<< Chapter < Page Chapter >> Page >

Water is a polar molecule, with the hydrogen atoms acquiring a partial positive charge and the oxygen a partial negative charge. This occurs because the nucleus of the oxygen atom is more attractive to the electrons of the hydrogen atoms than the hydrogen nucleus is to the oxygen’s electrons. Thus oxygen has a higher electronegativity    than hydrogen and the shared electrons spend more time in the vicinity of the oxygen nucleus than they do near the nucleus of the hydrogen atoms, giving the atoms of oxygen and hydrogen slightly negative and positive charges, respectively. Another way of stating this is that the probability of finding a shared electron near an oxygen nucleus is more likely than finding it near a hydrogen nucleus. Either way, the atom’s relative electronegativity contributes to the development of partial charges whenever one element is significantly more electronegative than the other, and the charges generated by these polar bonds may then be used for the formation of hydrogen bonds based on the attraction of opposite partial charges. (Hydrogen bonds, which are discussed in detail below, are weak bonds between slightly positively charged hydrogen atoms to slightly negatively charged atoms in other molecules.) Since macromolecules often have atoms within them that differ in electronegativity, polar bonds are often present in organic molecules.

Nonpolar covalent bonds

Nonpolar covalent bonds form between two atoms of the same element or between different elements that share electrons equally. For example, molecular oxygen (O 2 ) is nonpolar because the electrons will be equally distributed between the two oxygen atoms.

Another example of a nonpolar covalent bond is methane (CH 4 ), also shown in [link] . Carbon has four electrons in its outermost shell and needs four more to fill it. It gets these four from four hydrogen atoms, each atom providing one, making a stable outer shell of eight electrons. Carbon and hydrogen do not have the same electronegativity but are similar; thus, nonpolar bonds form. The hydrogen atoms each need one electron for their outermost shell, which is filled when it contains two electrons. These elements share the electrons equally among the carbons and the hydrogen atoms, creating a nonpolar covalent molecule.

Table compares water, methane and carbon dioxide molecules. In water, oxygen has a stronger pull on electrons than hydrogen resulting in a polar covalent O-H bond. Likewise in carbon dioxide the oxygen has a stronger pull on electrons than carbon and the bond is polar covalent. However, water has a bent shape because two lone pairs of electrons push the hydrogen atoms together so the molecule is polar. By contrast carbon dioxide has two double bonds that repel each other, resulting in a linear shape. The polar bonds in carbon dioxide cancel each other out, resulting in a nonpolar molecule. In methane, the bond between carbon and hydrogen is nonpolar and the molecule is a symmetrical tetrahedron with hydrogens spaced as far apart as possible on the three-dimensional sphere. Since methane is symmetrical with nonpolar bonds, it is a nonpolar molecule.
Whether a molecule is polar or nonpolar depends both on bond type and molecular shape. Both water and carbon dioxide have polar covalent bonds, but carbon dioxide is linear, so the partial charges on the molecule cancel each other out.

Hydrogen bonds and van der waals interactions

Ionic and covalent bonds between elements require energy to break. Ionic bonds are not as strong as covalent, which determines their behavior in biological systems. However, not all bonds are ionic or covalent bonds. Weaker bonds can also form between molecules. Two weak bonds that occur frequently are hydrogen bonds and van der Waals interactions. Without these two types of bonds, life as we know it would not exist. Hydrogen bonds provide many of the critical, life-sustaining properties of water and also stabilize the structures of proteins and DNA, the building block of cells.

Questions & Answers

the difference between the two cells
Obeng Reply
explain the courses and the correction of lon term sightedness and short term sightedness
Isaac Reply
why drinking excess alcohol causes thirst and dehydration
uwikuzo Reply
what is reproduction
smart Reply
it is d act of bringing young ones to life
to ensure survival of a species🚴‍♀️
what is a genotype
what is hazardous
a cell is the smallest unit of a living thing. so we all have cell
It is the formation of a zygote resulting from the fusion of the sperm cell with the ovum.Thus,this results in the production of new species which are genetically dissimilar from their parent cells.
what is size of cell
Mohd Reply
what is size of Hart
nanometers=um sign thingie
monomers and polymers of nucleic acids?
Jyrl Reply
dna and rna involvement
give me the elements of the soil
Iguma Reply
Air, water, organic matter, inorganic matter
soil water humus air
silica, iron
potassium, sulfur, calcium, carbon
what is cell
iyaji Reply
A cell is a smallest fundamental unit of a living organisms.
the basic structural and functional unit of life
what is size of cell
all things are made up of.....all things cannot exist without pre-exisiting cells...check out the 16th ce tury to learn more about microscope use and cells. i will give a hint: Mr. L.
we are all made of cells
Nutrition - sensitive intervention
Therowda Reply
what does the sori In fern mean
arhin Reply
biology is the study .exactly what is life?
i'm sorry , the study of life
how can U identify a person through his blood
Frankyx Reply
through genetic fingerprinting where specific DNA sequences in a person genome can be identified.
by help of genetics and DNA test
can it also be detected using an RNA test
environmental biology
Ojesola Reply
what is phytoplankton
What is anabolism
Treasure Reply
the break down of substance
how many teeth has an adult person
32 teeth
32 (or 36 including the wisdom teeth)
what is homoestastis
Ayo Reply
hypothalamus negative feedback vs. postive feedback systems.
it is the maintenance of a steady internal environment.it is controlled largely by the brain especially the hypothalamus.

Get the best Biology course in your pocket!

Source:  OpenStax, Biology. OpenStax CNX. Feb 29, 2016 Download for free at http://cnx.org/content/col11448/1.10
Google Play and the Google Play logo are trademarks of Google Inc.

Notification Switch

Would you like to follow the 'Biology' conversation and receive update notifications?