric, isothermal and adiabatic processes.
• These processes differ from one another based on how they affect pressure, volume, temperature, and heat transfer.
• If the work done is performed on the outside environment, work ( $W$ ) will be a positive value. If the work done is done to the heat engine system, work ( $W$ ) will be a negative value.
• Some thermodynamic processes, including isothermal and adiabatic processes, are reversible in theory; that is, both the thermodynamic system and the environment can be returned to their initial states. However, because of loss of energy owing to the second law of thermodynamics, complete reversibility does not work in practice.

Conceptual questions

A great deal of effort, time, and money has been spent in the quest for the so-called perpetual-motion machine, which is defined as a hypothetical machine that operates or produces useful work indefinitely and/or a hypothetical machine that produces more work or energy than it consumes. Explain, in terms of heat engines and the first law of thermodynamics, why or why not such a machine is likely to be constructed.

One method of converting heat transfer into doing work is for heat transfer into a gas to take place, which expands, doing work on a piston, as shown in the figure below. (a) Is the heat transfer converted directly to work in an isobaric process, or does it go through another form first? Explain your answer. (b) What about in an isothermal process? (c) What about in an adiabatic process (where heat transfer occurred prior to the adiabatic process)?

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what is displacement
movement in a direction
Jason
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Hosea
Explain why magnetic damping might not be effective on an object made of several thin conducting layers separated by insulation? can someone please explain this i need it for my final exam
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saeid
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Yimam
What is thê principle behind movement of thê taps control
while
Hosea
what is atomic mass
this is the mass of an atom of an element in ratio with the mass of carbon-atom
Chukwuka
show me how to get the accuracies of the values of the resistors for the two circuits i.e for series and parallel sides
Explain why it is difficult to have an ideal machine in real life situations.
tell me
Promise
what's the s . i unit for couple?
Promise
its s.i unit is Nm
Covenant
Force×perpendicular distance N×m=Nm
Oluwakayode
İt iş diffucult to have idêal machine because of FRİCTİON definitely reduce thê efficiency
Oluwakayode
if the classica theory of specific heat is valid,what would be the thermal energy of one kmol of copper at the debye temperature (for copper is 340k)
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haider
what affects fluid
pressure
Oluwakayode
Dimension for force MLT-2
what is the dimensions of Force?
how do you calculate the 5% uncertainty of 4cm?
4cm/100×5= 0.2cm
haider
how do you calculate the 5% absolute uncertainty of a 200g mass?
= 200g±(5%)10g
haider
use the 10g as the uncertainty?
melia
haider
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haider
the relationship between the applied force and the deflection
melia
sorry wrong question i meant the 5% uncertainty of 4cm?
melia
its 0.2 cm or 2mm
haider
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melia
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Olokuntoye
0.2m
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