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By the end of this section, you will be able to:
  • Describe the synthesis of transuranium nuclides
  • Explain nuclear fission and fusion processes
  • Relate the concepts of critical mass and nuclear chain reactions
  • Summarize basic requirements for nuclear fission and fusion reactors

After the discovery of radioactivity, the field of nuclear chemistry was created and developed rapidly during the early twentieth century. A slew of new discoveries in the 1930s and 1940s, along with World War II, combined to usher in the Nuclear Age in the mid-twentieth century. Science learned how to create new substances, and certain isotopes of certain elements were found to possess the capacity to produce unprecedented amounts of energy, with the potential to cause tremendous damage during war, as well as produce enormous amounts of power for society’s needs during peace.

Synthesis of nuclides

Nuclear transmutation is the conversion of one nuclide into another. It can occur by the radioactive decay of a nucleus, or the reaction of a nucleus with another particle. The first manmade nucleus was produced in Ernest Rutherford’s laboratory in 1919 by a transmutation reaction, the bombardment of one type of nuclei with other nuclei or with neutrons. Rutherford bombarded nitrogen atoms with high-speed α particles from a natural radioactive isotope of radium and observed protons resulting from the reaction:

7 14 N + 2 4 He 8 17 O + 1 1 H

The 8 17 O and 1 1 H nuclei that are produced are stable, so no further (nuclear) changes occur.

To reach the kinetic energies necessary to produce transmutation reactions, devices called particle accelerators are used. These devices use magnetic and electric fields to increase the speeds of nuclear particles. In all accelerators, the particles move in a vacuum to avoid collisions with gas molecules. When neutrons are required for transmutation reactions, they are usually obtained from radioactive decay reactions or from various nuclear reactions occurring in nuclear reactors. The Chemistry in Everyday Life feature that follows discusses a famous particle accelerator that made worldwide news.

Cern particle accelerator

Located near Geneva, the CERN (“Conseil Européen pour la Recherche Nucléaire,” or European Council for Nuclear Research) Laboratory is the world’s premier center for the investigations of the fundamental particles that make up matter. It contains the 27-kilometer (17 mile) long, circular Large Hadron Collider (LHC), the largest particle accelerator in the world ( [link] ). In the LHC, particles are boosted to high energies and are then made to collide with each other or with stationary targets at nearly the speed of light. Superconducting electromagnets are used to produce a strong magnetic field that guides the particles around the ring. Specialized, purpose-built detectors observe and record the results of these collisions, which are then analyzed by CERN scientists using powerful computers.

Two photos are shown and labeled “a” and “b.” Photo a shows an aerial view of the Large Hadron Collider. Photo b shows a tunnel of concrete with rails on the ground and tubes and wires running along the wall. Two people walk along the tunnel.
A small section of the LHC is shown with workers traveling along it. (credit: Christophe Delaere)

In 2012, CERN announced that experiments at the LHC showed the first observations of the Higgs boson, an elementary particle that helps explain the origin of mass in fundamental particles. This long-anticipated discovery made worldwide news and resulted in the awarding of the 2103 Nobel Prize in Physics to François Englert and Peter Higgs, who had predicted the existence of this particle almost 50 years previously.

Questions & Answers

what is d meaning of organic chemistry
Elizabeth Reply
it's a compound that comprises of hydrocarbon
Omoru
what iz alkanol
icha Reply
alkanol there are organic compounds with the functional group of ROH and relative molecular formula (CnH2n+1+OH)
Omoru
ok tnk u
icha
you are welcome
Omoru
What's alkaline soil
Amoo Reply
a system in which only energy is transferred between the system and the surrounding is called?
Ani Reply
which Element exhibit diagonal relationship with aluminum
Ani
following processes: Solid phosphorus pentachloride decomposes to liquid phosphorus trichloride and chlorine gas b. Deep blue solid copper(II) sulfate pentahydrate is heated to drive off water vapor to form white solid copper(II) sulfate
Hisham Reply
How to know periodic table oftend
Ahmed Reply
u can know it through singing it as song it simple
Elizabeth
how to get atomic number of an element
Ogunleye Reply
how do you solve the examples in a much more explanatory way
Ogunleye
it seems by multiplying d number of d element by 2
Elizabeth
E.g like carbon 6*2=12 so d atomic number is 12
Elizabeth
The reaction of aceto nitrile with propane in the presence of the acid
Explain this paragraph in short
Manish Reply
What is solid state?
Manish Reply
What is chemical reaction
Manish
transforming reactants to product(s)
Andre
process
Andre
solid state is composed of tightly particles and it has a definite shape and volume
Elizabeth
Example of Lewis acid
Chidera Reply
Example of Lewis acid
Chidera
Chlorine
Mikidad
Anything with an empty orbital... the hydrogen ion is the most common example. BH3 is the typical example, but any metal in a coordination complex can be considered a Lewis acid.
Eszter
okay thanks
Jovial
aluminium and sulphur react to give aluminium sulfide.How many grams of Al are required to produce 100g of aluminium sulphide
Soni Reply
aluminium and sulphur react to give aluminium sulphide how many grams of Al are required to produce 100g of aluminium sulphide?
Soni
aluminium and sulphur react to give aluminium sulphide how many grams of Al are required to produce 100g of aluminium sulphide?
Soni
2Al+3S=Al2S3
galina
m(Al)=100×27×2/150=36g
galina
150 comes from?
Soni
thank you very much
Soni
molar mass of Al2S3
galina
150.158
thiru
what's periodic table
Agnes
Why can't atom be created or destroyed
Jacaranda Reply
matter simply converts to pure energy
that's nice
Meshach
explain how to distinguish ethanol from a sample of ethanoic acid by chemical test
Alice Reply
explain how ethanol can be distinguished from ethanoic acid by chemical test
Alice
Using a suitable experiment, describe how diffusion occurs in gases.
Melody Reply
when the excited energy which are in gaseous state collides with another to liberate from one place to another
Meshach

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Source:  OpenStax, Chemistry. OpenStax CNX. May 20, 2015 Download for free at http://legacy.cnx.org/content/col11760/1.9
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